Understanding the bending behaviour of a crystal onto a flexible platform is crucial for flexible electronics. The Young’s modulus, a measure of how easily a material deforms, plays a critical role in the coupled deformation of a crystal on a flexible substrate, as well as the transfer of strain from the substrate onto the layer. Here, we report on the bending behaviour of gallium selenide (GaSe), a van der Waals semiconductor with a small Young’s modulus and strain-dependent electronic band structure. A controllable, reproducible uniaxial strain, ϵ, is applied to nanometer-thick GaSe layers via their bending on a mica substrate. The spectral shift ΔE of the room temperature photoluminescence emission corresponds to a strain coefficient ΔE/ϵ of up to ~100 eV, the largest value reported in the literature to date. This is accompanied by coupled electronic and vibrational states under strain-induced resonant excitation conditions, as probed by Raman spectroscopy.

A simple method of measuring the vibrational response of a thin film membrane was developed. Piezoelectric excitation and acoustic detection (using a microphone) allowed the vibrational spectra of thin membranes to be measured in the kHz range. Vibrational frequencies were used to determine Young's modulus in thin (mu m) solvent tensioned films of polydimethylsiloxane and to measure tension in ultrathin polystyrene films. Simulations of membrane motion generated vibrational spectra that agreed with the results of experiments for different membrane shapes.

Video imaging was used to study large-slope folded telephone cord blister formation in solvent swollen films of polydimethylsiloxane (PDMS) elastomers. Chlorobenzene, chloroform, heptane and toluene were used to swell PDMS films with thickness values in the range 15 mu m < h < 223 mu m supported on glass substrates. Measurements of the blister width, corrugation wavelength and blister growth speed were studied as a function of the film thickness for all four solvents. Modified theories of buckling were shown to accurately predict the film thickness dependence of the width and corrugation wavelength and a modified fracture mechanics approach was shown to reproduce the non-monotonic thickness dependence of the blister growth rates. Two critical thickness values were identified for telephone cord blisters formed on solvent swollen PDMS films-one corresponding to a lower critical thickness for blistering and the other corresponding to a peak in the thickness dependent blister growth rates. Blister formation is shown to be consistent with the existence of mixed modality in the growth of the crack tip at the film-substrate interface. Both critical thickness values are shown to depend upon the strength of the adhesive interactions between the film and the substrate and the Young's modulus of the films. A simple method of patterning surfaces with telephone cord blisters is also introduced.

The thickness dependence of telephone cord blister formation in thin films of solvent swollen polydimethylsiloxane (PDMS) was studied using a simple imaging setup. Chloroform was deposited on top of PDMS that had been spin coated on to glass slides coated with a thin wax layer. After an initial thickness dependent nucleation time, straight-sided blisters were observed to form on the films. These later developed into sinusoidal telephone cord blisters. Movies of the growing telephone cord blisters were recorded at 200 fps for PDMS films with thickness values in the range 38 < h ≤ 223 μm. Software written in Python was used to analyse the movies and to extract the thickness dependence of the width of the telephone cord blisters as well as the wavelength of the sinusoidal corrugations and the blister growth rates. Data were interpreted in the context of theories of buckling and dynamic fracture mechanics.

A rotation stage was developed to allow the surface of bullet casings to be imaged under ultra-high vacuum (UHV) conditions using time-of-flight secondary ion mass spectrometry (ToF-SIMS). Experiments were performed over a period of seven months to determine how fingermarks deposited on the surface of Webley MkII revolver rounds change over time. Stitching software written in Python was used to combine image strips that were collected by performing ToF-SIMS analysis along the length of the revolver rounds. The ToF-SIMS analysis was performed by analysing a thin strip along the length of the casings, before rotating them through a few degrees and analysing a new strip. This process was repeated until the entire casing had been imaged. The resulting secondary ion images of the fingermarks were compared to optical images obtained from the same and similar rounds that had been exposed to cyanoacrylate fumes and subsequently stained using Basic Yellow 40 (BY40) dye. ToF-SIMS images were shown to display evidence of ridge and sweat pore level detail on samples that displayed no evidence of fingermarks when developed with cyanoacrylate and BY40. The effects of the curvature of the round casings on the morphology of fingermarks were also assessed. ToF SIMS images were compared to marks that had been deposited onto flat paper surfaces using ink. The distortions caused by differences in surface curvature and the deposition methods were found to be within acceptable limits.

