Freshwater systems are impacted by dams, which disrupt river flows, alter sediment dynamics, and store pollutants bound to sediments. Dams constructed in areas influenced by anthropogenic activities trap sediment containing pollutants reflective of the land use within the watershed; these pollutants may become concentrated in sediment due to the impacts of industrialization and urbanization. Analysis of dam sediment and stream sediment grab samples within a watershed can be used to map and identify zones of sediment contamination. We collected sediment from behind eight dams and used publicly available grab sample data from 18 sites to evaluate the distribution of metal contamination in relation to land use in the North Nashua River watershed in Central Massachusetts, USA. Concentrations of eleven metals in sediment were measured and then mapped to identify contamination hotspots. Results indicate high sediment metal concentrations near historical industry and urbanization and lower metal concentrations near forested areas in the watershed. Chromium and Pb had little enrichment, whereas As, Cd, Cu, and Zn had high levels of enrichment in sediment. Hot spot analysis indicated the highest degree of enrichment was near a historic steam hydropower plant and textile mill. Results suggest As enrichment may be due to the historical use of lead arsenate pesticides in agriculture. Overall, results can be used to identify potential zones within a watershed to target when evaluating the impacts of land use on sediment quality.

Coastal Zone Soil Survey mapping provides interpretive information that can be used to increase coastal resiliency and quantify how coastal ecosystems are changing over time. North Carolina has approximately 400,500 ha of land within 500 m of the tidal coastline that is expected to undergo some degree of salinization in the next century. This study examined 33 tidal wetlands in the Albemarle–Pamlico Sound along a salinity gradient to provide a coastal zone mapping framework to quantify shoreline change rates. The primary ecosystems evaluated include intact tidal forested wetlands (average water salinity, 0.15–1.61 ppt), degraded “ghost forest” wetlands (3.51–8.28 ppt), and established mesohaline marshes (11.73–15.47 ppt). The average shoreline rate of change (m/yr) was significantly different among estuary ecosystems (p = 0.004), soil type (organic or mineral) (p < 0.001), and shore fetch category (open or protected) (p < 0.001). From 1984 to 2020, a total of 2833 ha of land has been submerged due to sea level rise in the Albemarle–Pamlico Sound with the majority (91.6%) of this loss coming from tidal marsh and ghost forest ecosystems. The results from this study highlight the importance of maintaining healthy coastal forests, which have higher net accretion rates compared to other estuarine ecosystems.

Urbanization changes land cover through the expansion of impermeable surfaces, leading to a significant rise in runoff, sediment, and nutrient loading. The quality of stormwater is related to land use and is highly variable. Currently, stormwater is predominantly described through watershed models that rely minimally, if at all, on field monitoring data. The simple event mean concentration (EMC) wash-off approach by land use is a common method for estimating urban runoff loads. However, a major drawback of the EMC approach is it assumes concentration remains constant across events for a specific land use. Build-up/wash-off equations have been formulated to consider variations in concentration between events. However, several equation parameters are challenging to estimate, making them difficult to use. We conducted a monitoring and modeling study and investigated the impact of land use on stormwater quantity and quality and optimized and investigated the build-up/wash-off parameters for three homogenous urban land uses to estimate nutrients (nitrogen and phosphorus) and sediment loads. Stormwater from commercial, medium-density residential, and transportation land uses was sampled using automatic samplers during storm events, and water quality was characterized for a variety of them for 14 months. Analysis of stormwater samples included assessments for total nitrogen, total phosphorus, and total suspended solids. Results showed that medium-density residential land use had the highest median total nitrogen and total phosphorus event mean concentrations and commercial had the highest median total suspended solids EMCs. Water quality parameters (or build-up/wash-off parameters) exhibited significant variation between land uses, confirming that land use is a key determinant of stormwater quality. The median particle size for each land use was less than 150 μm, indicating that the most common particle size in stormwater was a very fine sand or smaller. This small size should be considered by stakeholders in the design of stormwater treatment systems.

