The present study experimentally investigates the evaporative characteristics for a nanofluid droplet on heated surface. For experiments, the alumina (Al2O3) nanoparticles having a 50 nm average diameter were distributed in deionized (DI)water. The equilibrium contact angles (ECA) of DI-water on bare (without texturing) and hole-patterned textured (by µ-CNC machine) copper surfaces were 60o and 82o. Also, advancing and receding contact angles were 73.3o and 25.8o for bare surface, and 101.3o and 55.2o for textured surface. Surface temperature was fixed as 100±0.2oC, measured by resistance temperature detector (RTD) sensors with data logger. During the experiments, the ambient temperature was 22oC with the relative humidity of 32%. At the initial stage, the dynamic contact angle (DCA) of 0.01 vol.% nanofluid droplet on the textured surface drastically increased over its own ECA due to the generation of large bubbles inside the droplet. However, the contact angle of 0.1vol.% nanofluid droplet at t = 5 s was smaller than that of 0.01vol.% case because the increase in nanofluid concentration caused the reduction of surface tension. After that, DCA gradually decreased until dried out, and total evaporation time was significantly delayed in the case of textured surface. Moreover,the heat transfer characteristics during evaporation phenomenon was affected by the nanofluid concentration and the contact area with the heated surface.

The present study examines the transient characteristics of droplet growth and heat transfer during dropwise condensation process on different hydrophobic surfaces. The self-assembled monolayer (SAM) of n-octadecyl mercaptan was coated on the surface to change the surface wettability with the contact angles of 148° and 124°. A Canon EOS 7D camera and an Infinity K2 lens were used to capture the spontaneous images during condensation. From the experiment, three regimes were observed: in the first regime where the droplets were formed with nearly homogenous pattern, the heat transfer coefficient increased rapidly. In the second regime, both the droplet size and the liquid area fraction increased. In the third regime, coalescence among larger droplets was dominant, causing the decrease in the liquid area fraction with time. Moreover, the measured fall-off time was faster in the case with higher contact angle because of relatively low surface energy.

The main objective of this study is to examine the frosting characteristics affected by the surface wettability. Two different copper surfaces – bare and nano structured - were prepared for the experiments. Their static contact angles are 74° (bare: without surface treatment) and 154° (nano-structured), respectively. The temperature of the copper substrate was measured by using resistance temperature detector (RTD) sensors embedded inside small holes drilled at 1 mm underneath the surface. During the phase change, the temperature of the copper substrates remained -7.8±0.6°C and the ambient temperature was set as 24±0.5°C with the relative humidity of 45%. Images were captured by using the CMOS camera with the 5 second time interval. Film condensation occurred because of higher wettability of the bare copper surface. Film condensates were frozen at the early stage and frost crystal grew in the vertical direction. On the other hand, dropwise condensates formed on the nano-structured copper surface remained as the supercooled liquid phase for 44 minutes owing to its low wettability. After 4 minutes, frosting on the bare copper substrate was triggered and propagated until it covered the whole surface. The frosting was significantly delayed on the superhydrophobic copper surface due to the lower surface free energy. The different porous media composed of frost which directly influence the heat transfer characteristics was formed on each surfaces. Therefore, additional investigation for heat transfer phenomenon on superhydrophobic surface should be conducted.

For occurring dropwise condensation, the droplet growth behavior such as single droplet growth, coalescence, and fall-off of large droplets play a major role in regard to condensation heat transfer and water harvesting. The present study visualized the droplet growth behavior of dropwise condensation which might be controlled by the surface tension. We used three copper plate with different hole area fraction (i.e., ϕ=0, 0.148 and 0.439). Surface texturing was conducted by using a μ-computer numerical control (μ-CNC) machine and composed of micro-holes (diameter: 300 μm, depth: 200 μm) with 691 μm, 401 μm pitch. To make the hydrophobic surfaces, the copper surfaces were coated self-assembled monolayer (SAM). From the results, it was found that for only SAM coated surface, random coalescence occurred and affected the droplet growth significantly, whereas for textured SAM coated surfaces, the droplet started to be grown up at the textured holes and coalesced near the holes, indicating that capillary effects might affect the droplet growth mechanism. In particular, the fall-off time at which a coalesced droplet is removed away from the surface increased when the textured surfaces was used, because of surface tension effect increased by the textured holes.

The present study investigates numerically the thermal and flow characteristics and transient particle behavior in the conventional flame spray process by using the computational fluid dynamics (CFD) code (ANSYS Fluent V. 16.1). From geometrical consideration, it is noted that the deposition angle of a particle decreases drastically on a curved surface because of the curvature effect, and significantly affects the normal impact velocity of the particle. Numerical results indicated that the normal component of the particle impact velocity on the curved surface was lower than that on a flat surface by up to 5.7%. This result is significant with regard to the adhesive characteristics, as binding energy with the substrate is proportional to the square of the particle's normal impact velocity. The influence of spray distances and radius of the curved substrate were examined and the corresponding results would be useful in finding optimal operating conditions for the curved substrate. It was observed in this study that the spray distance exhibited a more dominant effect on the particle impact velocity, substantially associated with the coating quality of the deposited layer.

Polycrystalline Er3+/Yb3+ co-doped CaMoO4 (CaMoO4:Er3+/Yb3+) film was successfully fabricated by a spray coating method. Crystal structure, surface morphology and upconversion (UC) luminescent properties were investigated. Under 980-nm excitation, CaMoO4:Er3+/Yb3+ film exhibited strong green UC emissions at 530 and 550 nm (2H,11/2 --> 4S3/2 - 4I15/2) visible to the naked eye with a weak red emission near 660 nm (4F9/2 --> 4I15/2) corresponding to the intra 4f transitions of Er3+. A possible UC mechanism related to the pump-power dependence is discussed in detail.

Polycrystalline Er3+/Yb3+ co-doped CaMoO4 (CaMoO4:Er3+/Yb3+) film was successfully fabricated by a spray coating method. Crystal structure, surface morphology and upconversion (UC) luminescent properties were investigated. Under 980-nm excitation, CaMoO4:Er3+/Yb3+ film exhibited strong green UC emissions at 530 and 550 nm (2H,11/2 --> 4S3/2 - 4I15/2) visible to the naked eye with a weak red emission near 660 nm (4F9/2 --> 4I15/2) corresponding to the intra 4f transitions of Er3+. A possible UC mechanism related to the pump-power dependence is discussed in detail.

도심지에서 초고층 건축물 및 지하시설물과 연계된 복합건축물 등 건축물이 대형화·복합화 됨에 따라 공간정보 서비스 대상영역의 범위가 실내공간으로 급속하게 확대되어 가고 있으며, 이러한 변화는 모바일 디바이스의 보급, IT기술의 발달과 함께 향후 실내공간정보 기반의 안전 및 시설물관리, 실내내비게이션 등 다양한 서비스 수요를 창출하게 될 것으로 판단된다. 하지만 실내공간정보의 경우, 구축된 실내공간정보 데이터 품질에 대한 인증 기준이 부재하여 이에 따른 검증 기준 마련이 시급하다. 이에 본 연구에서는 국내외 연구사례를 검토하고 이를 기반으로 실내공간정보 품질검증 방안을 마련하여 2014년도 구축된 영등포역의 실내공간정보에 대해 검증실험을 실시하였다. 그 결과, 본 연구에서 제시한 실내공간정보 품질인증의 방법 및 기준에 대한 검증실험을 통해 균일하고 완성도 높은 품질의 데이터를 분류할 수 있음을 확인하였으며, 오류 발생 빈도가 높은 유형 등에 대해 파악할 수 있었다. 이러한 결과는 향후 실내공간정보 품질인증체계를 구축을 위한 기초자료로 활용될 수 있을 것이다.

