Spectropolarimetric data allow for simultaneous monitoring of stellar chromospheric $\log{R^{\prime}_{\rm{HK}}}$ activity and the surface-averaged longitudinal magnetic field, $B_l$, giving the opportunity to probe the relationship between large-scale stellar magnetic fields and chromospheric manifestations of magnetism. We present $\log{R^{\prime}_{\rm{HK}}}$ and/or $B_l$ measurements for 954 mid-F to mid-M stars derived from spectropolarimetric observations contained within the PolarBase database. Our magnetically active sample complements previous stellar activity surveys that focus on inactive planet-search targets. We find a positive correlation between mean $\log{R^{\prime}_{\rm{HK}}}$ and mean $\log|B_l|$, but for G stars the relationship may undergo a change between $\log{R'_{\rm{HK}}}\sim-4.4$ and $-4.8$. The mean $\log{R^{\prime}_{\rm{HK}}}$ shows a similar change with respect to the $\log{R^{\prime}_{\rm{HK}}}$ variability amplitude for intermediately-active G stars. We also combine our results with archival chromospheric activity data and published observations of large-scale magnetic field geometries derived using Zeeman Doppler Imaging. The chromospheric activity data indicate a slight under-density of late-F to early-K stars with $-4.75\leq\log{R'_{\rm HK}}\leq-4.5$. This is not as prominent as the original Vaughan-Preston gap, and we do not detect similar under-populated regions in the distributions of the mean $|B_l|$, or the $B_l$ and $\log{R'_{\rm HK}}$ variability amplitudes. Chromospheric activity, activity variability and toroidal field strength decrease on the main sequence as rotation slows. For G stars, the disappearance of dominant toroidal fields occurs at a similar chromospheric activity level as the change in the relationships between chromospheric activity, activity variability and mean field strength.