Elmshorn fell April 25, 2023, about 30 km northwest of the city of Hamburg (Germany). Shortly after the fall, 21 pieces were recovered totaling a mass of 4277 g. Elmshorn is a polymict and anomalous H3-6 chondritic, fragmental breccia. The rock is a mixture of typical H chondrite lithologies and clasts of intermediate H/L (or L, based on magnetic properties) chondrite origin. In some of the 21 pieces, the H chondrite lithologies dominate, while in others the H/L (or L) chondrite components are prevalent. The H/L chondrite assignment of these components is based on the mean composition of their olivines in equilibrated type 4 fragments (similar to Fa(21-22)). The physical properties like density (3.34 g cm(-3)) and magnetic susceptibility (log chi <5.0, with chi in 10(-9) m(3) kg(-1)) are typical for L chondrites, which is inconsistent with the oxygen isotope compositions: all eight O isotope analyses from two different fragments clearly fall into the H chondrite field. Thus, the fragments found in the strewn field vary in mineralogy, mineral chemistry, and physical properties but not in O isotope characteristics. The sample most intensively studied belongs to the stones dominated by H chondrite lithologies. The chemical composition and nucleosynthetic Cr and Ti isotope data are typical for ordinary chondrites. The noble gases in Elmshorn represent a mixture between cosmogenic, radiogenic, and primordially trapped noble gases, while a solar wind component can be excluded. Because the chondritic rock of Elmshorn contains (a) H chondrite parent body interior materials (of types 5 and 6), (b) chondrite parent body near-surface materials (of types 3 and 4), (c) fragments of an H/L chondrite (dominant in many stones), (d) shock-darkened fragments, and (e) clasts of various types of impact melts but no solar wind-implanted noble gases, the different components cannot have been part of a parent body regolith. The most straightforward explanation is that the fragmental breccia of Elmshorn represents a reaccreted rock after a catastrophic collision between an H chondrite parent body and another body with H/L (or L) chondrite characteristics but with deviating O isotope values (i.e. that of H chondrites), complete disruption of the bodies, mixing, and reassembly. This is the only straightforward way that the implantation of solar wind gases could have been avoided in this kind of complex breccia. The gas retention ages of about 2.8 Gyr possibly indicate the closure time after the catastrophic collision between H and H/L (or L) chondrite parent bodies, while the cosmic ray exposure age for Elmshorn, which had a preatmospheric radius of 25-40 cm, is similar to 17-20 Myr.
The lunar regolith breccia Dhofar 1769, which was found in 2012 as a single 125 g piece in the Zufar desert area of Oman, contains a relatively large, dark-colored impact melt breccia embedded in a fine-grained clastic matrix. The internal texture of the fragment indicates the repeated melt breccia formation on the lunar surface, their repeated brecciation, and mixing in second, third, and fourth generations of brecciated rock types. The chemical and mineralogical data reveal the incorporation of a feldspar-rich subophitic crystalline melt within a feldspar-rich microporphyritic crystalline melt breccia. This lithic paragenesis itself is embedded within a mafic, crystalline melt breccia. The entire breccia with the three different impact melts has been finally incorporated into the whole rock breccia. The three impact melts are mixtures of different source rocks and impact projectiles, based on the obtained minor and trace element compositions (in particular of Ni and the rare earth elements [REE]) of the impact melt lithologies. For all processes of impact melt formation, additional steps of their brecciation and re-lithification require a minimum number of seven impact processes.