Coal fly ash is an industrial waste product generated by coal fired powerplants which has been shown to contain elevated concentrations of several toxic trace metals. When stored in landfills or other repositories, these trace metals can enter nearby surface waters via a number of routes including leaching or runoff. Our study examined 1) the presence and concentration of eleven trace elements in a range of lab-created coal ash leachate solutions at neutral pH using ICP-OES, 2) the physiological effects of these leachate solutions on a freshwater gastropod (Planorbella duryi), and 3) the ability of these trace metals to bioaccumulate in the tissues of exposed individuals. As, Cd, Cu, Mg, Mn, and Pb were detected in solutions at increasing concentrations concurrent with ash concentration. Exposure to leachates caused significant delays in embryonic development, reduced juvenile shell growth, decreases in egg and clutch production, and the display of avoidance behaviors. Tissues of exposed snails contained elevated concentrations of As, Cd, Cu, and Cr, with bioconcentration factors 177,550 times higher in cadmium and 85,468 times higher in arsenic in the highest treatment compared to control organisms. Our results highlight the potential harmful effects of coal ash leachates on a novel freshwater invertebrate species using several unique methodologies, providing key information regarding their potential impacts on surrounding aquatic ecosystems.

Coal ash (CA) is an industrial waste product that has been shown to contain several neurotoxic constituents such as cadmium, selenium, mercury, lead, and arsenic. Contaminant-laced leachates enter the environment via seepage, runoff, permitted discharge, or accidental spills from CA storage ponds or landfills which may pose a risk to wildlife residing in receiving waterways. In this study, we assessed 1) the presence and concentration of thirteen trace elements (Al, Ca, Mg, Cr, Cd, As, Se, Pb, Cu, Zn, Mn, Fe, B) in surface water and sediment grab samples using ICP-OES, 2) the temporal variability of trace elements using Pb-210 dated sediment core samples, 3) differences in species diversity using environmental DNA (eDNA) analyses, and 4) the presence and con-centration of trace metals in banded killifish (Fundulus diaphanus) epaxial muscle tissue collected from waterways surrounding the Possum Point Power Station (Stafford, VA). Results showed the highest concentrations of As, Cd, Cr, Cu, Fe, Mg, Se, Zn, and B in Quantico Creek (QC) adjacent to the coal ash ponds and elevated average cadmium and zinc concentrations compared to both upstream and downstream locations along the Potomac River. Sediment core profiles and Pb-210 analyses showed historical enrichment of several trace elements in QC beginning after the commissioning of the power plant in 1948. When compared to upstream and downstream sites, species diversity was drastically reduced in Quantico Creek based on eDNA identification. Muscle tissues of banded killifish collected in Quantico Creek displayed increased Al, Cd, and Zn concentrations compared to upstream and downstream sites. Collectively, our results demonstrate the potential impacts of coal ash landfills on aquatic ecosystems and suggest that further research is needed to fully inform risk assessment and remedi-ation efforts.

In this study, the acute impacts of aqueous methoxychlor exposure on the viability, locomotive behavior, and heartrate of Daphnia magna was assessed. Adults were exposed to 0 (ethanol control), 1, 2.5, 5, or 10 mu g/L of methoxychlor for 48 hr using a static exposure assay. After 24 hr mobility was quantified using automated behavioral analysis software and differences in mortality and heartrate assessed after 24 and 48 hr. Exposure caused an increase in mortality after 48 hr, with effects seen in as little as 24 hr in the 10 mu g/L treatment. Decreases in speed, total distance traveled, and frozen events were observed after 24 hr. Heartrate in the 10 mu g/L treatment was depressed after 24 hr, with decreases in the 2.5 and 5 mu g/L treatments observed after 48 hr. These results provide an expanded understanding of the impacts of a well-established legacy organochlorine pesticide on a model invertebrate.

