ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTProperties of organic-water mixtures. 13. Self-diffusion coefficients of sodium(1+) ion in glycerol triacetate-water mixturesHarold O. Phillips, Arthur J. Shor, Arthur E. Marcinkowsky, and Kurt A. KrausCite this: J. Phys. Chem. 1977, 81, 7, 682–683Publication Date (Print):April 1, 1977Publication History Published online1 May 2002Published inissue 1 April 1977https://pubs.acs.org/doi/10.1021/j100522a020https://doi.org/10.1021/j100522a020research-articleACS PublicationsRequest reuse permissionsArticle Views58Altmetric-Citations1LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access options Get e-Alerts

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTProperties of organic-water mixtures. 11. Self-diffusion coefficients of sodium(1+) ion in polyethylene glycol-water mixtures at 25.degree.CHarold O. Phillips, Arthur E. Marcinkowsky, S. Baruch Sachs, and Kurt A. KrausCite this: J. Phys. Chem. 1977, 81, 7, 679–682Publication Date (Print):April 1, 1977Publication History Published online1 May 2002Published inissue 1 April 1977https://pubs.acs.org/doi/10.1021/j100522a019https://doi.org/10.1021/j100522a019research-articleACS PublicationsRequest reuse permissionsArticle Views71Altmetric-Citations7LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access options Get e-Alerts

Chemischer InformationsdienstVolume 3, Issue 5 Preparative Inorganic Chemistry ChemInform Abstract: DIFFUSIONSUNTERSUCHUNGEN 3. MITT. TRACER-DIFFUSIONSKOEFFIZIENTEN VON LANTHAN(III) IN KONZENTRIERTEN LOESUNGEN GEN VON HCL UND HCLO4 BEI 25 GRAD ARTHUR E. MARCINKOWSKY, ARTHUR E. MARCINKOWSKYSearch for more papers by this authorHAROLD O. PHILLIPS, HAROLD O. PHILLIPSSearch for more papers by this author ARTHUR E. MARCINKOWSKY, ARTHUR E. MARCINKOWSKYSearch for more papers by this authorHAROLD O. PHILLIPS, HAROLD O. PHILLIPSSearch for more papers by this author First published: February 1, 1972 https://doi.org/10.1002/chin.197205012AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat No abstract is available for this article. Volume3, Issue5February 1, 1972 RelatedInformation

Tracer diffusion coefficients of LaIII, DLa, were measured in HCl (1·0M–10·0M) and HClO4(1·1M–9·76M). DLa in HCl decreased slowly as the HCl concentration increased; at 10M-HCl DLa is still ca. 65% of D°La(0·62 × 10–5 cm2 s–1). In HClO4, DLa remains nearly constant at 0·6 × 10–5 cm2 s–1 from 1·1M to ca. 3·5M-acid and then decreases rapidly to 0·2 × 10–5 cm2 s–1 in 9·76M-acid.For the highest concentrations of acid (ca. 10M) studied, DLa in HClO4 is about half the value in HCl. However, the product of the relative diffusion coefficient and the relative viscosity has the same value in both systems when the activities of water are equal.

Tracer diffusion coefficients of copper(II) in HCl and HClO4(0·25–10M) were measured by the radiometric porous-frit method. Complexes of CuII with chloride ions appear to account for the differences observed in the two acid systems. A comparison of the relative diffusion coefficient–viscosity products of CuII, ZnII, and SrII in HCl shows that CuII is complexed to a lesser extent than ZnII while SrII does not appear to be complexed. Our measured diffusion coefficient for copper in 1M-HCl agrees reasonably well with the values reported in several chronopotentiometric and polarographic papers in the literature. In perchloric acid solutions (0·25–8M), the relative diffusion coefficient–viscosity products for CuII and ZnII are essentially the same.

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTProperties of organic-water mixtures. VII. Self-diffusion coefficients of sodium(1+) in ethylene glycol-water and glycerol-water mixtures at 25.degree.Arthur E. Marcinkowsky, Harold Olney Phillips, and Kurt A. KrausCite this: J. Phys. Chem. 1968, 72, 4, 1201–1203Publication Date (Print):April 1, 1968Publication History Published online1 May 2002Published inissue 1 April 1968https://pubs.acs.org/doi/10.1021/j100850a021https://doi.org/10.1021/j100850a021research-articleACS PublicationsRequest reuse permissionsArticle Views179Altmetric-Citations6LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access options Get e-Alerts

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTHyperfiltration Studies. IV. Salt Rejection by Dynamically Formed Hydrous Oxide Membranes1A. E. Marcinkowsky, K. A. Kraus, H. O. Phillips, J. S. Johnson Jr., and A. J. ShorCite this: J. Am. Chem. Soc. 1966, 88, 24, 5744–5746Publication Date (Print):December 1, 1966Publication History Published online1 May 2002Published inissue 1 December 1966https://doi.org/10.1021/ja00976a013Request reuse permissionsArticle Views175Altmetric-Citations93LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (314 KB) Get e-Alertsclose Get e-Alerts

Salt-filtering layers can be formed on porous bodies by circulating by them pressurized solutions containing small concentrations of organic polyelectrolytes. These films reject substantial fractions of solute from dilute solutions, frequently with high transmission rates through the membranes (e.g. 100 to 200 gpd/ft2 under 35 atm. pressure). Possibilities of applications in hyperfiltration (reverse osmosis) processes are discussed briefly.

Sulfides of Ag(I), FE(II), Cu(II), Zn(II), Pb(II), Cd(II), and As(III), “adsorb” a number of transition metal ions from solution. The process proceeds primarily through metathetical reactions in which the metal of the sulfide is displaced by appropriate ions in solution. The reactions are usually fast and can be carried out in small columns at flow rates of several cm/min. With Ag(I) and 1- to 2-cm columns of various sulfides, flow rates as high as 50 cm/min were feasible without breakthrough. The percent conversion of the sulfides at 50% breakthrough varied from 5% for the reaction of Hg(II) with CuS at 25° to about 128° for the reaction of Hg(II) with Ag2S. With ZnS uptakes as high as 20 moles of Ag(I) per liter of bed were obtained at 50% breakthrough and a flow rate of 7 cm/min. While possibility of conversion must depend on relative stability of the sulfides, neither the rate of reaction nor the completeness of conversion seems related to the relative solubilities. The nature of the solid and the ease with which diffusion takes place are presumably important factors.

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTProperties of Organic-Water Mixtures. V. Self-Diffusion Coefficients of Na+ in Alcohol-Water Mixtures at 25°1,2Arthur E. Marcinkowsky, Harold O. Phillips, and Kurt A. KrausCite this: J. Phys. Chem. 1965, 69, 11, 3968–3972Publication Date (Print):November 1, 1965Publication History Published online1 May 2002Published inissue 1 November 1965https://doi.org/10.1021/j100895a054RIGHTS & PERMISSIONSArticle Views71Altmetric-Citations2LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (464 KB) Get e-Alerts

This chapter presents chromatography as a branch of science that bridges a century of science and discovery. Chromatography represents the premier analytical method of the 20th century for the advancement of a variety of the disciplines of science. Chromatography has grown over the past century to be a vigorous enterprise of scientists; societies with the background of their patrons from government, academia, and research institutions; and the corporate sector and private foundations. The scientific community and public at large has benefited from these interactions. Chromatography as one of the separation sciences has become a common denominator for analytical methods and biological/medical sciences research. They have caused many changes in other sciences, but particularly in analytical chemistry—a change from the determination of one or several components in a sample to the separation, detection, and the quantitative measurement of all the components in a sample.

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAdsorption on Inorganic Materials. V. Reaction of Cadmium Sulfide with Copper(II), Mercury(II) and Silver(I)Harold O. Phillips and Kurt A. KrausCite this: J. Am. Chem. Soc. 1963, 85, 4, 486–487Publication Date (Print):February 1, 1963Publication History Published online1 May 2002Published inissue 1 February 1963https://doi.org/10.1021/ja00887a035RIGHTS & PERMISSIONSArticle Views94Altmetric-Citations8LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (311 KB) Get e-Alerts Get e-Alerts

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTAdsorption on Inorganic Materials. IV. Cation Exchange Properties of Zirconium AntimonateHarold O. Phillips and Kurt A. KrausCite this: J. Am. Chem. Soc. 1962, 84, 11, 2267–2268Publication Date (Print):June 1, 1962Publication History Published online1 May 2002Published inissue 1 June 1962https://pubs.acs.org/doi/10.1021/ja00870a057https://doi.org/10.1021/ja00870a057research-articleACS PublicationsRequest reuse permissionsArticle Views72Altmetric-Citations23LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts