We investigated the conditions for forming the single-frequency monopulse operation mode of the transversally diode pumped Yb,Er-phosphate glass laser with a passive Q-switch based on the Co 2 + :MgAl 2 O 4 crystal. It was shown experimentally that the spectral selectivity that ensures the stable single-frequency operation for the Yb,Er-laser is achieved in the intracavity Fabry–Perot interferometer in the form of the totally reflecting mirror and nearest end surface of an active element with plane-parallel faces, as well as the polarization interference filter (PIF, Lyot filter). Meanwhile, the PIF created by an active element with thermally induced anisotropy and a polarizer in the form of a passive Q-switch plate, oriented at Brewster’s angle to the resonator axis, acts as a preliminary spectral selector. The maximum energy of the formed output laser pulses was 6 mJ with a duration of 20.2 ns, a repetition rate of 1 Hz, and a singlefrequency lasing spectrum width of 41 MHz.

It was found that the long-wavelength absorption band of the laser dye IR 1061 and its analogue with an unsubstituted polymethine chain is strongly broadened and decreases in intensity in polar solvents, while the fluorescence band remains narrow and practically does not change in a wide range of solvent polarities. Based on the quantum-chemical calculations of these dyes by the ab initio DFT/B3LYP/6-31G (d,p) and TDDFT methods, taking into account the polarity of the medium by the PCM method, it is shown that the reason for this difference is the weakening of solvation in the fluorescent state as compared to the ground state due to the greater equalization of the charge in the first than in the latter. An increase in the alternation of bond orders in the polymethine chain in the fluorescent state was found, which causes an increase of vibronic interactions in the radiative transition as compared to the absorptive one. Spectral effects caused by a change in the angle of rotation of phenyl groups in the thiopyrylium cycle upon excitation have been analyzed.

The formation features of the regime of single-frequency unidirectional monopulse lasing of Nd:YAG laser with a triple-mirror ring cavity and a side diode-pump under the condition of injection of external narrow-band optical radiation into the resonator are studied. It is experimentally shown that the asymmetrical layout of the intracavity elements relative to the laser output mirror and the depolarization effects in these elements lead to a difference in the energy and polarization of the monopulse Nd:YAG ring laser depending on the direction (clockwise or anticlockwise) of the input of the injected radiation. The difference in the output characteristics of the single-frequency unidirectional monopulse Nd:YAG ring laser is the most evident in the case of transition from the active to the passive Q-switching.