On October 7, 2008, the asteroid 2008 TC3 exploded as it entered the Earth’s atmosphere, producing significant dust (in the atmosphere) and delivering thousands of stones in a strewn field in Sudan, collectively known as the Almahata Sitta (AhS) stones. About 600 fragments were officially recovered in 2008 and 2009. Further rocks were collected since the fall event by local people. From these stones, 249 were classified at the Institut für Planetologie in Münster (MS) known as MS‐xxx or MS‐MU‐xxx AhS subsamples. Most of these rocks are ureilitic in origin (168; 67%): 87 coarse‐grained ureilites, 60 fine‐grained ureilites, 15 ureilites with variable texture/mineralogy, four trachyandesites, and two polymict breccias. We identified 81 non‐ureilitic fragments, corresponding to 33% of the recovered samples studied in Münster. These included chondrites, namely 65 enstatite chondrites (43 EL; 22 EH), 11 ordinary chondrites (OC), one carbonaceous chondrite, and one unique R‐like chondrite. Furthermore, three samples represent a unique type of enstatite achondrite. Since all AhS stones must be regarded as individual specimens independent from each other, the number of fresh ureilite and enstatite chondrite falls in our meteorite collections has been increased by several hundred percent. Overall, the samples weigh between <1 and 250 g and have a mean mass of ~15 g. If we consider—almost 15 years after the fall—the mass calculations, observations during and after the asteroid entered the atmosphere, the mineralogy of the C1 stones AhS 91A and AhS 671, and the experimental work on fitting the asteroid spectrum (e.g., Goodrich et al., 2019; Jenniskens et al., 2010; Shaddad et al., 2010), the main portion of the meteoroid was likely made of the fine‐grained (carbonaceous) dust and was mostly lost in the atmosphere. In particular, the fact that C1 materials were found has important implications for interpreting asteroid 2008 TC3's early spectroscopic results. Goodrich et al. (2019) correctly suggested that if scientists had not recovered the “water‐free” samples (e.g., ureilites, enstatites, and OC) from the AhS strewn field, 2008 TC3 would have been assumed to be a carbonaceous chondrite meteoroid. Considering that the dominating mass of the exploding meteoroid consisted of carbonaceous materials, asteroid 2008 TC3 cannot be classified as a polymict ureilite; consequently, we state that the asteroid was a polymict carbonaceous chondrite breccia, specifically a polymict C1 object that may have formed by late accretion at least 50–100 Ma after calcium–aluminum‐rich inclusions.
In the last 7 years, three meteorites (Blaubeuren, Cloppenburg, and Machtenstein) found in Germany were identified as chondrites. Two of these rocks had been recovered from the impact sites decades ago but were not considered to be meteorites. The aim of this study is to fully characterize these three meteorites. Based on the compositional data on the silicates, namely olivine and low‐Ca pyroxene, these meteorites fit nicely within the H‐group ordinary chondrites. The brecciated texture of Blaubeuren and Cloppenburg (both H4‐5) is perfectly visible, whereas that of Machtenstein, officially classified as an H5 chondrite, is less obvious but was detected and described in this study. Considering chondrites in general, brecciated rocks are very common rather than an exception. The bulk rock degree of shock is S2 for Blaubeuren and Machtenstein and S3 for Cloppenburg. All samples show significant features of weathering. They have lost their original fusion crust and more than half (W3) or about half (W2‐3) of their original metal abundances. The oxygen isotope compositions of the three chondrites are consistent with those of other H chondrites; however, the Cloppenburg values are heavily disturbed and influenced by terrestrial weathering. This is supported by the occurrence of the very rare hydrated iron phosphate mineral vivianite (Fe2+Fe2+2[PO4]2·8H2O), which indicates that the chondrite was weathered in a very wet environment. The terrestrial ages of Blaubeuren (~9.2 ka), Cloppenburg (~5.4 ka), and Machtenstein (~1.8 ka) show that these chondrites are very similar in their degree of alteration and terrestrial age compared to meteorite finds from relatively wet terrestrial environments. They still contain abundant metal, although, as noted, the oxygen isotope data indicate substantial weathering of Cloppenburg. The bulk compositions of the three meteorites are typical for H chondrites, although terrestrial alteration has slightly modified the concentrations, leading in general to a loss of Fe, Co, and Ni due to preferential alteration of metals and sulfides. As exceptions, Co and Ni concentrations in Machtenstein, which has the shortest terrestrial age, are typical for H chondrites. The chemical data show no enrichments in Ba and Sr, as is often observed in different meteorite groups of desert finds.
