The Neoproterozoic Cryogenian ('Marinoan') Ghaub Formation of northwestern Namibia represents an important founding pillar of the Snowball Earth hypothesis and its derivative, the Panglacial Earth hypothesis. These hypotheses assume oceans and continents covered by thick ice, even in the tropics, which caused a very distinct drop in eustatic sea-level. Over time, strongly increased CO2 contents of the atmosphere led to sudden ice melting, very substantial sea-level rise, and strong weathering on the continents associated with the deposition of cap carbonates in the newly ice-free oceans. The ongoing controversy about Snowball-type glaciations in Namibia and elsewhere is reviewed, and other hypotheses (Slushball Earth, Waterbelt Earth, Jormungand state of the Earth, Thin Ice state of the Earth, Zipper-Rift Earth, High-Obliquity Earth) are discussed. We prefer the term 'Waterbelt Earth' instead of the originally proposed `Waterbelt state' because of the clearer contrast with 'Snowball Earth'. Because a great deal of information related to Cryogenian glaciations comes from the Ghaub Formation of northwestern Namibia, these hypotheses should be tested independently based on a time-equivalent depositional system. This analogue was found in the carbonate-dominated successions of the Otavi Mountainland (OML), northeastern Namibia, and is highly comparable with the successions in the well-investigated northwest of the country. An extreme eustatic sea-level drop caused by a global glaciation of oceans and continents and imposed on a carbonate platform or ramp such as the one in the OML would have led either to glacial cover or widespread subaerial exposure and extensive erosion, including deeply incised valleys. The presence of such features would strongly support the Snowball Earth hypotheses if tectonic effects did not play a major role. During the post glacial transgression, distinct reworking of the carbonate platform/ramp surface would have occurred, leaving behind lag deposits, as well as infills of incised valleys with fluvial, reworked glacial, and marine deposits. The main objective of our research was to weigh and investigate the strengths and weaknesses of the proposed Snowball Earth model of glacially induced large-amplitude sea-level changes during Ghaub time, and to compare different models to obtain a rough estimate of the amount of glaciation. The study area in the OML includes two different, age-equivalent facies realms: platform sedimentation in the Southern area without diamictites, and slope deposits, including Ghaub diamictites, in the Northern area. The southern, continuously shallow-marine area shows a shallowing-upward succession from the pre-glacial lower Auros Formation, often varve-like laminated shales formed below wave base, to metre-high columnar stromatolites and microbial mat-related carbonates with intervals of vertical tubes (degassing features) of the upper Auros Formation, overlain by cap carbonates of the Maieberg Formation. The columnar stromatolites and the microbial tubestone lithotypes were clearly deposited in the euphotic zone. Indications for tidal conditions or subaerial exposure were not recorded in this platform succession without unconformities. Neither dropstones, nor incised channels, nor transgressive lag deposits were observed. The facies changes from below storm wave base to the photic zone and finally a shallow subtidal zone is explained by a prolonged, modest sea-level fall, partly counterbalanced by subsidence, followed by a slow transgression. In contrast, coarse-grained sedimentary rocks (e.g., oolites, debrites) characterise the time-equivalent successions in the Northern area. Starting with laminated shales at the base, similar to the Southern area, the overlying redeposited oolites and breccias of the Auros Formation show distinct lateral and vertical in homogeneities and thickness changes, which indicate long-lasting synsedimentary tectonism. The same phenomenon is observed in the overlying diamictites of the Ghaub Formation. Their variable clast content indicates erosion of a strongly uplifted local source area formerly covered by a thick carbonate succession, which was downstripped to the crystalline basement. The prograding diamictite succession with repeatedly intercalated silt stringers is interpreted as periglacial debris flows into a marine environment. Sparse striated clasts in the diamictites and very rare dropstones (much less common than in northwestern Namibia) are indicators of glaciations somewhere in the area. However, compared with other glacial sequences, e.g. Quaternary periglacial sediments at the forefront of continental ice, dropstones and striated clasts would be expected to be much more common and more uniformly distributed if the entire area was covered by melting continental ice, as proposed in the Snowball/Panglacial Earth scenario. In the Southern area, dropstones would be expected to occur on the flooded platforms/ramps as well, even when diamictites are absent. Both the relatively moderate sea-level change and the less common, irregular distribution of locally concentrated glacial rainouts provide strong evidence against the presence of a thick, laterally continuous ice cover over oceans and continents extending to equatorial areas. The oceans possibly corresponded to the scenario of a Waterbelt Earth or High-Obliquity Earth; evidence of open oceanic water exists, which would have enabled the continued evolution of biota. Glacial ice was present on tropical continents, but its occurrences may have been regional in patches, sourced from mountainous areas, and ice streams would have reached the oceans only locally, unrelated to a thick continental ice cover.

Sedimentological insights underpin many of the important recent advances in understanding of Earth system behaviour in the Neoproterozoic Era. This article reviews three main areas: (i) chemical proxies and their preservation, with emphasis on carbonate facies; (ii) glacial and post-glacial facies, including their age constraints; (iii) sedimentary evidence for biotic innovations and responses. Chemostratigraphy plays an important role in ordering Neoproterozoic events and defining disturbances to the carbon cycle. There is increasing attention being paid to assessing the role of diagenetic origination or modification of chemostratigraphic signals. Alongside this, new criteria for identifying primary dolomite and precursor metastable phases such as ikaite have been developed. In respect of oxygenation, geochemical proxies substantiate the concept of a Neoproterozoic Oxygenation Event as a very gradual transition, the ocean being at any one time a heterogeneous assemblage of ferruginous, sulphidic and oxic conditions, with some evidence of increasing deep-sea oxidation through the Ediacaran Period. Techniques such as Fe-speciation need to be supplemented with proxies sensitive to suboxic conditions. More generally, it is predicted that petrographically constrained microanalytical studies will also become more important in reconstructing palaeoenvironmental conditions. The global distribution of Neoproterozoic glacial deposits combined with palaeomagnetic evidence supports the concept of panglaciations in which ice sheets reached sea-level in the tropics. Advances in radiometric dating have demonstrated the synchronous onset of global (Sturtian) glaciation at 717Ma and the demise of a second (Marinoan) glaciation at 635Ma, and plausibly indicate long durations for each (55Myr for Sturtian and 5 to 15Myr for Marinoan). However, a compilation of radiometric dates indicates ambiguities indicating the need for further improvements to the radiometric and Sr-isotope database to understand events within the Sturtian time frame, the timing of onset of Marinoan glaciations, and the age and synchroneity of individual negative C-13 anomalies. Sturtian deposits are typically thick, rift-related successions containing a range of environments influenced or dominated by dynamic glaciers, as well as ice-free marine intervals. Marinoan glacial deposits, by contrast, tend to be thin and continental. During the latter interval, oxygen isotope systematics of sulphate demonstrate that atmospheric CO2 was high, as predicted by Snowball Earth theory, and that sedimentation was influenced by orbital forcing. The Sturtian record, by comparison, needs to be searched for evidence of cold-climate hiatuses on the one hand and orbital forcing on the other. Cap carbonate formation appears to have coincided with rising sea-levels following panglaciations. Snowball theory considers that they formed rapidly in the postglacial greenhouse, but an alternative model of slower formation with clastic sediment starvation during transgression may prove to be consistent with new data and models showing extensive glacier terminations on land. For all facies, but especially caps, the use of microanalytical techniques and holistic studies of petrogenesis are future priorities. There are important discrepancies between molecular clock predictions of early metazoan origination and the hard evidence from sedi-mentary records which largely depend on local exceptional preservation by early diagenesis.A variety of life survived panglaciation, and there is little evidence that glaciations directly caused oxygenation or stimulated evolution.

Abstract Naturally fractured reservoirs, within which porosity, permeability pathways and/or impermeable barriers formed by the fracture network interact with those of the host rock matrix to influence fluid flow and storage, can occur in sedimentary, igneous and metamorphic rocks. These reservoirs constitute a substantial percentage of remaining hydrocarbon resources; they create exploration targets in otherwise impermeable rocks, including under-explored crystalline basement, and they can be used as geological stores for anthropogenic carbon dioxide. Their complex fluid flow behaviour during production has traditionally proved difficult to predict, causing a large degree of uncertainty in reservoir development. The applied study of naturally fractured reservoirs seeks to constrain this uncertainty and maximize production by developing new understanding, and is necessarily a broad, integrated, interdisciplinary topic. Some of the methods, challenges and advances in characterizing the interplay of rock matrix and fracture networks relevant to fluid flow and hydrocarbon recovery are reviewed and discussed via the contributions in this volume.

Natural fractures control primary fluid flow in low-matrix-permeability carbonate hydrocarbon reservoirs, making it important to understand the factors that affect natural fracture distributions and networks. Away from the influence of folds and faults, stratigraphic controls are accepted to be the major control on fracture networks. The influence of carbonate nodular chert rhythmite successions on natural fracture networks is investigated here using a Discrete Element Modelling (DEM) technique that draws on outcrop observations of naturally fractured carbonates in the Eocene Thebes Formation, exposed in the west central Sinai of Egypt, that also form reservoir rocks in the subsurface. Stratally-bound chert nodules below bedding surfaces create lateral heterogeneities that vary over short distances. The resulting distribution of physical properties (differing stiffnesses) caused by chert rhythmites is shown to generate extra complexity in natural fracture networks in addition to that caused by bed thickness and lithological physical properties. Chert rhythmite successions need to be considered as a distinct type of carbonate fractured reservoir. Stratigraphic rules for predicting the distribution, lengths and spacing of natural fractures, and quantitative fracture indices (P-11, P-21, P-22 and fractal dimension) are generated from the DEM outcomes. In a less-stiff carbonate medium, the presence of chert nodules reduces fracture intensity at chert horizons, and fractures per unit area are higher in chert-free vertical corridors. In a stiff carbonate medium, chert has little influence on fracture development. In a peritidal cyclic succession with constant layer thicknesses, the presence of chert in less-stiff carbonate horizons results in a reduction in fracture intensity. When chert is introduced in a subtidal cyclic sequence with constant layer thicknesses, it has little effect on fracture distribution. The study has widespread significance for characterizing naturally fractured reservoirs containing carbonate nodular chert rhythmites.

Natural fractures control primary fluid flow in low matrix permeability carbonate hydrocarbon reservoirs. Fracture stratigraphy partitions a rock succession based on quantifiable fracture parameters. Mechanical stratigraphy is defined by physical rock properties. However, mechanical stratigraphy can vary spatially and temporally due to lateral facies changes and post depositional diagenetic modification. Carbonate rocks are particularly susceptible to repeated episodes of diagenetic alteration. The consequence of this is that extant mechanical stratigraphy in outcrop and core/boreholes need not always correlate with fracture stratigraphy. Fracture stratigraphy is the product of tectonic history and the mechanical stratigraphy that existed when fracturing occurred). In this study mechanical variables are defined as the starting input parameters to construct geologically appropriate carbonate mechanical stratigraphies that are then forward modelled using a numerical 2D discrete element method to generate discrete fracture networks (DFN). DFN define fluid pathways, and may be classified into fracture stratigraphic units. This approach allows mechanical stratigraphy and fracture stratigraphy to be characterised separately.

Abstract The geological paradox of at least two Neoproterozoic glacial intervals at tropical latitudes intercalated within carbonates remains an unsolved puzzle. Several conceptual models have been proposed to explain these apparent rapid swings between climatic extremes and the associated isotopic changes in sea-water chemistry. In Oman, post-glacial transgressive sedimentary successions represent important hydrocarbon source rocks. Source rock characteristics of Neoproterozoic post-glacial successions in other parts of the world (even if not directly correlatable) are, therefore, of special economic interest. This paper concentrates on the Ghaub Formation diamictite interval in northern Namibia and the major environmental change in the aftermath of the assumed glaciation. The relationship of the post-glacial sediments with the underlying different types of cap carbonate and diamictite successions is discussed, and a model of the succession of events is presented. The palaeotopography, caused mostly by ongoing tectonic activity including uplift on the scale of thousands of metres, strongly influenced the petroleum system created and played an important role for the hydrocarbon prospectivity of this post-glacial succession. Tectonic activity on the shelf of the southern margin of the Congo Craton was repeated, and different sub-basins were created before, during and after the Ghaub glaciation. The newly formed relief was flooded, and the different sub-basins were affected by restricted circulation for quite some time. This general scenario bears many similarities to the late Ordovician–early Silurian petroleum system, also formed during post-glacial sea-level rise.

A re-appraisal of the factors controlling the deposition of carbonate megabreccias and their sequence stratigraphic significance is presented based on an examination of the mechanisms for instigating carbonate seafloor slope instability and a review of the depositional settings of these distinctive rock deposits. Limestone megabreccias have classically been interpreted as formed by the catastrophic collapse of high-angle metastable 'oversteepened' carbonate platform margins. However, a review of megabreccia occurrence shows that these deposits formed on a broad range of carbonate slope angles and that metastable oversteepened slopes are not necessary for their genesis. A re-evaluation constructed from first principles of mechanisms promoting submarine gravitational instability indicates that pore-water overpressure of confined aquifer horizons beneath the seafloor rather than slope oversteepening, is the critical control on megabreccia deposition. Catastrophic release of overpressure may initiate gravitational instability of previously kinematically stable slopes.The relative importance of endogenic processes intrinsically linked to the depositional system and exogenic processes operating independently in generating megabreccias is assessed. Two particularly important mechanisms in generating megabreccias are endogenic processes causing overpressure at discrete hydrologically confined horizons beneath the seafloor during relative sea-level falls, and increases in stress as pore-fluid drains from the sediment when the platform-top becomes subaerially exposed during relative lowstands of sea-level. The increased likelihood of megabreccia genesis during relative sea-level falls is supported by an empirical trend identified from a review of the stratigraphic distribution of documented megabreccias. Exogenic causes of gravitational instability with inherently random periodicity, especially seismicity, may account for the small number of documented megabreccias that do not conform to this underlying trend.The proposed endogenic pattern favouring megabreccia deposition during relative sea-level falls is important in a sequence stratigraphic context. Megabreccia deposits may build volumetrically significant toe-of-slope wedges and aprons during relative lowstands of sea-level, partially compensating for the decrease/loss in the supply of fresh granular sediment as the platform-top carbonate factory contracts. Lowstand wedges and aprons in carbonate systems therefore generally differ in composition from equivalent highstand deposits in being composed not of calciturbidite deposits but of megabreccias cannibalized from the upper slope.