The standard treatment for breast cancer is surgical removal mainly through breast-conserving surgery (BCS). We developed a new technique based on auto-fluorescence (AF) spectral imaging and Raman spectroscopy for fast intraoperative assessment of excision margins in BCS. A new wide-field AF imaging unit based on total internal reflection (TIR) was combined with a Raman spectroscopy microscope equipped with a 785 nm laser. The wavelength of the AF excitation was optimized to 365 nm in order to maximize the discrimination of adipose tissue. This approach allows for the non-adipose regions of tissue, which are at a higher risk of containing a tumor, to be targeted more efficiently by the Raman spectroscopy measurements. The integrated TIR-AF-Raman was tested on small tissue samples as well as fresh wide local excisions, delivering the analysis of the entire cruciate surface of BCS specimens (5.1 × 7.6 cm2) in less than 45 minutes and also providing information regarding the location of the tumor in the specimen. Full automation of the instrument and selection of a faster translation stage would allow for the measurement of BCS specimens within an intraoperative time scale (20 minutes). This study demonstrates that the TIR-AF Raman microscope represents a feasible step towards the development of a technique for intraoperative assessment of large WLE within intraoperative timescales.

Periodic wrinkling of a rigid capping layer on a deformable substrate provides a useful method for templating surface topography for a variety of novel applications. Many experiments have studied wrinkle formation during the compression of a rigid film on a relatively soft pre-strained elastic substrate, and most have focused on the regime where the substrate thickness can be considered semi-infinite relative to that of the film. As the relative thickness of the substrate is decreased, the bending stiffness of the film dominates, causing the bilayer to transition to either local wrinkling or a global buckling instability. In this work optical microscopy was used to study the critical parameters that determine the emergence of local wrinkling or global buckling of freestanding bilayer films consisting of a thin rigid polymer capping layer on a pre-strained elastomeric substrate. The thickness ratio of the film and substrate as well as the pre-strain were controlled and used to create a buckling phase diagram which describes the behaviour of the system as the ratio of the thickness of the substrate is decreased. A simple force balance model was developed to understand the thickness and strain dependences of the wrinkling and buckling modes, with excellent quantitative agreement being obtained with experiments using only independently measured material parameters.

Frustrated total internal reflection (FTIR) imaging was used to perform remote optical measurements of the forces/pressures exerted beneath shoes and feet during a number of different training activities including countermovement jumps, jogging and drop jumps. A single camera was used to simultaneously image two acrylic, FTIR waveguide imaging elements from below, at frame rates up to 200 frames per second. The images obtained using the camera were converted into pressure/force maps using a previously developed theory which combines the mechanics of contact of soft objects and the scattering of evanescent waves. The forces obtained from the optical measurements were shown to be in good agreement with measurements obtained from load cells placed beneath the FTIR imaging elements. The ability to produce accurate spatial maps of the force/pressure distribution beneath soft contacting objects such as feet and shoe outsoles at high frame rates has numerous potential applications in sports sciences and medicine.

A simple device based on the principle of frustrated total internal reflection was used to image the regions of contact between rubber objects and a large area perspex waveguide. Measurements of the intensity of light scattered at the interface were found to depend upon the magnitude of the applied force, the mechanical properties of the contacting material and the roughness of the contacting objects. The intensity/force response was found to have the same functional dependence irrespective of the position on the waveguide surface, but to scale by an amount that was proportional to the local intensity of light incident on the perspex/object interface. Once this spatial variation in intensity had been calibrated, the waveguide could be used to perform optical measurements of the forces/pressures exerted on the surface of the waveguide and to generate spatial maps of the pressure at frame rates up to 200 Hz. The resulting optical force platform was used to measure the time dependent evolution of the pressure distribution beneath a foot and a sports shoe during a foot strike event. A simple theory was developed to describe the light scattering phenomenon and to explain the relationship between the scattered light intensity and the applied force.