Decline in global surface water quality around the world is closely linked to excess sediment and nutrient inputs. This study examined sediment and phosphorus fluxes in Aquia Creek, a fourth-order sub-watershed of the Chesapeake Bay located in Stafford, Virginia. The Revised Universal Soil Loss Equation (RUSLE), sediment delivery ratio (SDR), field sediment traps, bank erosion pins, and LIDAR data, combined with historical aerial images, were used in quantifying rill and inter-rill erosion from the basin, as well as internally generated sediments. Stream water and stream bank soils were analyzed for phosphorus. RUSLE/SDR modeling estimates a basin total sediment flux of 25,247 tons year−1. The greatest calculated soil losses were in deciduous forests and cropland areas, whereas medium and high-intensity developed areas had the least soil loss. Cut-bank erosion ranged from 0.2 to 27.4 cm year−1, and annual bank sediment fluxes were estimated at 1444 Mg, with a corresponding annual mass of phosphorous of 13,760 kg year−1. The highest bank loss estimates were incurred along reaches draining urban areas. Stream water total phosphorous levels ranged from 0.054 μg g−1 during low flows to 134.94 μg g−1 during high discharge periods in autumn and spring. These results show that stormwater management practices in urban areas are limiting runoff water and soil contact, reducing surficial soil loss. However, the runoff acceleration due to expansion of impervious surfaces is progressively increasing the significance of intrinsic sediment and phosphorous sources by exacerbating stream bank erosion and resuspension of internally stored sediments.

Increasing anthropogenic alteration has resulted in increased exposure to both point and nonpoint source pollution. These exposures are increasingly studied for their role in human diseases, including diseases with known genetic or lifestyle risk factors. This study analyzed associations between a variety of human diseases and trace metals, PCBs, and PAHs in soil, groundwater, sediment, and fish. Contaminant spatial data at the county level from Virginia were used in ArcGIS to identify these associations among socially vulnerable populations. The neurologic and psychiatric disorders and cognitive markers were associated with numerous metals in groundwater/soil and/or aquatic system contaminants. Cancer death rates, fetal deaths, and infant deaths were also related to multiple environmental exposures from both categories of exposure. In contrast, many of the chronic diseases which are primarily attributed to lifestyle showed little association with these exposures with the exception of COPD which did appear to be associated with multiple metal exposures. Asthma showed similar associations compared to COPD. Our data suggest that within the context of socially vulnerable populations, where disease burden is often highest, exposures to metals, PAHs, and PCBs may play a role in the development or exacerbation of several highly prevalent categories of disease. These environmental exposures likely act through a variety of pathways all generally leading to increased oxidative stress, inflammation, or interference with biological systems and a subsequent role in disease development.

The progressively declining ecological condition of the Chesapeake Bay is attributed to the influx of contaminants associated with sediment loads supplied by its largest tributaries. The continued urban expansion in the suburbs of Virginia cities, modern agricultural activities in the Shenandoah Valley, the anthropogenic and climate driven changes in fluvial system hydrodynamics and their potential associated impacts on trace metals enrichment in the bay's tributaries necessitate constant environmental monitoring of these important water bodies. Eight (210)Pb and (137)Cs dated sediment cores and seventy two sediment grab samples were used to analyze the spatial and temporal distributions of Al, Ca, Mg, Cr, Cd, As, Se, Pb, Cu, Zn, Mn, and Fe in the waterways of the Virginia portion of the Chesapeake Bay basin. The sediment cores for trace metal historical fluctuation analysis were obtained in lower fluvial-estuarine environments and reservoirs in the upper reaches of the basin. The trace metal profiles revealed high basal enrichment factors (EF) of between 0.05 and 40.24, which are interpreted to represent early nineteenth century agricultural activity and primary resource extraction. Surficial enrichment factors on both cores and surface grab samples ranged from 0.01 (Cu) to 1421 (Cd), with Pb, Cu, Zn, and Cd enrichments a plausible consequence of modern urban expansion and industrial development along major transportation corridors. Contemporary surficial enrichments of As, Se, and Cr also ranged between 0 and 137, with the higher values likely influenced by lithological and atmospheric sources. Pearson correlation analyses suggest mining and agricultural legacies, coupled with aerosol deposition, are responsible for high metal concentrations in western lakes and headwater reaches of fluvial systems, while metal accumulation in estuarine reaches of the major rivers can be attributed to urban effluence and the remobilization of legacy sediments.

