A broad study of zircons from plutonic rocks of the Sawatch and Mosquito ranges of west-central Colorado (U.S.A.) was undertaken to significantly refine the magmatic chronology and chemistry of this under-studied region of the Colorado province. This region was chosen because it lies just to the north of the suspected arc-related Gunnison-Salida volcano-plutonic terrane, which has been the subject of many recent investigations—and whose origin is still debated. Our new results provide important insights into the processes active during Proterozoic crustal evolution in this region, and they have important ramifications for broader-scope crustal evolution models for southwestern North America. Twenty-four new U-Pb ages and sequentially acquired rare-earth element (REE), U, Th, and Hf contents of zircon have been determined using the sensitive high-resolution ion microprobe-reverse geometry (SHRIMP-RG). These zircon geochemistry data, in conjunction with whole-rock major- and trace-element data, provide important insights into zircon crystallization and melt fractionation, and they help to further constrain the tectonic environment of magma generation. Our detailed zircon and whole-rock data support the following three interpretations: (1) The Roosevelt Granite in the southern Sawatch Range was the oldest rock dated at 1,766 ± 7 Ma, and it intruded various metavolcanic and metasedimentary rocks. Geochemistry of both whole-rock and zircon supports the contention that this granite was produced in a magmatic arc environment and, therefore, is likely an extension of the older Dubois Greenstone Belt of the Gunnison Igneous Complex (GIC) and the Needle Mountains (1,770–1,755 Ma). Rocks of the younger Cochetopa succession of the GIC, the Salida Greenstone Belt, and the Sangre de Cristo Mountains (1,740–1,725 Ma) were not found in the Sawatch and Mosquito ranges. This observation strongly suggests that the northern edge of the Gunnison-Salida arc terrane underlies the southern portion of the Sawatch and Mosquito ranges. (2) Calc-alkalic to alkali-calcic magmas intruded this region approximately 55 m.y. after the Roosevelt Granite with emplacement of pre-deformational plutons at ca. 1,710 Ma (e.g., Henry Mountain Granite and diorite of Denny Creek), and this continued for at least 30 m.y., ending with emplacement of post-deformational plutons at ca. 1,680 Ma (e.g., Kroenke Granodiorite, granite of Fairview Peak, and syenite of Mount Yale). The timing of deformation can be constrained to sometime after intrusion of the diorite of Denny Creek and likely before the emplacement of the undeformed granite of Fairview Peak. Geochemistry of both whole-rock and zircon indicates that the older group of ca. 1,710-Ma plutons formed at shallower depths, and then they intruded the younger group of more deeply generated, commonly peraluminous and sodic plutons. Although absent in the Sawatch and Mosquito ranges, Mazatzal-age (ca. 1,680–1,620 Ma) plutonic rocks are present regionally. Inherited zircon components of Mazatzal-age were found as cores in some 1.4-Ga Sawatch and Mosquito Range zircons, indicating the likelihood of a relatively local source. These combined data suggest the possibility that all were produced within a continental-margin magmatic arc created as a result of southward-migrating (slab rollback?), north-dipping subduction to the south of the region. (3) Widespread Mesoproterozoic plutonism—with emplacement at various depths and exhibiting bimodal geochemistry—is recognized in 16 different samples. An older group of predominantly peraluminous, yet magnesian granitoids (e.g., granodiorite of Sayers, granite of Taylor River, and the St. Kevin Granite) were emplaced between ca. 1,450 and 1,425 Ma. These geochemical parameters suggest moderate degrees of partial melting in a low-pressure environment. Three younger metaluminous, but ferroan plutons (diorite of Grottos, diorite of Mount Elbert, and granodiorite of Mount Harvard), probably represent a final magmatic pulse at ca. 1,416 Ma. A comprehensive treatment of zircon REE and whole-rock trace-element behavior from Proterozoic rocks is scarce. Discriminant U/Yb versus Y diagrams using zircon data show that the Sawatch and Mosquito plutons are of continental origin, not oceanic. Additional bivariate diagrams incorporating cation ratio combinations of Gd, Ce, Yb, U, Th, Hf, and Eu offer refined insight into differences in fractionation trends and depth of magma generation for the various plutons. These interpretations, on the basis of zircon trace-element data, are mirrored in the whole-rock geochemistry data.

