Observing the interplay between material conductivity, cohesion and density for electrostatic liquid marble formation using metal-shell polymer particles.

Recovering fine valuable material has been a significant challenge in minerals processing. This primarily stems from insufficient collision opportunities between fine particles and bubbles, specifically when utilising traditional recovery methods such as froth flotation. This research endeavours to address this challenge by exploring the use of various commercially available, high molecular weight polymers- specifically polyacrylamide (PAM)to selectively aggregate hematite from quartz. Investigation of the conditions in which selective aggregation of hematite over quartz occurs, with the goal to achieve aggregate sizes of between 20 and 150 mu m, were undertaken. Targeting this size range ensure that conditions are optimised for future use in conventional mechanical flotation cells as an efficient mineral recovery method. The study investigates the selectivity of charged PAM towards hematite and quartz at pH 10, using adsorption studies. Anionic PAM demonstrates a preference for hematite, with a range of charge density studies, highlighting stronger adsorption capacity with lower charge density polymers. Using BlazeMetrics probe technology for in-situ sizing and imaging, it was observed that conditioning 50-300 g APAM per t of hematite resulted in aggregates in the range of 30-230 mu m after 5 min. Interestingly, the charge density of APAM does not markedly affect the size of the hematite aggregates, although altering the charge density of the polymer impacts the selectivity towards quartz. Additionally, cationic PAM results in the simultaneous aggregation of both hematite and quartz, not demonstrating selectivity. To mitigate heterocoagulation between minerals, a common dispersant, sodium hexametaphosphate (SHMP), was employed, which notably prevents quartz aggregation. Separation of aggregated hematite from quartz by sedimentation was only slightly effective with the majority of quartz settling with the hematite. Adding up to 1000 g of dispersant per t of hematite reduced the amount of quartz in the sediment bed by 23 %. The dispersant increased the magnitude of the negative zeta potential of the two minerals, particularly hematite, lowering heterocoagulation and improving effectiveness of hematite flocculation.

Selective aggregation can be used to improve the collection of fine valuable mineral particles often lost in industrial separation processes. This approach might be applicable to flocculate fine copper mineral particles such as chalcopyrite. It is hypothesised that the polymeric flocculant charge type will influence selectivity between chalcopyrite and waste minerals. This work investigates the use of charged anionic (APAM) and cationic (CPAM) polyacrylamides to selectively aggregate negatively charged chalcopyrite from its common waste (quartz). The interaction of the polymers with the mineral's surfaces as well as its flocculation capability were investigated through adsorption isotherms, turbidity tests, and in-situ aggregate size measurement. Furthermore, the ability to selectively aggregate and recover the valuable chalcopyrite from a quartz mixture by sedimentation was assessed. The results indicated that both charged polymers can be used to aggregate fine chalcopyrite particles, however, CPAM is non-selective towards the valuable mineral, as it also aggregates quartz. CPAM has a stronger affinity for both minerals, probably due to charge-charge interaction adsorption mechanisms, whereas APAM adsorption was lower, and more likely to be driven by hydrogen bonding. The interaction of APAM with quartz was limited probably because its highly negatively charged surface tends to repel the anionic polymer. Finally, the recovery of the chalcopyrite by sedimentation separation improved when using both polymers, but higher recoveries were obtained when using APAM.

We report an unusually large spacing observed between microparticles after delivery to the surface of a pendent water droplet using a DC nonuniform electrostatic field, primarily via dielectrophoresis. The influence of particle properties was investigated using core particles, which were either coated or surface-modified to alter their wettability and conductivity. Particles that exhibited this spacing were both hydrophobic and possessed some dielectric material exposed to the external field, such as a coating or exposed dielectric core. The origin of this behavior is proposed to be the induced dipole-dipole repulsion between particles, which increases with particle size and decreases when the magnitude of the electric field is reduced. When the particles were no longer subjected to an external field, this large interparticle repulsion ceased and the particles settled to the bottom of the droplet under the force of gravity. We derive a simple model to predict this spacing, with the dipole-dipole repulsion balanced against particle weight. The external electric field was calculated using the existing electric field models. The spacing was found to be dependent on particle density and the induced dipole moment as well as the number of particles present on the droplet interface. As the number of particles increased, a decrease in interparticle spacing was observed.

