Low-power visible light can lead to spectacular nonlinear effects in soft-matter systems. The propagation of visible light through transparent solutions of certain polymers can experience either self-focusing or defocusing nonlinearity, depending on the solvent. We show how the self-focusing and defocusing responses can be captured by a nonlinear propagation model using local spatial and time-integrating responses. We realize a remarkable pattern formation in ternary solutions and model it assuming a linear combination of the self-focusing and defocusing nonlinearities in the constituent solvents. This versatile response of solutions to light irradiation may introduce a new approach for self-written waveguides and patterns.

Light induced self-written waveguides (LISWs) with unique elongation characteristics and low optical loss are formed in a monodispersed polyisoprene solution using a low-power laser photopolymerization process, while their light transmission characteristics are exemplified in the flexible interconnection of two single-mode optical fibers operating in the visible/near infrared wavelengths. The LISWs formed exhibit rubbery properties, allowing extensibilities upon cases from 400% to 800%, while still retaining significant optical transmission. The rubber elasticity enables sustaining LISWs at stressed lengths longer than 500 µm propagation losses from 1.0 to 2.9 dB/mm.

There is an increasing demand of spatially denser photonic structures as evidenced by the introduction of multi-core optical fibers, large scale photonics integration and miniaturized optical fiber sensors. As the packaging density increases so does the necessity of waveguide interconnections that are easily realized while being optically functional. A promising interconnection approach comes in the form of self-written waveguides (SWWs) because of their recording process without employing complex beam projection systems. Such waveguide interconnections have been previously demonstrated by using photo-polymerization methods [1] and SWWs have also been used in order to homogenize multimode optical fiber beams [2]. In this work, the connection of two single mode optical fibers by means of a self-written rubbery waveguide is demonstrated, using viscoelastic polymer solutions known to present self-written patterning upon laser irradiation [3].

The formation of permanent structures upon mild red laser illumination in transparent polydiene solutions is examined in the case of gem-dichlorocyclopropanated polybutadiene (gDCC-PB) polymers bearing 15% functional units of the dichlorocyclopropane groups. The response was found to be distinct from the precursor PB. Whereas fiber-like patterns were clearly observed in both precursor and gDCC-PB solutions in cyclohexane, these were absent in the case of gDCC-PB/chloroform but were present in the precursor PB/chloroform solutions. The involved mechanical stresses were not sufficient for the gDCC activation to be detected by NMR spectroscopy. Remarkably, addition of even 10 wt % gDCC-PB into the latter solution sufficed to suppress the light-induced patterning. The importance of the chemical environment on the response to light irradiation was further checked and confirmed by use of other PB copolymers. Different diameter patterns and kinetics were observed. The strong solvent and comonomer mediated effect was reflected neither in solvency nor in optical polarizability differences of the polymers solvent couples.