The basement-domain map is a compilation of basement domains in the conterminous United States and Alaska designed to be used at 1:5,000,000-scale, particularly as a base layer for national-scale mineral resource assessments. Seventy-seven basement domains are represented as eighty-three polygons on the map. The domains are based on interpretations of basement composition, origin, and architecture and developed from a variety of sources. Analysis of previously published basement, lithotectonic, and terrane maps as well as models of planetary development were used to formulate the concept of basement and the methodology of defining domains that spanned the ages of Archean to present but formed through different processes. The preliminary compilations for the study areas utilized these maps, national-scale gravity and aeromagnetic data, published and limited new age and isotopic data, limited new field investigations, and conventional geologic maps. Citation of the relevant source data for compilations and the source and types of original interpretation, as derived from different types of data, are provided in supporting descriptive text and tables. The tectonic settings for crustal types represented in the basement domains are subdivided into constituent geologic environments and the types of primary metals endowments and deposits in them are documented. The compositions, architecture, and original metals endowments are potentially important to assessments of primary mineral deposits and to the residence and recycling of metals in the crust of the United States portion of the North American continent. The databases can be configured to demonstrate the construction of the United States through time, to identify specific types of crust, or to identify domains potentially containing metal endowments of specific genetic types or endowed with specific metals. The databases can also be configured to illustrate other purposes chosen by users.