Fingermarks are a key form of physical evidence for identifying persons of interest and linking them to the scene of a crime. Visualising latent (hidden) fingermarks can be difficult and the correct choice of techniques is essential to develop and preserve any fingermarks or other (e.g. DNA) evidence that might be present. Metal surfaces (stainless steel in particular) have proven to be challenging substrates from which to reliably obtain fingermarks. This is a great cause for concern among police forces around the globe as many of the firearms, knives and other metal weapons used in violent crime are potentially valuable sources of fingermark evidence. In this study, a highly sensitive and non-destructive surface science technique called time of flight secondary ion mass spectroscopy (ToF-SIMS) was used to image fingermarks on metal surfaces. This technique was compared to a conventional superglue based fuming technique that was accompanied by a series of contrast enhancing dyes (basic yellow 40 (BY40), crystal violet (CV) and sudan black (SB)) on three different metal surfaces. The conventional techniques showed little to no evidence of fingermarks being present on the metal surfaces after a few days. However, ToF-SIMS revealed fingermarks on the same and similar substrates with an exceptional level of detail. The ToF-SIMS images demonstrated clear ridge definition as well as detail about sweat pore position and shape. All structures were found to persist for over 26 days after deposition when the samples were stored under ambient conditions.

X‐ray photoelectron spectroscopy (XPS) was used in conjunction with gas cluster ion source etching to analyze polystyrene and polyvinylpyrrolidone multilayer samples, total thickness ~15 μm, to establish optimal conditions for depth profiles over many μm in depth. Using standard conditions, these samples demonstrate a reduction in depth resolution and sputtering yield, which is shown to be partly due to X‐ray–induced damage and partly due to roughening of the sputtered surface. By limiting the X‐ray exposure, it was possible to retain depth resolution to a depth of approximately 5 μm; to obtain useful depth profiles beyond this depth, it was necessary to use sample rotation. The use of optimized conditions allowed the chemical integrity of the polymer layers to remain intact during the etching process with relatively sharp interfaces over the full depth of the films. Both the elemental intensities in XPS and the line shape of the C 1s peak could be used to determine the differences in chemical structure of the films in the depth profile. Detailed analysis suggests that a “stepwise” rotation scheme can maintain depth resolution better than continuous rotation during sputtering.

Fingerprints are widely used as a means of identifying persons of interest because of the highly individual nature of the spatial distribution and types of features (or minuta) found on the surface of a finger. This individuality has led to their wide application in the comparison of fingerprints found at crime scenes with those taken from known offenders and suspects in custody. However, despite recent advances in machine vision technology and image processing techniques, fingerprint evidence is still widely being collected using outdated practices involving ink and paper – a process that can be both time consuming and expensive. Reduction of forensic service budgets increasingly requires that evidence be gathered and processed more rapidly and efficiently. However, many of the existing digital fingerprint acquisition devices have proven too expensive to roll out on a large scale. As a result new, low-cost imaging technologies are required to increase the quality and throughput of the processing of fingerprint evidence. Here we describe an inexpensive approach to digital fingerprint acquisition that is based upon frustrated total internal reflection imaging. The quality and resolution of the images produced are shown to be as good as those currently acquired using ink and paper based methods. The same imaging technique is also shown to be capable of imaging powdered fingerprints that have been lifted from a crime scene using adhesive tape or gel lifters.

Forensic image retrieval and processing are vital tools in the fight against crime e.g. during fingerprint capture. However, despite recent advances in machine vision technology and image processing techniques (and contrary to the claims of popular fiction) forensic image retrieval is still widely being performed using outdated practices involving inkpads and paper. Ongoing changes in government policy, increasing crime rates and the reduction of forensic service budgets increasingly require that evidence be gathered and processed more rapidly and efficiently. A consequence of this is that new, low-cost imaging technologies are required to simultaneously increase the quality and throughput of the processing of evidence. This is particularly true in the burgeoning field of forensic footwear analysis, where images of shoe prints are being used to link individuals to crime scenes. Here we describe one such approach based upon frustrated total internal reflection imaging that can be used to acquire images of regions where shoes contact rigid surfaces.

