The morphology of the hitherto unknown female of Somatochlora borisi is described and illustrated basing upon eight adults from Bulgaria, Greece and Turkey.A key is provided which allows the determination of the females of all West Palaearctic Cordulia and Somatochlora spp.A list of the presently known localities and a distribution map show the range of the species as currently known.The species is new to Turkey.
The reaction of allene (3a) and alkyl substituted allenes 1,2-hexadiene (3b), cyclopropylallene (3c), and vinylidene cyclopropane (3d) with lithium metal was investigated in order to access 2,3-dilithioalkenes 4a–d. These dilithioalkenes 4a–d are very reactive in polar solvents like THF and act as strong bases, either metalation of the starting allene 3a–d, the solvent, or sufficiently acidic intermediates like 8 a–d is observed. The metalation products 5–7 show follow-up reactions like 1,3-H shift to the corresponding 1-lithio-1-alkynes 8 and subsequent metalation to the dilithioalkynes 9. Additionally, lithium hydride elimination and ring-chain rearrangement (for 5c) are observed. 1,2-Hexadiene (3b) can be brought to reaction with lithium metal in the apolar solvent pentane, here the follow-up reactions are much slower due to the insolubility of 4b. In all cases the elucidation of the reaction pathways is hampered by the formation of complex mixtures of, amongst others, regio- and stereoisomeric products upon quenching with simple electrophiles.
The product of the reaction of ethylene with lithium in 1,4-dioxane as described in the literature, is not 1,2-dilithioethane but dilithioacetylene. The reaction can be performed also in 1,2- dimethoxyethane but not in tetrahydrofuran. In the latter solvent, in the presence of catalysts, the reaction is known to stop at the vinyllithium intermediate.