First posted August 10, 2015 For additional information, contact: Center Director, Central Mineral and Environmental Resources Science Center U.S. Geological Survey Box 25046, Mail Stop 973 Denver, CO 80225http://minerals.cr.usgs.gov/ The purpose of this report is to present available geochemical, modal, and geochronologic data for approximately 1.4 billion year (Ga) A-type granitoid intrusions of the United States and to make those data available to ongoing petrogenetic investigations of these rocks. A-type granites, as originally defined by Loiselle and Wones (1979), are iron-enriched granitoids (synonymous with the ferroan granitoids of Frost and Frost, 2011) that occur in an anorogenic, within-continent setting. Relative to other granitic rocks, A-type granites have high FeO*/(FeO*+MgO), high K2O and K2O/Na2O, are metaluminous to weakly peraluminous, and are enriched in incompatible trace elements. Loiselle and Wones (1979) further suggested that A-type granites are relatively anhydrous. Anderson (1983) provides an early compilation of data for the products of 1.4 Ga magmatism in North America and notes the spatial and temporal association of a trio of rock types, which includes gabbro to anorthosite, intermediate composition mangerite, and granitic rapakivi rocks. In North America, the majority of known A-type intrusions were emplaced between 1.5 and 1.3 Ga and are predominantly of the granitic variety (Anderson, 1983). This report addresses the broadly Mesoproterozoic-age granitic rocks of the conterminous United States. Constituents of this group of intrusive rocks were defined using a variety of spatial, compositional, and geochronologic metrics. Thomas and others (2012) provided an updated synthesis, largely based on new isotopic and geochronologic data (for example, Fisher and others, 2010), for the large-scale geologic and tectonic evolution of the eastern United States. Their findings suggest that the basement rocks of the central and southern Appalachian region are allochthonous relative to the remainder of Laurentia and were accreted along the Grenville front between 1.25 and 1.0 Ga. Accordingly, Mesoproterozoic rocks east of the Grenville front and south of the approximate latitude of New York City do not represent North American magmatism. Consequently, geochemical, modal, and geochronologic data for these rocks are not included in the compilation described herein. Further, the structural styles and compositions of granitoid rocks east of the Grenville front, mostly highly deformed gneissic rocks, are dissimilar to those characteristic of the A-type granitoid rocks described herein. A variety of compositional and age information further characterizes the 1.4 Ga A-type granitoid rocks in the conterminous United States. Most samples included in this compilation have felsic compositions, although some extend to intermediate compositions. SiO2 contents range from 56 to almost 78 weight percent, and median and mean SiO2 contents are 72.0 and 71.1 weight percent, respectively. The majority of these rocks for which modal data are available are composed of monzogranite (Streckeisen, 1976), although the dataset also contains many samples composed of granodiorite and syenogranite. A smaller group of the granitoid rocks in this dataset are composed of quartz monzodiorite and quartz monzonite, and a very small subset of samples is composed of alkali-feldspar granite, tonalite, alkali-feldspar quartz syenite, and quartz syenite (fig. 1). Many of the 1.4 Ga granitoid rocks are further characterized by medium- to coarse-grain size and are also conspicuously porphyritic; alkali feldspar phenocrysts or megacrysts (2–10 cm), often with rapakivi overgrowths, are a common feature of many of these rocks (Anderson, 1983; Anderson and Bender, 1989; Anderson and Cullers, 1978; Condie and Budding, 1979). The age of A-type magmatism in North America ranges from about 1.8 to 1.0 Ga, although Anderson (1983) suggests that more than 70 percent (by volume) of A-type magmatism in this region occurred between 1.49 and 1.41 Ga. In the conterminous United States, ages of A-type granitoid rocks are restricted to the period between about 1.49 and 1.33 Ga (Anderson, 1983; Bauer and Pollock, 1993; Bickford and Mose, 1975; Bickford, Harrower, and others, 1981; Bickford and others, 1989; Dewane and Van Schmus, 2007; Hoppe and others, 1983; Peterman and Hedge, 1968; Van Schmus and Bickford, 1981; Van Schmus and others, 1975). Using these recognition criteria, we identified A-type granitoid intrusions of the conterminous United States; for those intrusions, we compiled available geochemical, modal, isotopic (Sr and Nd) and geochronologic data for inclusion in the databases described herein. The significance of 1.4 Ga granitoid rocks relative to the geologic evolution of the conterminous United States remains unclear, despite Anderson’s (1983) compilation and synthesis of compositional data pertinent to these rocks. The large-volume magmatic events indicated by these rocks, as well as their broad geographic distribution, tectonic significance, and association with mineral deposits, underscore their importance. The broad distribution of these rocks, from the northern mid-continent to the southwestern United States (in New Mexico, Arizona, California, and southernmost Nevada), throughout the Rocky Mountains in New Mexico and Colorado (and sporadically in southern Wyoming and central Idaho), and beneath much of the Plains region (as indicated by drilling), has led to the large-scale tectonic and magmatic processes responsible for genesis of the associated magmas being actively studied. In addition, Kisvarsanyi (1972) suggests that iron-copper deposits in the St. Francois Mountains of southeastern Missouri are petrogenetically associated with 1.4 Ga A-type granitoids that occur in that region. Similarly, Dall’Agnol and others (2012) summarize important global associations between A-type granitoid rocks and a variety of important ore deposit types, particularly tin, high-field-strength elements (Zr, Hf, Nb, Ta), rare-earth elements, and iron oxide-copper-gold deposits. Consequently, the need to better understand relations between A-type granitoid rocks, tectonic setting, and magma petrogenesis, as well as their genetic associations with important types of ore deposits, suggests that developing a definitive geochemical, modal, and geochronologic database for these rocks in the conterminous United States is of considerable value.