Introduction: Carbon is of utmost importance for the volatile inventory of Earth. Although enriched in surface reservoirs as both organic and inorganic carbon, bulk Earth is highly depleted when compared to solar system abundances. Indeed, inner solar system material that eventually formed planetesimals and protoplanets accreting to Earth was subjected to high temperature processes causing loss of volatile carbon compounds [1,2]. A refractory phase that possibly survived high temperature processing is graphite which is present, e.g., in reduced assemblages of enstatite chondrites. These are considered as possible terrestrial building blocks, e.g., based on their isotopic similarity in oxygen, Cr and other isotopes [e.g., 3,4]. Isotopic analyses of carbon in graphite can provide important insights into the source materials involved in the accretion of terrestrial planets, as well as processes modifying primordial compositions by thermal processes in the solar nebula or on meteorite parent bodies. Previous graphite analyses yielded δC values of –9‰ to +4‰ for enstatite chondrites [5] and –10‰ to 0‰ for ureilites [6,7]. Isotopic analyses of secondary ion mass spectrometry (SIMS) can provide additional insights by detecting variations at even smaller spatial scales. Samples and techniques: Among 136 ureilites and 59 enstatite chondrites preliminarily studied by optical microscopy, we selected 33 polished thin sections, comprising 19 ureilites and 11 enstatite chondrites for SIMS analyses, using the Cameca ims 1280-HR at University of Heidelberg (HIP). We applied two slightly different setups (S1/S2), with a 20 keV Cs primary ion beam of ~ 200 pA (S1) and ~ 400 pA (S2), and a raster size of 5 μm (7 μm during pre-sputtering). Negative secondary ions were accelerated to 10 keV. The secondary ion image was limited to 20 μm, with the dynamic transfer optical system (DTOS) being activated. C, C and CH2 were detected simultaneously in two Faraday cups (10 ) and one electron multiplier, respectively. The nominal mass resolving power was 5000 (S1) or 6000 (S2) for C, and 2500 for C and CH2. Typical C secondary ion intensities (normalised to the primary beam current) were IG = 610 cps/pA on graphite and IE = 310 cps/pA on epoxy. CH2/C ratios were used to discriminate and reject mixed analyses of epoxy and graphite and to correct for an instrumental mass bias which depends on the CH2/C ratio (Fig. 1). Including the time for beam centering, the analyses started after a total pre-sputtering time of ~190 s. Each analysis had 20 cycles with 7.5 s (S1) and 6 s (S2) integration time per cycle. USGS24 graphite powder (pressed at 0.5 GPa in a closed Al-capsule) was used as a primary standard (δCVPDB = –16.049‰ ± 0.035 [8]. During S2 a second reference material GR961 was added, which is a solid natural graphite sample from Sri Lanka (δCVPDB = –6.62‰ ± 0.04), in order to correct for a systematic bias induced by the presence of CH2 (Fig. 1) The typical repeatability of bias-corrected analyses was ± 0.6 ‰ (1sd) for USGS24 and ± 0.4 ‰ for GR961. The internal precision of an analysis (1sd) was typically < 0.15 ‰.
Carbon is of fundamental interest for constraining the volatile element inventory of terrestrial planets. In some meteorites, like ureilites and enstatite chondrites, graphite is the major carbon-carrier. Here, we report the in-situ analyses of graphite in 19 ureilites, 11 enstatite chondrites, and 3 graphite-bearing clasts in ordinary chondrites by secondary ion mass spectrometry (SIMS). In coarse-grained ureilites the obtained carbon-compositions of graphite range from –9.2‰ to –0.1‰ (δ13C). The carbon-composition tends to be homogeneous within a sample and correlates with the Fa content in olivine. In contrast, fine-grained ureilites exhibit considerable intra-sample heterogeneity, and graphite tends towards 13C-enriched compositions (up to +10.4‰). Isotopic and petrographic differences are presumably a result of post-igneous shock processing, including annealing during impact smelting. Enstatite chondrites host a variety of graphite morphologies, occurring in two distinct assemblages: Silicate-associated graphite (SAG) and metal-associated graphite (MAG). These assemblages show diverging carbon-compositions: SAG consistently exhibits δ13C in a narrow range between –4‰ and +1‰, very similar to the bulk silicate Earth value. In contrast, diverse compositions from –19.7‰ to +13.7‰ were observed for MAG. These differences are likely pre-accretionary in origin and potentially point towards isotopically distinct precursors. If Earth accreted from enstatite-chondrite-like material, carbon potentially hosted by Earth's core may have an isotopically light signature when compared to the mantle. Although graphite-bearing clasts in unequilibrated ordinary chondrites (UOCs) are extraordinarily rare, these clasts are of particular interest as they might represent materials, not corresponding to known meteorites. Graphite from these clasts show coinciding carbon-compositions with a mean δ13C close to –1‰. Although the coinciding compositions might argue for a genetic relationship among the clasts, petrographic evidence suggests they have experienced distinct thermal histories.