Aquatic ecosystems are known to undergo fluctuations in nutrient levels as a result of both natural and anthropogenic processes. Changes in both extrinsic and intrinsic fluvial dynamics necessitate constant monitoring as anthropogenic alterations exert new pressures to previously stable river basins. In this study, we analyzed stream water and riparian zone soil phosphorous (P) dynamics in two third-order sub-watersheds of the lower Chesapeake Bay in Virginia, USA. The Ni River is predominantly forested (70 % forested), and Sugarland Run is a more human impacted (>45 % impervious surfaces) sub-watershed located in the suburbs of Washington D.C. Total stream P concentrations were measured during both high and low flows and Mehlich-3 methods were used to evaluate potential P fluxes in riparian soils. The results show total stream P concentrations in Sugarland Run ranged from 0.002 to 0.20 ppm, with an average of 0.054 ppm. In contrast, the forested Ni River had typical stream P concentrations <0.01 ppm. Total soil P was significantly higher in the more urbanized Sugarland Run basin (23.8 ± 2.1 ppm) compared to the Ni River basin (16 ± 3.7 ppm). Average stream bank erosion rates and corresponding cut-bank P flux rates were estimated to be 7.98 cm year−1 and 361 kg P year−1 for Ni River and 9.84 cm year−1 and 11,600 kg P year−1 for Sugarland Run, respectively. The significantly higher values of total P in the stream water and floodplain cut-banks of Sugarland Run suggests erosion and resuspension of previously deposited legacy sediments is an important processes in this human-impacted basin.

Watershed sediment fluxes and reservoir sediment accumulation rates were analyzed in two contrasting reservoir systems in central and western Virginia. Lake Pelham, located in the Piedmont geologic province, is a human-impacted reservoir with a watershed dominated by agricultural, residential and industrial land uses. Conversely, Lake Moomaw has a largely undeveloped watershed characterized by very steep slopes and forested land use located in the Valley and Ridge province. The Revised Universal Soil Loss Equation (RUSLE) and sediment delivery ratios (SDRs) were used to estimate soil losses in the two watersheds. Bathymetric and sediment accumulation surveys of the two reservoirs were also conducted using a multi-frequency hydroacoustic surveying system. The RUSLE/SDR erosion model estimates 2150 kg ha−1 year−1 for Lake Pelham and 2720 kg ha−1 year−1 for Lake Moomaw, a 410 and 13 % increase from assumed pristine (100 % forested) land use for the respective basins. Mean sediment accumulation rates of 1.51 and 0.60 cm year−1 were estimated from the hydroacoustic survey of Lake Pelham and Lake Moomaw, respectively. Overall, Lake Moomaw has relatively low sediment accumulation rates; however, the reservoir is vulnerable to increases in sediment fluxes with further human development due to the steep slopes and highly erodible colluvial soils that characterize the basin. Higher erosion and sediment accumulation rates in Lake Pelham are most likely reflecting the impact of human development on sedimentation processes, where the loss of vegetal buffers and increase in impervious surfaces exacerbates both the surficial soil losses as well as intrinsic stream sediment production leading to the current annual reservoir capacity loss of 0.4 %.

Anthropogenic forces that alter the physical landscape are known to cause significant soil erosion, which has negative impact on surface water bodies, such as rivers, lakes/reservoirs, and coastal zones, and thus sediment control has become one of the central aspects of catchment management planning. The revised universal soil loss equation empirical model, erosion pins, and isotopic sediment core analyses were used to evaluate watershed erosion, stream bank erosion, and reservoir sediment accumulation rates for Ni Reservoir, in central Virginia. Land-use and land cover seems to be dominant control in watershed soil erosion, with barren land and human-disturbed areas contributing the most sediment, and forest and herbaceous areas contributing the least. Results show a 7 % increase in human development from 2001 (14 %) to 2009 (21.6 %), corresponding to an increase in soil loss of 0.82 Mg ha(-1) year(-1) in the same time period. (210)Pb-based sediment accumulation rates at three locations in Ni Reservoir were 1.020, 0.364, and 0.543 g cm(-2) year(-1) respectively, indicating that sediment accumulation and distribution in the reservoir is influenced by reservoir configuration and significant contributions from bedload. All three locations indicate an increase in modern sediment accumulation rates. Erosion pin results show variability in stream bank erosion with values ranging from 4.7 to 11.3 cm year(-1). These results indicate that urban growth and the decline in vegetative cover has increased sediment fluxes from the watershed and poses a significant threat to the long-term sustainability of the Ni Reservoir as urbanization continues to increase.