The origin of gold nuggets in placers is enigmatic as they can be mechanically separated from the primary vein deposit or can be of secondary origin, formed in the placer environment. Pb isotopes can be a valuable tracer as a match in the isotopic ratios between vein and placer gold will indicate that the placer nuggets are simply mechanically separated from the hydrothermal vein and unmodified by weathering.Reconnaissance elemental analyses revealed that vein and placer gold from the Rich Hill district, Arizona, contain up to thousands of ppm Pb and therefore both are suitable for Pb isotope analyses. We measured Pb isotopes in placer gold nuggets and compare the results to primary vein gold and sulfides and also gangue minerals and host rocks in the Rich Hill area. Primary vein gold and galena show similar Pb isotope ratios with Pb-206/Pb-204 ranging from 18.364 to 18.486, Pb-207/Pb-204 from 15.574 to 15.593, and Pb-208/Pb-204 from 37.150 to 37.359. This indicates that the ore metals were derived from a similar source during a hypogene hydrothermal event in the geologic past. Present-day Pb isotope compositions of local rocks in the area show distinct values compared to the primary vein mineralization. Age-corrected and modeled Pb isotope compositions for local magmatic rocks do not provide a clear picture for a possible hydrothermal ore metal source due to possible alteration processes and the long time elapsed since the mineralization event. The distinct present-day Pb isotopes in local lithological units, however, provide an excellent tracer for deciphering the origin of the placer gold.All the placer gold nuggets show very distinct Pb isotope compositions when compared to their respective hydrothermal vein source represented by the vein gold and galena. The placer gold Pb isotopes show very wide variations, with Pb-206/Pb-204 ranging from 17.985 to 20.057, 207Pb/Pb-204 from 15.494 to 15.749, and Pb-208/Pb-204 from 36.863 to 38.606. The placer nuggets follow the present-day Pb isotope trend observed in rocks and sediments in the area. In addition, the Pb isotopes in majority of the placer gold nuggets are far more radiogenic compared to the vein gold, sulfides, and even gangue minerals. This is indicating that a significant part, if not all, of the Pb in the placer gold was relatively recently acquired from the placer sediments. The observed distinct Pb isotope compositions between primary and placer samples suggest that gold undergoes significant chemical changes during the supergene stage. Considering a number of possible scenarios, the most plausible explanation for the observed present-day Pb isotope similarity between placer gold and local rocks is formation of a significant part of the total mass of these nuggets within the placer environment.

In conjunction with the future planning needs of the U.S. Department of Agriculture, Forest Service, the U.S. Geological Survey conducted a detailed environmental assessment of the effects of historical mining on Forest Service lands in central Colorado. Stream sediment, macroinvertebrate, and various filtered and unfiltered water quality samples were collected during low-flow over a four-year period from 2004–2007. This report summarizes the sampling strategy, data collection, and analyses performed on these samples. The data are presented in Geographic Information System, Microsoft Excel, and comma-delimited formats. Reports on data interpretation are being prepared separately.

Geologic processes strongly influence water and sediment quality in aquatic ecosystems but rarely are geologic principles incorporated into routine biomonitoring studies. We test if elevated concentrations of metals in water and sediment are restricted to streams downstream of mines or areas that may discharge mine wastes. We surveyed 198 catchments classified as "historically mined" or "unmined," and based on mineral-deposit criteria, to determine whether water and sediment quality were influenced by naturally occurring mineralized rock, by historical mining, or by a combination of both. By accounting for different geologic sources of metals to the environment, we were able to distinguish aquatic ecosystems limited by metals derived from natural processes from those due to mining. Elevated concentrations of metals in water and sediment were not restricted to mined catchments; depauperate aquatic communities were found in unmined catchments. The type and intensity of hydrothermal alteration and the mineral deposit type were important determinants of water and sediment quality as well as the aquatic community in both mined and unmined catchments. This study distinguished the effects of different rock types and geologic sources of metals on ecosystems by incorporating basic geologic processes into reference and baseline site selection, resulting in a refined assessment. Our results indicate that biomonitoring studies should account for natural sources of metals in some geologic environments as contributors to the effect of mines on aquatic ecosystems, recognizing that in mining-impacted drainages there may have been high pre-mining background metal concentrations.

This database was initiated, designed, and populated to collect and integrate geochemical data from central Colorado in order to facilitate geologic mapping, petrologic studies, mineral resource assessment, definition of geochemical baseline values and statistics, environmental impact assessment, and medical geology. The Microsoft Access database serves as a geochemical data warehouse in support of the Central Colorado Assessment Project (CCAP) and contains data tables describing historical and new quantitative and qualitative geochemical analyses determined by 70 analytical laboratory and field methods for 47,478 rock, sediment, soil, and heavy-mineral concentrate samples. Most samples were collected by U.S. Geological Survey (USGS) personnel and analyzed either in the analytical laboratories of the USGS or by contract with commercial analytical laboratories. These data represent analyses of samples collected as part of various USGS programs and projects. In addition, geochemical data from 7,470 sediment and soil samples collected and analyzed under the Atomic Energy Commission National Uranium Resource Evaluation (NURE) Hydrogeochemical and Stream Sediment Reconnaissance (HSSR) program (henceforth called NURE) have been included in this database. In addition to data from 2,377 samples collected and analyzed under CCAP, this dataset includes archived geochemical data originally entered into the in-house Rock Analysis Storage System (RASS) database (used by the USGS from the mid-1960s through the late 1980s) and the in-house PLUTO database (used by the USGS from the mid-1970s through the mid-1990s). All of these data are maintained in the Oracle-based National Geochemical Database (NGDB). Retrievals from the NGDB and from the NURE database were used to generate most of this dataset. In addition, USGS data that have been excluded previously from the NGDB because the data predate earliest USGS geochemical databases, or were once excluded for programmatic reasons, have been included in the CCAP Geochemical Database and are planned to be added to the NGDB.