The present study investigates numerically the airflow and thermal characteristics as well as the transient behavior of different particles such as nickel, copper, titanium, and tungsten during the flame spray process by using the computational fluid dynamics (CFD) code (Fluent Ver. 13.0). The combustion model was used in conjunction with the Arrhenius model to describe multi-component turbulent flows occurring during a chemical reaction. It was found that secondary air increased flame temperature and changed the flow direction which can affect the particle behavior. Further, the particle velocity and temperature rapidly changed with the decrease in particle size, causing faster absorption of thermal energy from the hot gas. Moreover, the particle experiences the phase change depending on the temperature and its phase significantly depends on the variation of heat capacity of selected particle. Because the particle phase prior to impact on the sample surface determines the quality of the coating layer, the secondary air pressure should be controlled carefully together with considering the particle type.

The nanocrystalline Ho3+/Tm3+/Yb3+ co-doped CaWO4 upconversion (UC) phosphors were successfully synthesized by a modified citrate complex method using microwave irradiation. The citrate complex precursors were heat-treated at temperature ranging from 300 to 700 °C for 3 h. Crystallization of the Ho3+/Tm3+/Yb3+ co-doped CaWO4 was detected at 400 °C, and entirely completed at 600 °C. The Ho3+/Tm3+/Yb3+ co-doped CaWO4 heat-treated at 600 °C showed primarily spherical and homogeneous morphology. Under the laser excitation of 980 nm, Ho3+/Tm3+/Yb3+ co-doped CaWO4 shows the bright white upconversion (UC) emission visible to the naked eye, which is composed of a blue emission at 475 nm from Tm3+, and green and red emissions at 543 and 651 nm respectively from Ho3+. The coordinates of Ho3+/Tm3+/Yb3+ co-doped CaWO4 in the Commission International De'eclairage (CIE) chromaticity diagram could be controlled from a cool to a warm white color depending on the Tm3+ and Ho3+ concentrations. The UC luminescent properties on Tm3+ and Ho3+ concentrations and related mechanism based on laser pump power were discussed in detail.

The present study aims to investigate the flow characteristics with respect to fuel type and equivalence ratio in the flame spray coating process. The flame spray flow is characterized by much complex phenomena including combustion, turbulent flows, and combined heat transfer. The present study numerically simulated the flam spray process and examined the gas dynamics involving combustion, gas temperature and velocity distributions in flame spray process by using commercial computational fluid dynamics (CFD) code of FLUENT (ver. 13.0). In particular, we studied the effect of fuel type and equivalence ratio on thermal and flow characteristics which could substantially affect the coating performance. From the results, it was found that the gas temperature distributions were varied with different fuels because of reaction times were different according to the fuel type. The equivalence ratio also could change the spatial flame distribution and the characteristics of coated layer on the substrate.

In this work, experimental results on the morphology and adhesive characteristics of flame-sprayed Ni-20 mass%Cr coating layers deposited on preheated SCM415 surfaces are presented. The flame spray distance was varied from 100 to 200 mm so as to investigate the change in the adhesive strength of the deposited layers. Commercially available Ni-20 mass%Cr particles with a mean diameter of 451 mu m were employed in the experiments, and computational fluid dynamics (CFD) simulations using a commercial code (FLUENT) were conducted so as to estimate the temperature and velocity distributions of continuous and discrete phases before impact on the substrate. From FE-SEM images of the deposited layers, it was observed that, as the flame spray distance decreased, the metal particle morphology exhibited a splash-like pattern and a short, stretched shape. Such morphological characteristics were induced by the higher particle momentum associated with very high gas velocities. In addition, as the flame spray distance decreased, the adhesive strength between the deposited layer and the substrate increased due to the stronger momentum of the molten metal particles. [doi:10.2320/matertrans.M2012217]

White LEDs (light-emitting diodes) are promising new- generation light sources which can replace conventional lamps due to their high reliability, low energy consumption and eco-friendly effects. This paper briefly reviews recent progress of oxy/nitride host phosphor and quantum dot materials with broad excitation band characteristics for phosphorconverted white LEDs. Among oxy/nitride host materials, M2Si5N8 : Eu2+, MAlSiN3 : Eu2+ M-SiON (M = Ca, Sr, Ba), alpha/beta-SiAlON : Eu2+ are excellent phosphors for white LED using blue-emitting chip. They have very broad excitation bands in the range of 440 similar to 460 nm and exhibit emission from green to red. In this paper, In this review we focus on recent developments in the crystal structure, luminescence and applications of the oxy/nitride phosphors for white LEDs. In addition, the application prospects and current trends of research and development of quantum dot phosphors are also discussed.

