Chemischer InformationsdienstVolume 17, Issue 10 Organoelement Compounds ChemInform Abstract: Synthesis of 3-Methyl- and 3-Aryl-penten-yn-Substituted Alcohols, Ethers and Aldehydes. N. A. BYCHKOVA, N. A. BYCHKOVASearch for more papers by this authorN. V. ZOTCHIK, N. V. ZOTCHIKSearch for more papers by this authorZH. N. MOTORINA, ZH. N. MOTORINASearch for more papers by this authorI. A. RUBTSOV, I. A. RUBTSOVSearch for more papers by this author N. A. BYCHKOVA, N. A. BYCHKOVASearch for more papers by this authorN. V. ZOTCHIK, N. V. ZOTCHIKSearch for more papers by this authorZH. N. MOTORINA, ZH. N. MOTORINASearch for more papers by this authorI. A. RUBTSOV, I. A. RUBTSOVSearch for more papers by this author First published: March 11, 1986 https://doi.org/10.1002/chin.198610292Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat No abstract is available for this article. Volume17, Issue10March 11, 1986 RelatedInformation
Hydrogenation of the acetylacetonates of Ni, Co, Cu, and Zn at atmospheric pressure and at 100 atm both on Ni and on NiM proceeded at a lower rate than the hydrogenation of pure acetylacetone. The rate of hydrogenation grew along the series of acetylacetonates Co < Zn ≤ Ni < Cu (Ni) and Co < Zn ≤ Cu < Ni (NiM).
AbstractIn Gegenwart eines Cu‐Ni‐Kata1ysators, der durch Behandeln von "Aerosil" mit einer Kupfer‐ und Nickelnitrat‐Lösunganschließendem Erhitzen auf 350°C und Modifizierung mit einer 0,5%igen Weinsäure‐ Lösung erhalten wird, entsteht bei der Hydrierung von Acetylaceton (I) das Ketol (II) in 9%iger optischer Ausbeute.
A mixed Cu-Ni (1∶1) catalyst, deposited on aerosil and modified with D-(+)-tartarie acid, was obtained, which is active in theselective stereoselective hydrogenation of acetylacetone to the (-)-ketol. The optical yield of the ketol is 9.1% at 133°.
Aus dem Silylacetylen (I) werden durch aufeinanderfolgende Umsetzungen mit Äthylmagnesiumbromid (II) und Aceton (IV), Dehydratisierung durch Erhitzen mit p‐Toluolsulfonsäure in Benzol und Substitution des Silylrestes mit Hilfe der Carbonsäure= Chloride (VII) die ungesättigten Acetylenketone (VIII) hergestellt.
Chemischer InformationsdienstVolume 4, Issue 23 Heterocyclic Compounds ChemInform Abstract: SYNTH. VON N-SUBSTITUIERTEN NICOTINSAEUREAMIDEN L. A. GONCHAROVA, L. A. GONCHAROVASearch for more papers by this authorA. V. STARKOV, A. V. STARKOVSearch for more papers by this authorI. A. RUBTSOV, I. A. RUBTSOVSearch for more papers by this author L. A. GONCHAROVA, L. A. GONCHAROVASearch for more papers by this authorA. V. STARKOV, A. V. STARKOVSearch for more papers by this authorI. A. RUBTSOV, I. A. RUBTSOVSearch for more papers by this author First published: June 5, 1973 https://doi.org/10.1002/chin.197323279Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat No abstract is available for this article. Volume4, Issue23June 5, 1973 RelatedInformation
Abstract(‐)‐a‐Dimethylamino‐propiophenon (I) läßt sich in Äther mit Komplexverbindungen aus Lithium‐aluminiumhydrid und (+)‐Butanol, (‐)‐Chinin oder (+)‐Chinidin zu einem ca. 1:1‐Gemisch aus threo‐ und erythro‐N‐Methyl‐ephedrin (II) und (III) reduzieren (Ausbeute 86% bis quantitativ).
AbstractDas durch Umsetzung von Äthylmagnesiumbromid (II) mit Acetylen (I) in Tetrahydrofuran erhaltene Acetylen‐bis‐magnesiumbromid (III) wird" in Tetrahydrofuran mit Trimethylchlorsilan (IV) zum Trimethylsilylacetylen (V) um′ gesetzt.