AbstractThe o‐iodosobenzoic acids (I) and (III) are prepared by oxidative chlorination of the corresponding o‐iodo compounds, while the o‐iodoxybenzoic acids (II) and (IV) are obtained from the same starting materials by oxidation with H2O2/Ac2O. The o‐iodoxybenzoic acids (VII) and (X) are synthesized from the benzoic ester (V).

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCatalytic hydrolysis of phosphate esters in microemulsions. 4. p-Nitrophenyl diphenyl phosphate hydrolysis catalyzed by iodosobenzoate and some of its derivativesBeth A. Burnside, Barry L. Knier, Raymond A. Mackay, H. Dupont Durst, and Frederick R. LongoCite this: J. Phys. Chem. 1988, 92, 15, 4505–4510Publication Date (Print):July 1, 1988Publication History Published online1 May 2002Published inissue 1 July 1988https://doi.org/10.1021/j100326a050RIGHTS & PERMISSIONSArticle Views103Altmetric-Citations15LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (3 MB) Get e-Alerts

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTCatalytic hydrolysis of phosphate esters in microemulsions. 3. Analysis of the hydrolysis products of p-nitrophenyl diphenyl phosphate via 31P NMRBeth A. Burnside, Linda L. Szafraniec, Barry L. Knier, H. Dupont Durst, Raymond A. Mackay, and F. R. LongoCite this: J. Org. Chem. 1988, 53, 9, 2009–2011Publication Date (Print):April 1, 1988Publication History Published online1 May 2002Published inissue 1 April 1988https://pubs.acs.org/doi/10.1021/jo00244a030https://doi.org/10.1021/jo00244a030research-articleACS PublicationsRequest reuse permissionsArticle Views297Altmetric-Citations19LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTSubstituted o-iodoso- and o-iodoxybenzoic acids. Synthesis and catalytic activity in the hydrolysis of active phosphorus esters and related systemsAlan R. Katritzky, Bradley L. Duell, H. Dupont Durst, and Barry L. KnierCite this: J. Org. Chem. 1988, 53, 17, 3972–3978Publication Date (Print):August 1, 1988Publication History Published online1 May 2002Published inissue 1 August 1988https://pubs.acs.org/doi/10.1021/jo00252a017https://doi.org/10.1021/jo00252a017research-articleACS PublicationsRequest reuse permissionsArticle Views564Altmetric-Citations51LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-AlertscloseSupporting Info (1)»Supporting Information Supporting Information Get e-Alerts

We have continued our kinetics investigation of the iodosobenzoate (IBA) catalysis of the hydrolysis of p-nitrophenyl diphenyl phosphate (PNDP), in microemulsion media composed of hexadecane in water stabilized by cetyltrimethylammonium bromide and 1-butanol over a range of water mass fractions. We have examined two iodosobenzoic acid derivatives (5-nitro-2-iodosobenzoic acid and 5-octyloxy-2-iodosobenzoic acid) as catalysts. In addition, we have determined by31P FT-NMR techniques that the major product of the hydrolysis of PNDP, both in IBA catalyzed and in uncatalyzed media, is diphenylphosphate.

ChemInformVolume 19, Issue 37 Organoelement Compounds ChemInform Abstract: Catalytic Hydrolysis of Phosphate Esters in Microemulsions. Part 3. Analysis of the Hydrolysis Products of p-Nitrophenyl Diphenyl Phosphate via 31P-NMR. B. A. BURNSIDE, B. A. BURNSIDE Chem. Res. Dev. Eng. Center, Aberdeen Proving Ground, MD 21010-5423, USASearch for more papers by this authorL. L. SZAFRANIEC, L. L. SZAFRANIEC Chem. Res. Dev. Eng. Center, Aberdeen Proving Ground, MD 21010-5423, USASearch for more papers by this authorB. L. KNIER, B. L. KNIER Chem. Res. Dev. Eng. Center, Aberdeen Proving Ground, MD 21010-5423, USASearch for more papers by this authorH. D. DURST, H. D. DURST Chem. Res. Dev. Eng. Center, Aberdeen Proving Ground, MD 21010-5423, USASearch for more papers by this authorR. A. MACKAY, R. A. MACKAY Chem. Res. Dev. Eng. Center, Aberdeen Proving Ground, MD 21010-5423, USASearch for more papers by this authorF. R. LONGO, F. R. LONGO Chem. Res. Dev. Eng. Center, Aberdeen Proving Ground, MD 21010-5423, USASearch for more papers by this author B. A. BURNSIDE, B. A. BURNSIDE Chem. Res. Dev. Eng. Center, Aberdeen Proving Ground, MD 21010-5423, USASearch for more papers by this authorL. L. SZAFRANIEC, L. L. SZAFRANIEC Chem. Res. Dev. Eng. Center, Aberdeen Proving Ground, MD 21010-5423, USASearch for more papers by this authorB. L. KNIER, B. L. KNIER Chem. Res. Dev. Eng. Center, Aberdeen Proving Ground, MD 21010-5423, USASearch for more papers by this authorH. D. DURST, H. D. DURST Chem. Res. Dev. Eng. Center, Aberdeen Proving Ground, MD 21010-5423, USASearch for more papers by this authorR. A. MACKAY, R. A. MACKAY Chem. Res. Dev. Eng. Center, Aberdeen Proving Ground, MD 21010-5423, USASearch for more papers by this authorF. R. LONGO, F. R. LONGO Chem. Res. Dev. Eng. Center, Aberdeen Proving Ground, MD 21010-5423, USASearch for more papers by this author First published: September 13, 1988 https://doi.org/10.1002/chin.198837260AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat No abstract is available for this article. Volume19, Issue37September 13, 1988 RelatedInformation

AbstractDie Titelreaktion der Ionen (I) mit Nucleophilen (Nu) wie z.B. 1,1‐Dimethyl‐ethylendiamin, 2‐Cyan‐ethylamin, Propylamin, CH3COO‐ und HO‐ verlaufen als Reaktionen 2. Ordnung mit Geschwindigkeitskonstanten von (1.95‐184)·10‐5/M·s zu den Substitutionsprodukten (II) und den Anilinen (III).

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMechanism of reactions of N-(methoxymethyl)-N,N-dimethylanilinium ions with nucleophilic reagentsBarry L. Knier and William P. JencksCite this: J. Am. Chem. Soc. 1980, 102, 22, 6789–6798Publication Date (Print):October 15, 1980Publication History Published online1 May 2002Published inissue 15 October 1980https://pubs.acs.org/doi/10.1021/ja00542a021https://doi.org/10.1021/ja00542a021research-articleACS PublicationsRequest reuse permissionsArticle Views481Altmetric-Citations75LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts