The synthesis is described of a 2-chloro-6,9-dihydro-5,9-methanobenzo[7]annulen-10(5H)-one 4 and the corresponding 8,9-dihydro-5,8-methano[7]annulen-10(5H)-one analogue 5 which are converted into amine derivatives 2 and 3.
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C 13 H 15 ClN + •Cl − •1.5H 2 O cristallise dans le systeme triclinique, groupe d'espace P1 et sa structure est affinee jusqu'a R=0,051. Il y a deux cations independants dans l'unite asymetrique, avec des dimensions tres similaires