We report the results of simulations of rigid colloidal helices suspended in a shear flow, using dissipative particle dynamics for a coarse-grained representation of the suspending fluid, as well as deterministic trajectories of non-Brownian helices calculated from the resistance tensor derived under the slender-body approximation. The shear flow produces nonuniform rotation of the helices, similarly to other high aspect ratio particles, such that more elongated helices spend more time aligned with the fluid velocity. We introduce a geometric effective aspect ratio calculated directly from the helix geometry and a dynamical effective aspect ratio derived from the trajectories of the particles and find that the two effective aspect ratios are approximately equal over the entire parameter range tested. We also describe observed transient deflections of the helical axis into the vorticity direction that can occur when the helix is rotating through the gradient direction and that depend on the rotation of the helix about its axis.
We report the results of simulations of suspensions of sheared rigid rods in the presence of strong attractive inter-particle interactions, using dissipative particle dynamics for a coarse-grained representation of the suspending fluid. We find that the combined effect of the attractive interactions and shear-induced alignment generically produces aggregates of aligned bundles when the contact points between rods are free to rotate. However, the introduction of substantial torsional stiffness to the inter-particle contacts recapitulates the disordered aggregates often observed in suspensions of high aspect ratio particles. We show that the degree of alignment within the aggregates depends on the strength of the torsional stiffness, while the stability of the aggregates and their impact on system viscosity depend on the competition between the attractive interaction and the shear stresses.
Equilibrium statistical mechanics allows the prediction of collective behaviors of large numbers of interacting objects from just a few system-wide properties; however, a similar theory does not exist for far-from-equilibrium systems exhibiting complex spatial and temporal behavior. We propose a method for predicting behaviors in a broad class of such systems and apply these ideas to an archetypal example, the spatiotemporal chaotic 1D complex Ginzburg-Landau equation in the defect chaos regime. Building on the ideas of Ruelle and of Cross and Hohenberg that a spatiotemporal chaotic system can be considered a collection of weakly interacting dynamical units of a characteristic size, the chaotic length scale, we identify underlying, mesoscale, chaotic units and effective interaction potentials between them. We find that the resulting equilibrium Takahashi model accurately predicts distributions of particle numbers. These results suggest the intriguing possibility that a class of far-from-equilibrium systems may be well described at coarse-grained scales by the well-established theory of equilibrium statistical mechanics.
We study the three-body systems of He-3 and pd scattering and demonstrate, both analytically and numerically, that a new pd three-body force is needed at next-to-leading order in pionless effective field theory. We also show that at leading order these observables require no new three-body force beyond what is necessary to describe nd scattering. We include electromagnetic effects by iterating only diagrams that involve a single photon exchange in the three-body sector.
Free-flowing granular media can quickly become jammed above a critical density. Nonlinear dynamical systems analysis now suggests that jamming arises from the interaction between the density of instabilities and the propagation of disturbances throughout the material. Granular materials are collections of discrete, macroscopic particles characterized by relatively straightforward interactions. Despite their apparent simplicity, these systems exhibit a number of intriguing phenomena, including the jamming transition, in which a disordered collection of grains becomes rigid when its density exceeds a critical value1,2. Many aspects of this transition have been explored, but an explanation of the underlying dynamical mechanisms for the transition remains elusive. Here, applying nonlinear dynamical techniques3,4,5 to simulated two-dimensional Couette shear cells6,7,8, we reveal the mechanisms of jamming and find that they conflict with the prevailing picture of growing cooperative regions. In addition, at the density corresponding to random close packing9,10, we find a dynamical transition from chaotic to non-chaotic states accompanied by diverging dynamical length- and timescales. Furthermore, we find that the dominant cooperative dynamical modes are strongly correlated with particle rearrangements and become increasingly unstable before stress jumps, providing a way to predict the times and locations of these striking stress-release events in our simulations.
We demonstrate the effect of the depletion force in experiments and simulations of vertically vibrated mixtures of large and small steel spheres. The system exhibits size segregation and a large increase in the pair correlation function of the large spheres for short distances that can be accurately described using a combination of the depletion potential derived for equilibrium colloidal systems and a Boltzmann factor. The Boltzmann factor defines an effective temperature for the system, which we compare to other measures of temperature.
We describe a series of experiments and computer simulations on vibrated granular media in a geometry chosen to eliminate gravitationally induced settling. The system consists of a collection of identical spherical particles on a horizontal plate vibrating vertically, with or without a confining lid. Previously reported results are reviewed, including the observation of homogeneous, disordered liquid-like states, an instability to a 'collapse' of motionless spheres on a perfect hexagonal lattice, and a fluctuating, hexagonally ordered state. In the presence of a confining lid we see a variety of solid phases at high densities and relatively high vibration amplitudes, several of which are reported for the first time in this article. The phase behaviour of the system is closely related to that observed in confined hard-sphere colloidal suspensions in equilibrium, but with modifications due to the effects of the forcing and dissipation. We also review measurements of velocity distributions, which range from Maxwellian to strongly non-Maxwellian depending on the experimental parameter values. We describe measurements of spatial velocity correlations that show a clear dependence on the mechanism of energy injection. We also report new measurements of the velocity autocorrelation function in the granular layer and show that increased inelasticity leads to enhanced particle self-diffusion.
We report the observation of the homogenous nucleation of crystals in a dense layer of steel spheres confined between two horizontal plates vibrated vertically. Above a critical vibration amplitude, two-layer crystals with square symmetry were found to coexist in steady state with a surrounding granular liquid. By analogy to equilibrium hard-sphere systems, the phase behavior may be explained through entropy maximization. However, dramatic nonequilibrium effects are present, including a significant difference in the granular temperatures of the two phases.