The new bimetallic nickel(II) compound (PPh4)(4)[Ni-2(2)]. 6H(2)O (3), where H-8[2] stands for N,N',N",N'''-1,2,4,5-benzenetetrayltetrakis(oxamic acid), has been synthesized and its crystal structure determined by single-crystal X-ray diffraction. The structure of 3 consists of [Ni-2(eta(4):eta(4)-2)](4-) anions, tetraphenylphosphonium cations, and water molecules. Facile one-electron oxidation of the square-planar diamagnetic dinickel(II) complex [Ni-2(eta(4):eta(4)-2)](4-) generates the metallo-radical species [Ni-2(eta(4):eta(4)-2(.+))](3-) with characteristic intra-ligand pi-cation radical transitions in the visible region (475-550 nm) as well as a typical quasi-isotropic EPR signal at g approximate to 2.0.
Yves Journaux合作论文数1
Muñoz Roca, María del Carmen合作论文数Escuela Técnica Superior de Ingeniería Aeroespacial y Diseño Industrial, Universitat Politècnica de València;Dpto. de Física Aplicada, Universitat Politècnica de València1
Pei Yu合作论文数1
Beatriz Cervera合作论文数1
Ally Aukauloo合作论文数iBiTeC-S, CEA Saclay1Sandrine Poussereau合作论文数INSTM – UdR Firenze, Università degli Studi di Firenze1
Paul Fleurat-Lessard合作论文数1Xavier Ottenwaelder合作论文数1Rafael Ruiz-García合作论文数Departament de Química Orgànica, Universitat de València1
