The rainfall reduction in the 1970s, less marked in Central Africa than in West Africa, still had a major impact on the hydrological regimes of the region's large rivers. The study of the hydropluviometric behavior of the Ubangi River at Mobaye has the advantage of being a study of a basin excluding anthropogenic impact. Forest cover and population density have not changed since at least 1970. Statistical analysis of the breaks in the long rainfall time series to Mobaye (1938–2015) confirms a long period of drought from 1969 to 2006, corresponding to a reduction of 8% in rainfall. Also, the study of the corresponding hydrological series indicates a second downward break in 1981, marking an exceptional hydrological drought. Flows increased in 2013, a few years after the rainfall increase. The statistical study of the annual rainfall/flow series of the upstream basins over the period 1951–1995 (the Kotto River in Kembe and Bria, the Mbomu River in Bangassou and Zemio, and the Uele River + Bili hydrographic system) highlights different hydrological behaviors related to the vegetation cover. On the one hand, the savannah basins show a continuous hydrological deficit marked by a runoff coefficient (CE) that fell to only 5% from the 1990s. On the other hand, the basins under forest show a runoff increase since 1990, marked by a CE above 10%. Under savannah, the part of the flow infiltrating to recharge the aquifer would have decreased faster than under forest, which results in a runoff CE very significantly negatively correlated with the savannah area present in the studied watershed.

We test the applicability of bivalve shell oxygen isotope composition to reconstruct hydrological dynamics in four riverine sites in the Congo River basin. Twenty-three specimens from the Unionoida order were collected from locations where long-term discharge data are available, and in situ measurements and water samples were collected over several years. Due to the highly variable (species-specific) shell morphology, various sampling techniques were used to analyze the shell sections; however, every specimen recorded the seasonality of the host water oxygen stable isotope composition (δ18Ow) in its δ18Oshell record. Discharge data showed an inverse relationship with δ18Ow values, which was well described with a logarithmic fit. An exception was the Kasai River, where the δ18Ow record shows an additional peak occurring during the high discharge period, which renders the discharge-δ18Ow relationship more complex than in the other systems investigated. Low ratios of maximum to minimum discharge (Qmax/Qmin) were found to result in a low δ18Ow amplitude, which was reflected as low δ18Oshell variability. The Congo and Kasai rivers had Qmax/Qmin ratios ~2 to 2.5, while the Oubangui showed a much higher Qmax/Qmin (~19). Shells correspondingly showed a large δ18Oshell range (amplitude between 2.4 and 5.0‰) for individual Oubangui shells, and lower amplitude for other sites (1.0 to 2.2‰). Thus, shells have a high resolving power to be used to record hydrological variability, since long-term changes in precipitation pattern, discharge, land-use change, or other hydrological changes have an influence on δ18Ow values. Shells with wide range of δ18O values reflect high seasonal variability in rivers, while shells with lower δ18O amplitude correspond to sites with more steady river conditions over the year. Our study illustrates that fossil shell δ18O values could indicate Qmax/Qmin values in ancient African river systems.

Freshwater bivalve shell oxygen and carbon stable isotope ratios (δ18O, δ13C) may act as recorders of hydroclimate (e.g., precipitation-evaporation balance, discharge) and aquatic biogeochemistry. We investigate the potential of these hydroclimate proxies measured along the growth axis of shells collected from the Oubangui River (Bangui, Central African Republic) and the Niger River (Niamey, Niger). Biweekly water samples and in situ measurements collected over several years, along with daily discharge data from both sites allowed a direct comparison with proxies recorded in the shells. Data from a total of 14 unionid shells, including three species (Chambardia wissmanni, Aspatharia dahomeyensis, and Aspatharia chaiziana), confirmed that shells precipitate carbonate in oxygen isotope equilibrium with ambient water. Because water temperature variations were small, shell δ18O values (δ18Oshell) also accurately record the seasonality and the range observed in water δ18O (δ18Ow) values when calculated using an average temperature. Calculated δ18Ow values were in good agreement over the entire record of measured δ18Ow values, thus δ18Oshell records can be reliably used to reconstruct past δ18Ow values. Discharge and δ18Ow values from both rivers fit a logarithmic relationship, which was used to attempt reconstruction of past hydrological conditions, after calculating δ18Ow values from δ18Oshell values. A comparison with measured discharge data suggests that for the two rivers considered, δ18Oshell data are good proxies for recording discharge conditions during low(er) discharge levels, but that high discharge values cannot be accurately reconstructed due to the large scatter in the discharge-δ18Ow relationship. Moreover, periods of bivalve shell growth cessation due to high turbidity or air exposure should be taken into account. While δ13C values of dissolved inorganic carbon in both rivers showed clear seasonality and correlated well with discharge, most of the shells analyzed did not record these variations adequately, likely due to the complication of vital effects including the variable contribution of metabolic CO2. Thus, tropical African unionid δ18Oshell values can be used to reconstruct δ18Ow values with high confidence to provide insight on past hydroclimate such as precipitation-evaporation balance and periods of low discharge.

The Oubangui is a major tributary of the Congo River. We describe the biogeochemistry of contrasting tributaries within its central catchment, with watershed vegetation ranging from wooded savannahs to humid rainforest. Compared to a 2-year monitoring record on the mainstem Oubangui, these tributaries show a wide range of biogeochemical signatures, from highly diluted blackwaters (low turbidity, pH, conductivity and total alkalinity) in rainforests to those more typical for savannah systems. Spectral analyses of chromophoric dissolved organic matter showed wide temporal variations in the Oubangui compared to spatio-temporal variations in the tributaries and confirm that different pools of dissolved organic carbon are mobilized during different hydrological stages. δ13C of dissolved inorganic carbon ranged between −28.1‰ and −5.8‰ and was strongly correlated to both partial pressure of CO2 and to the estimated contribution of carbonate weathering to total alkalinity, suggesting an important control of the weathering regime on CO2 fluxes. All tributaries were oversaturated in dissolved greenhouse gases (CH4, N2O, CO2), with highest levels in rivers draining rainforest. The high diversity observed underscores the importance of sampling that covers the variability in subcatchment characteristics, to improve our understanding of biogeochemical cycling in the Congo Basin.