Annals of the New York Academy of SciencesVolume 415, Issue 1 p. 235-243 THE HYDROGENATION OF CARBONYL COMPOUNDS CATALYZED BY ANIONIC RUTHENIUM HYDRIDE COMPLEXES AND ALKALI-DOPED SUPPORTED GROUP VIII METALS Roger A. Grey, Roger A. Grey Technology and Development ARCO Chemical Company Newtown Square, Pennsylvania 19073Search for more papers by this authorGuido P. Pez, Guido P. Pez Corporate Science Center Air Products and Chemicals, Inc. Allentown, Pennsylvania 18105Search for more papers by this authorAndrea Wallo, Andrea Wallo Corporate Research and Development Allied Corporation Morristown, New Jersey 07960Search for more papers by this authorJeff Corsi, Jeff Corsi Corporate Research and Development Allied Corporation Morristown, New Jersey 07960Search for more papers by this author Roger A. Grey, Roger A. Grey Technology and Development ARCO Chemical Company Newtown Square, Pennsylvania 19073Search for more papers by this authorGuido P. Pez, Guido P. Pez Corporate Science Center Air Products and Chemicals, Inc. Allentown, Pennsylvania 18105Search for more papers by this authorAndrea Wallo, Andrea Wallo Corporate Research and Development Allied Corporation Morristown, New Jersey 07960Search for more papers by this authorJeff Corsi, Jeff Corsi Corporate Research and Development Allied Corporation Morristown, New Jersey 07960Search for more papers by this author First published: December 1983 https://doi.org/10.1111/j.1749-6632.1983.tb47362.xCitations: 9AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Citing Literature Volume415, Issue1Catalytic Transition Mental HydratesDecember 1983Pages 235-243 RelatedInformation
AbstractDie luftempfindlichen Hydridoruthenat‐Komplexe K [(Ph3P), ?hg P‐C6H4 ‐lkuH, T‐Naphthalin ‐ Ether (HPR) und K; [(Ph3P)3 Ph2PRu2 H4 12′ ° 2 Diglyme (Ph = Phenyl) (DHPR) bewirken die homogene Katalyse der Hydrierung (620 kPa) von Ketonen oder Aldehyden wie z.B. Aceton (I) Cyclohexanon oder Propanal innerhalb von 16 bzw. 1 h zu den entsprechenden Alkoholen wie z.B. (II) und Kondensationsprodukten wie (III), wobei ein Zusatz von 18‐ Krone‐ö die Reaktionsdauer teilweise erheblich verkürzt.
The photochemical decomposition of Nd3+/EDTA and Ho3+/EDTA has been carried out at 300 nm, and followed by changes within the hypersensitive absorption transitions of these ions. It was found that a single decarboxylation of the EDTA ligand occurred, and CO2 gas was evolved. The reaction terminates after approx. 1 mol of CO2 per mole of EDTA is produced, since the photoproduct absorbs strongly at 300 nm. Initial quantum yields were found to vary with pH, but averaged between 0.1 and 0.5 mol/Einstein.
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAnionic metal hydride catalysts. 2. Application to the hydrogenation of ketones, aldehydes, carboxylic acid esters, and nitrilesRoger A. Grey, Guido P. Pez, and Andrea WalloCite this: J. Am. Chem. Soc. 1981, 103, 25, 7536–7542Publication Date (Print):December 1, 1981Publication History Published online1 May 2002Published inissue 1 December 1981https://doi.org/10.1021/ja00415a022RIGHTS & PERMISSIONSArticle Views1953Altmetric-Citations192LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (1 MB) Get e-Alerts Get e-Alerts
AbstractDie Hydrierung z.B. von Anthracen unter Druck in THF und in Gegenwart des anionischen Hydridkomplexes (Ph3P)2(Ph2PC6H4 kuH;K ‐C",H8‐(Et2O) bei 100°C führt nach 20stündiger Reaktion bei 99proz. Umsatz zu 98% Tetrahydroanthracen und 2% 1,2,3,4,5,6,7,8‐Octahydro‐anthracen.
The homogeneous catalytic hydrogenation of activated and simple aliphatic carboxylic acid esters to their corresponding primary alcohols has been accomplished under mild conditions [90 °C; 620 kPa (gauge) of hydrogen] using a novel anionic ruthenium hydride complex.