Composite alkalic plutonic suites and tuffaceous diamictite, although discontinuously exposed across central Idaho in roof pendants and inliers within the Idaho batholith and Challis volcanic-plutonic complex, define the >200-km-long north west-aligned Big Creek-Beaverhead belt. Sensitive high-resolution ion microprobe (SHRIMP) U-Pb zircon dates on these igneous rocks provide direct evidence for the orientation and location of the Neoproterozoic-Paleozoic western Laurentian rift margin in the northern U.S. Cordillera. Dating delimits two discrete magmatic pulses at ca. 665-650 Ma and 500-485 Ma at the western and eastern ends. respectively, of this belt. Together with the nearby 685 Ma volcanic rocks of the Edwardsburg Formation, there is a 200 Ma history of recurrent extensional magmatic pulses along the belt. A similar history of recurrent uplift is reflected in the stratigraphic record of the associated miogeoclinal and cratonal platform basins, suggesting that the Big Creek-Beaverhead belt originated as a border fault during continental rift events. The magmatic belt is paired with the recurrently emergent Lemhi Arch and narrow miogeoclinal facies belts and it lies inboard of a northwest-striking narrow zone of thinned continental crust. These features define a northeast-extending upper-plate extensional system between southeast Washington and southeast Idaho that formed a segment of the Neoproterozoic-Paleozoic miogeocline. This segment was flanked on the north by the St. Mary-Moyie transform zone (south of a narrow southern Canadian upper-plate margin) and on the south by the Snake River transfer zone (north of broad Great Basin lower-plate margin). These are the central segments of a zigzag-shaped Cordilleran rift system of alternating northwest-striking extensional zones offset by northeast-striking transfers and transforms. The data substantiate polyphase rift and continental separation events that included (1) pre- and syn-Windermere rifting, (2) Windermere margin subsidence, (3) late Ediacaran-Cambrain rifting, and (4) well-developed late Ediacaran-Devonian passive margin subsidence and deposition. Timing and geometries support synchronous but opposing divergence along Cordilleran and Atlantic rifts with a Junction in Southern California-Sonora.

The US Geological Survey is conducting a study of surface-water quality in the Rocky Mountains of central Colorado, an area of approximately 55,000km2. Using new and existing geologic maps, the more than 200 rock formations represented in the area were arranged into 17 groups based on lithologic similarity. The dominant regional geologic feature affecting water quality in central Colorado is the Colorado mineral belt (CMB), a NE-trending zone hosting many polymetallic vein or replacement deposits, and porphyry Mo deposits, many of which have been mined historically. The influence of the CMB is seen in lower surface-water pH (<5), and higher concentrations of SO42- (>100mg/L) and chalcophile metals such as Cu (>10μg/L), Zn (>100μg/L), and Cd (>1μg/L) relative to surface water outside the CMB. Not all streams within the CMB have been affected by mineralization, as there are numerous catchments within the CMB that have no mineralization or alteration exposed at the surface. At the regional-scale, and away from sites affected by mineralization, hydrothermal alteration, or mining, the effects of lithology on water quality can be distinguished using geochemical reaction modeling and principal components analysis. At local scales (100s of km2), effects of individual rock units on water chemistry are subtle but discernible, as shown by variations in concentrations of major lithophile elements or ratios between them. These results demonstrate the usefulness of regional geochemical sampling of surface waters and process-based interpretations incorporating geologic and geochemical understanding to establish geochemical baselines.