An instrument was developed for measuring real time changes in the surface tension and viscosity of multicomponent droplets of miscible liquids and other soft materials. Droplets containing glycerol and water were supported on superamphiphobic surfaces and vibrated by applying a short mechanical impulse. Laser light was refracted through the droplets and allowed to fall on the surface of a photodiode. Time dependent variations in the intensity measured by the photodiode during vibration were used to monitor the decay of the droplet oscillations. The frequencies and spectral widths of the droplet vibrational resonances were then obtained from Fourier transforms of these time dependent intensity signals. A recently developed model of viscoelastic droplet vibration was used along with these values and measurements of the drop dimensions to extract the surface tension and viscosity of the drops as they evaporated. Collection of data was automated and values of frequency, spectral width, drop size, surface tension and viscosity were obtained with a time resolution of three seconds over a period of thirty minutes. The values of surface tension and viscosity obtained were shown to be in good agreement with literature values obtained from bulk glycerol/water solutions; thus validating the technique for wider application to other multicomponent liquids and soft matter systems.

Films formed through the drying of nanoparticle suspensions release the build-up of strain through a variety of different mechanisms including shear banding, crack formation and delamination. Here we show that important connections exist between these different phenomena: delamination depends on the dynamics of crack hopping, which in turn is influenced by the presence of shear bands. We also show that delamination does not occur uniformly across the film. As cracks hop they locally initiate the delamination of the film which warps with a timescale much longer than that associated with the hopping of cracks. The motion of a small region of the delamination front, where the shear component of interfacial crack propagation is believed to be enhanced, results in the deposition of a complex zig-zag pattern on the supporting substrate.

The rheological properties of microliter sized drops of polymer solutions were investigated using measurements of their mechanical vibrational response. Drops were suspended on superamphiphobic substrates and vibrated by the application of a short mechanical impulse. Surface vibrations were monitored by refracting laser light through the drops and focusing the refracted light onto the surface of a photodiode. Time dependent variations in the photodiode output were Fourier transformed to obtain the frequency and spectral width of the mechanical resonances of the drops. These quantities were related to the frequency dependent shear storage and loss moduli (G' and G″, respectively) using a simple theoretical model. The resulting rheological properties were found to be in agreement with microrheology measurements of the same solutions. Drop vibration therefore provides a fast and accurate method of quantifying the rheological properties of single drops.

The adsorption of Ca vapor on phenyl-C-61-butyric acid methyl ester (PCBM) at 300 K has been studied by X-ray photoelectron spectroscopy (XPS), low-energy He+ ion scattering spectroscopy (LEIS), adsorption microcalorimetry, and atomic beam/surface scattering. This interface commonly occurs in some of the highest efficiency organic solar cells. It is found that over 10 nm of the PCBM undergoes aggressive reaction with the Ca vapor to make the Ca carboxylate of PCBM. This thick reacted layer, which was not previously known to be present, lies at the interface between the metallic Ca film and PCBM and is expected to influence charge transfer across that interface during photovoltaic operation. The heat of Ca adsorption is very high below 0.03 ML (800-850 kJ/mol) due to reaction of Ca with impurities. Between 0.05 and 0.4 ML, the heat of adsorption is 624 kJ/mol and nearly constant. This heat is assigned to the reaction of Ca with subsurface methyl ester groups to form the Ca carboxylate of PCBM. This assignment is supported by the shift of the 0 is XPS peak of PCBM toward lower binding energy (BE) due to this reaction with Ca, and the absence of Ca LEIS signal, below 0.4 ML coverage. Conversely, the C is XPS peak shifts toward higher BE due to downward band bending. Beyond 0.4 ML, the heat of adsorption decreases nearly exponentially to the sublimation enthalpy of Ca (178 kJ/mol) by 3 ML, attributed to the formation of Ca(solid) nanoparticles on the surface and eventually a continuous Ca film. This model is supported by LEIS. Impinging Ca atoms face a kinetic competition between diffusing subsurface to react with methyl ester groups of PCBM and the formation and growth of three-dimensional Ca clusters on the surface. The total extent of reaction of Ca with subsurface ester groups to make the Ca carboxylate of PCBM is equivalent to similar to 14 layers of reacted PCBM molecules or similar to 13 nm of reacted depth.