Millimetre-wave rotational spectra have been recorded for the molecules (CH3)(3CBr)-Br-79, (CH3)(3CBr)-Br-81 and (CH3)(3CI)-I-127. In addition, we have recorded low-J spectra at much greater precision using a Fourier-transform spectrometer. The combined results yield rotational, centrifugal distortion, quadrupole and spin-rotation constants which are more accurate than any determined independently.
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