The interactions between particles and the role of their physical properties are not well understood for the electrostatic formation of liquid marbles. Here we focus initially on the impact of increasing particle diameter (notionally 20 to 140 μm) on the ease of particle extraction from an advancing bed of charged particles beneath an earthed, suspended water droplet. A larger particle diameter increased the ease of extraction, due to decreased interparticle cohesion, with increased potential applied to the particle bed. Whilst particle extraction is a crucial step in liquid marble formation, transport to the droplet and subsequent coating and stabilisation of the liquid is also significant. Further investigation highlighted that the smaller particle diameters afforded increased liquid stabilisation due to increased coverage and smaller interstitial spaces between particles on the liquid surface. Optimal conditions for controllable liquid marble formation using electrostatics was postulated as a trade-off between drop-bed separation distance, applied potential and kinetics of coating when studying impact of particle size. Furthermore, preliminary modelling, utilising weakest-link statistics and fracture mechanics, of the experimental data was undertaken to focus on development of the relationship between particle properties and extractability in the presence of electrostatics. This model represents a step towards predicting the suitability of particles for use in the electrostatic formation of liquid marbles prior to undertaking experimental work.

Hypothesis: Particle cohesion and conductivity affects the electrostatically driven transport of particles to a suspended water droplet. The conditions at which liquid marbles and particle stabilised liquid droplets form are a function of these parameters. Experiment: Particle beds placed below an earthed pendent water drop had a negative potential applied, thus inducing an opposing positive charge on the liquid, which results in particle transfer and eventual coating of the liquid drop. Experiments where both the particle bed was constantly moved slowly toward the droplet, and the particle bed remained at a fixed, small separation distance were completed. These enabled the investigation of a number of variables that influence successful aggregate formation, including separation distance between the droplet and particle bed, coating mechanism and kinetics of the transfer process. Findings: Monodisperse polystyrene core particles with polypyrrole shells of various cohesiveness and conductivity were observed to behave differently in the presence of the applied potential, where the least cohesive and conductive sample (polystyrene) required the smallest separation distance, i.e. the greatest field strength for particle transfer. Increasing conductivity of the particle shell decreases the field strength required for particle transfer, and thus an increase was observed in separation distance at which particles were observed to move to the air-water interface. The transfer kinetics followed the same trend where the least conductive and cohesive sample was the slowest to coat the air-water interface, and vice-versa. Since an increase in cohesion hinders particle transfer, it is concluded that particle conductivity is of greater importance in the electrostatic aggregation process. (C) 2018 Elsevier Inc. All rights reserved.

Liquid marbles, or small liquid droplets stabilised by hydrophobic particles, have been used in a wide variety of applications including cosmetics, gas sensing and microfluidics. Interest in the commercial and research areas have increased significantly recently to diversify both gas and liquid phases and improve the formation process. Currently, liquid marbles are generally formed by rolling the liquid droplet over a bed of particles, resulting in attachment at the interface. An alternate, non-contact method of liquid marble production, using electrostatic transfer of particles to a pendent drop has been developed within our group. Removing the requirement of direct contact for liquid marble production has allowed for the investigation of a larger range of particles, including polymer latexes with lower contact angles, resulting in the formation of non-spherical shaped liquid aggregates. This study investigates the impact of changing various liquid phase characteristics, including conductivity (NaCl), viscosity (glycerol) and surface tension (ethanol) on the formation of liquid marbles using hydrophobic polystyrene core-shell particles. The observation of the electrostatic transfer of particles at certain applied potentials to the droplet interface is studied as a function of bed-droplet separation. Furthermore, the kinetics and charge transfer were also investigated to assess the impact of the liquids on these mechanisms. Overall surface tension of the ethanol mixture (20 wt%) was too low for consistent liquid marble formation. Increasing viscosity and conductivity did not appear to alter the separation distances at which particles were initially transferred, but charge transfer and kinetic mechanisms were variable between tap water, glycerol and sodium chloride solutions.