This paper reports on breakup characteristics of fuel droplet which includes metal nanoparticles. In order to develop a new injection system for nanoparticle-coated layers overcoming the conventional flame spray system, fundamental experiments were conducted to examine the interaction between a fuel droplet with nanoparticles and the external energy induced by the laser. In the experiments, this study used nickel nanoparticles whose size was under 100 nm to mix with kerosene as the fuel, and utilized a syringe pump and a metal needle to inject a fuel droplet. In particular, the Nd-YAG laser was adopted to give additional energy to the nanoparticles for evaporation of a fuel droplet containing nanoparticles. When the laser energy as 96 mJ was irradiated during the injection, it was observed that such an explosive evaporation occurred to break up a fuel droplet including nanoparticles, making the rapid increase in the ratio surface area to liquid volume. From this work, we suggest the possibility that the laser energy can be used for rapid evaporation of a fuel droplet.

The present study aims to examine the influence of flame spray distance on the thermal behavior of micro-metal particles and the morphological characteristics of $Ni_{20}Cr$ layers coated on the preheated SCM415 substrates by using the conventional flame spray system. Commercially available nickel-based $Ni_{20}Cr$ particles with a mean diameter of $45{\mu}m$ were used. In addition, CFD simulations using a commercial code (FLUENT ver. 6.3.26) were conducted to estimate temperature and velocity distributions of the continuous and discrete phases before impact on the substrate. From FE-SEM images of coated layers on the substrates, it was observed that as the spray distance decreased, the metal particle morphology showed splash-like patterns and such a short stretch shape, resulting from higher particle momentums and the impact of partially melted particles. Moreover, it was found that the spray distance should be considered as one of important parameters in controlling the porosity and the adhesion strength.

We investigated the effect of substrate surface roughness on c-axis preferred orientation of ZnO films deposited by radio frequency (rf) magnetron sputtering. We used as substrates a bare Si(100), evaporated Au/Si(100), evaporated Al/Si(100), and sputtered Al/Si(100), of which rms roughness by atomic force microscope (AFM) were 0.127, 1.71, 2.11, and 6.5∼11.8 nm, respectively. The crystallinity and the c-axis preferred orientation of ZnO films strongly depended on the surface roughness of the used substrates.

The preheating effect of SCM415 steel substrates on the flattening behavior of Ni20Cr flame-sprayed particles was investigated in a temperature range from 278 K to 523K. In the present study, we calculated the particle temperature and velocity distributions of the continuous and discrete phases before collision with the substrate by using a computational fluid dynamics (CFD) code of Fluent (ver. 6.3.26). Particle velocity and gas temperature decreased rapidly in the radial direction while the particles traveled toward the substrate, suggesting that substrate size and distance from the nozzle should be carefully controlled to improve coating quality. The conventional flame spray gun was used to accelerate molten particles and K-type thermocouples were used to monitor the substrate temperature during a preheating process. Commercially available nickel-based Ni20Cr particles with a mean diameter of 45 mu m and 20 mu m were used for experiments to examine the particle size effect on the coating characteristics. Herein we present FE-SEM images of coated layers on the substrates. As the substrate preheating temperature increased, the flatter surface morphology was seen at the interface between substrate and coating layer because of better wetting and corresponding higher shear adhesion strength. Moreover, the splat morphology was significantly dependent on the particle size. [doi:10.2320/matertrans.M2011068]