Geochemical data presented in this report pertain to Cretaceous igneous intrusions of the Boulder batholith and its satellitic plutons in southwest Montana. The geographic area addressed in this compilation is approximately bounded by lats 45.6 deg and 46.7 deg N. and longs 112.75 deg and 111.5 deg W. These data were compiled in order to establish the geologic framework for world-class mineral deposits of the Butte district. Although these deposits and their host rocks have been the subject of many investigations, the petrologic characteristics of associated intrusive rocks have not been systematically compiled, synthesized, or interpreted. Abundant late Mesozoic intrusions in the study area are probably byproducts of subduction-related processes, including back-arc magmatism that prevailed along the west edge of the North American plate during this interval. The ultimate goal of this effort will be an evaluation of the time-space-compositional evolution of Mesozoic magmatism associated with the Boulder batholith and identification of genetic associations between magmatic and mineralizing processes in this region.

Stream water and sediment toxicity to aquatic insects were quantified from central Colorado catchments to distinguish the effect of geologic processes which result in high background metals concentrations from historical mining. Our sampling design targeted small catchments underlain by rocks of a single lithology, which allowed the development of biological and geochemical baselines without the complication of multiple rock types exposed in the catchment. By accounting for geologic sources of metals to the environment, we were able to distinguish between the environmental effects caused by mining and the weathering of different mineralized areas. Elevated metal concentrations in water and sediment were not restricted to mined catchments. Impairment of aquatic communities also occurred in unmined catchments influenced by Schmidt is a Mendenhall post doctoral fellow and research ecologist, U.S. Geologic Survey, Mineral Resource Science Center, Denver, CO 80225; Fort Collins Science Center, Fort Collins, CO 80521. Church, Fey, Wanty, Verplanck, San Juan, DeWitt, Rockwell, and Klein are geologists, geochemists, and geospatial scientists, all with the U.S. Geological Survey, P.O Box 25046, MS 973, Denver, CO 80225. Clements and Mitchell ecotoxicologists, both with Colorado State University–Fish, Wildlife, and Conservation Biology Department, Fort Collins, CO 80521. Email: tschmidt@usgs.gov; schurch@usgs.gov; defy@usgs.gov; rwanty@usgs.gov; plverplanck@usgs.gov; csanjuan@usgs.gov; edewitt@usgs.gov; barnabyr@usgs.gov; tklein@usgs.gov; willc@cnr.colostate.edu; kmitchel@warnercnr.colostate.edu. hydrothermal alteration. Hydrothermal alteration style, deposit type, and mining were important determinants of water and sediment quality and aquatic community structure. Weathering of unmined porphyry Cu-Mo occurrences resulted in water (median toxic unit (TU) = 108) and sediment quality (TU = 1.9) that exceeded concentrations thought to be safe for aquatic ecosystems (TU = 1). Metalsensitive aquatic insects were virtually absent from streams draining catchments with porphyry Cu-Mo occurrences (1.1 individuals/0.1 m). However, water and sediment quality (TU = 0.1, 0.5 water and sediment, respectively) and presence of metalsensitive aquatic insects (204 individuals/0.1 m) for unmined polymetallic vein occurrences were indistinguishable from that for unmined and unaltered streams (TU = 0.1, 0.5 water and sediment, respectively; 201 individuals/0.1 m). In catchments with mined quartz-sericite-pyrite altered polymetallic vein deposits, water (TU = 8.4) and sediment quality (TU = 3.1) were degraded and more toxic to aquatic insects (36 individuals/0.1 m) than water (TU = 0.4) and sediment quality (TU = 1.7) from mined propylitically altered polymetallic vein deposits. The sampling approach taken in this study distinguishes the effects of different mineral deposits on ecosystems and can be used to more accurately quantify the effect of mining on the environment.

The Mount Evans batholith, in the central Front Range of Colorado, is composed of a main phase of massive to conspicuously foliated monzogranite and granodiorite and undeformed aplite and pegmatite. The Mount Evans batholith was previously considered to be part of the 1.7 Ga Routt Plutonic Suite. New U-Pb zircon ages on four samples (granodiorite, monzogranite, and granite), however, indicate that the batholith was emplaced at 1,442 +/- 2 Ma and belongs to the Berthoud Plutonic Suite. Most of the batholith has igneous textures and structures, except in the vicinity of the Idaho Springs-Ralston shear zone where those features are tectonically recrystallized and foliated. Foliation elsewhere in the batholith is a How structure.Zircons in two granodiorite samples, collected near the shear zone (just south of the Colorado Mineral Belt), are reversely discordant by about 0.8%-2.1%, with a considerable spread in Pb-207/Pb-206 ages. Many of the zircons from these samples contain apatite, K-feldspar, and quartz inclusions that appear to replace zircon along cracks and imperfections from rim to core. We suggest that these inclusions formed during a Laramide ore-forming event and incorporated Early and Middle Proterozoic radiogenic lead scavenged from the country rock. The excess radiogenic lead caused the scatter and reverse discordance in the data.

The Early Proterozoic basement of the southwestern US can be divided into at least 3 major crustal provinces on the basis of Pb isotopic and geochemical signatures. These are: (1) the Mojave of SE CA, southern NV, and western AZ; (2) the Yavapai of central and northern AZ, northern NM and southern CO; and (3) the Mazatzal of southern AZ., and central and southern NM. The boundary between the Yavapai and Mazatzal provinces is close to the age province boundary proposed by Silver. Crustal provinces defined by chronologic, structural, lithologic, or metamorphic criteria usually don't distinguish regions unique in crustal formation character because these criteria often represent events that affected the crust (well) after the time of its original formation or represent non-unique information (e.g., magmatism can occur at the same time in entirely different crustal provinces). In comparison, isotopic and certain geochemical data often provide unique criteria because they are related to distinct mantle sources, specific processes, or the specific time of crustal formation. New U-Pb zircon ages determined by the SHRIMP ion microprobe indicate that the Mojave province probably has a latest Archean/earliest Proterozoic basement on which sedimentary rocks containing 2.7--2.5 Ga and 2.0--1.8 Ga detrital zircon populationsmore » were deposited. The timing of plutonic events in the Mojave and Yavapai provinces is indistinguishable from 1.76--1.70 Ga. Plutonic rocks with Yavapai isotopic and geochemical signatures intruded the eastern edge ( ) of the Mojave province as early as 1.74 Ga. This suggests that the two provinces were in close proximity from 1.76 Ga and that the older Mojave province was a buttress against which juvenile Yavapai crust formed.« less

Volcanic and shallow intrusive features of the deeply dissected 34 Ma Grizzly Peak caldera in west-central Colorado record evolution of the magmatic center from pre-caldera through post-resurgent stages. Pre-caldera dikes, zones of hydrothermally altered rocks, and lava flows formed along a circular swarm of cone-sheet fractures around the site of the future caldera. Early, largely rhyolitic upper-crustal magmatism culminated in the caldera-forming eruption of the Grizzly Peak Tuff. Intracaldera tuff is zoned from high-silica rhyolite at the base to low-silica rhyolite at the eroded top and, further, contains dacite to mafic latite pumice lumps in two heterogeneous tuff layers in the upper third of the preserved section.Half of the erupted tuff ponded in the 17-by 23-km, > 600-km3 caldera, filling the asymmetric depression to a compacted thickness locally > 2.7 km, including intercalated rock-avalanche megabreccias shed from ring-fault scarps. The asymmetric caldera has an inner ring-fracture zone that separates two structural segments that collapsed to different depths. Caldera fill buried collapse structures as they formed; the inner ring-fracture zone is a growth (or syn-depositional) fault in the single-cooling-unit tuff. Welded-tuff ring dikes are locally exposed at erosion levels below the caldera fill. These dikes are remanants of fissure vents in the outer ring-fracture zone.Following collapse, the Grizzly Peak caldera was uplifted, forming a complexly faulted resurgent dome. Resurgence resulted partly from emplacement of a composite granodiorite laccolith now exposed in the eroded core of the dome. A belt of mafic latite to rhyolite porphyry dikes and small stocks formed across the center of the domed caldera during the waning of the magmatic center. Latite intrusions in this suite represent the penetration of relatively mafic magma to the surface following solidification of the felsic subcaldera batholith.