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1On the Question of Carbonyl Oxide Intermediates in the Oxygen-Transfer by Furan Endoperoxides and Bicyclic Ozonides - Intramolecular Trapping Experiments

W ADAM,A RODRIGUEZ

On heating the furan endoperoxide (2) rearranges into the enol ester (4) and the bicyclic ozonide (3) affords instead the rearranged ozonide (7). The process (2) → (4) represents an intramolecular Baeyer-Villiger rearrangement presumably via the dioxirane (D-2), while the process (3) → (7) represents intramolecular trapping of the carbonyl oxide (C-3).

1981Tetrahedron Letters（1981）引用：37

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2Intramolecular Silyl Migration in the Singlet Oxygenation of 2-Methyl-5-trimethylsilylfuran

W ADAM,A RODRIGUEZ

Tetraphenylporphyrin-sensitized photooxygenation of 2-methyl-5-trimethylsilylfuran (4) affords quantitatively trimethylsilyl 2-oxo-4-pentenoate (5), presumably via intramolecular Baeyer-Villiger rearrangement of the intermediary dioxirane (3a).

1981TETRAHEDRON LETTERS（1981）引用：81

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3ChemInform Abstract: BIS(TRIMETHYLSILYL) MONOPEROXYSULFATE: CONVENIENT BAYER‐VILLIGER OXIDANT

W. ADAM,A. RODRIGUEZ

AbstractAus Bis‐trimethylsilyl‐peroxid (I) erhält man mit Schwefeltrioxid das Persulfat (II), das in Baeyer‐Villiger‐Reaktionen eingesetzt werden kann.

1980Chemischer Informationsdienst引用：25

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4Cyclic Peroxides. 92. Oxygen Atom Transfer by Furan Endoperoxides

A RODRIGUEZ

AbstractDie Furan‐endoperoxide (I)‐(III) (hergestellt durch Photooxidation der entsprechenden Furanderivate in Gegenwart von Tetraphenylporphyrin als Sensibilisator) oxidieren in CFCl3 Tetramethylethylen zum Epoxid und Diphenylsulfid zum Sulfoxid, an.

1980JOURNAL OF THE AMERICAN CHEMICAL SOCIETY（1980）引用：60

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5ChemInform Abstract: CYCLIC PEROXIDE SERIES. 70. A CONVENIENT METHOD FOR THE PREPARATION OF BICYCLIC OZONIDES POSSESSING THE 2,3,7‐TRIOXABICYCLO(2.2.1)HEPTANE STRUCTURE

W. ADAM,H. J. EGGELTE,A. RODRIGUEZ

AbstractFurane (I) w den mit Singlet‐Sauerstoff in Methylenchlorid bei ‐78°C zu Trioxabicycloheptenen (II) umgesetzt, die nach Reduktion mit Diimin als Trioxabicycloheptan (III) isolie werden können.

1979Chemischer Informationsdienst引用：3

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6A Convenient Method for the Preparation of Bicyclic Ozonides Possessing the 2,3,7-Trioxabicyclo[2.2.1]-heptane Structure

W ADAM,HJ EGGELTE,A RODRIGUEZ

1979SYNTHESIS-STUTTGART（1979）引用：15

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7Bis(trimethylsilyl) Monoperoxysulfate: Convenient Bayer-Villiger Oxidant

W ADAM,A RODRIGUEZ

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTBis(trimethylsilyl) monoperoxysulfate: convenient Bayer-Villiger oxidantWaldemar Adam and Augusto RodriguezCite this: J. Org. Chem. 1979, 44, 26, 4969–4970Publication Date (Print):December 1, 1979Publication History Published online1 May 2002Published inissue 1 December 1979https://pubs.acs.org/doi/10.1021/jo00394a048https://doi.org/10.1021/jo00394a048research-articleACS PublicationsRequest reuse permissionsArticle Views342Altmetric-Citations31LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

1979JOURNAL OF ORGANIC CHEMISTRY（1979）引用：37

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8Cyclic Peroxides. 60. Prostanoid Endoperoxide Model Compounds: Preparation of 1,2-Dioxolanes from Cyclopropanes

A BIRKE,C CADIZ,S DIAZ,A RODRIGUEZ

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCyclic peroxides. 60. Prostanoid endoperoxide model compounds: preparation of 1,2-dioxolanes from cyclopropanesWaldemar Adam, Arnoldo Birke, Carlos Cadiz, Simon Diaz, and Augusto RodriguezCite this: J. Org. Chem. 1978, 43, 6, 1154–1158Publication Date (Print):March 1, 1978Publication History Published online1 May 2002Published inissue 1 March 1978https://pubs.acs.org/doi/10.1021/jo00400a028https://doi.org/10.1021/jo00400a028research-articleACS PublicationsRequest reuse permissionsArticle Views207Altmetric-Citations23LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

1978The Journal of Organic Chemistry（1978）引用：30

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