Binding of bismuth cation with two newly synthesized picolinate containing acyclic ( L1 ) and macrocyclic ( L2 ) ligands was studied. Both ligands demonstrate complex formation with Bi 3+ under ambient conditions with high complexation constants. Serum stability of the complexes was investigated in serum protein excess of 10- and 100-times. Experiments with no-carrier-added radiobismuth ( 207 Bi and 213 Bi) were performed. A one-column 225 Ac/ 213 Bi generator system, based on Ac resin (Triskem Inc.), was tested. The overall yield of 213 Bi was exceeding 85% with 225 Ac breakthrough below 10 −4 %.
Retention of Pa(V) on the extraction chromatographic resins (DGA, TRU, TEVA, UTEVA and octanol resin) produced by Triskem International Company has been studied. The capacity factor k′ values of Pa(V) were determined in static experiments (batch technique) for a wide concentration range of nitric and hydrochloric acid solutions. The obtained data are useful to devise chromatographic separation of Pa(V) from other actinides.
V. Ostapenko合作论文数2
Stanislav V. Ermolaev合作论文数2
Stepan Kalmykov合作论文数Faculty of Chemistry, Lomonosov Moscow State University;Department of Chemistry, Lomonosov Moscow State University2
A.D. Zubenko合作论文数1e v lapshina合作论文数1Т. П. Калмыкова合作论文数1
Vasiliev Aleksandr N合作论文数Karlsruher Institut für Technologie (KIT), Institut für Nukleare Entsorgung, P.O. Box 3640, 76021 Karlsruhe, Germany. nidhu.banik@kit.edu.1
Elena V. Lapshina合作论文数1Bayirta V. Egorova合作论文数1
B. L. Zhuikov合作论文数1
Olga A. Fedorova合作论文数Laboratory of Photoactive Supramolecular Systems, A.N.Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences1
