This work is an attempt to provide antistatic properties to a commercial epoxy resin made up with Epikote 1001(R) and Euredur 423(R). In this aim, two compounds were selected which could be chemically bonded to the resin network: (2,3-epoxypropyl)trimethylammonium chloride which contains an epoxy group and the ammonium chloride group for the antistatic properties and also tetrabutylammonium 2-aminoethanesulfonate which contains an amino group and the tetrabutylammonium sulfonate group. Different formulations of the resin were prepared with both compounds, their viscosity and their resistivity were measured. Antistatic properties were obtained with the highest contents of epoxy compound. On the contrary no antistatic properties could be observed with the amino compound. Hardness and adherence tests have given suitable results for the antistatic formulations.

Copolymers bearing benzodithioate quaternary ammonium salts moieties are synthesized by reacting a supported dithioester with ammonium hydrogensulphide in a polar solvent. A preliminary study on models has led to the determination of the reaction parameters. The nucleophilic properties of the benzodithioate anion allow numerous possibilities especially chemical modification of the copolymer and grafting with or without cross-linking.

In order to improve the permanence of the plasticizer in a poly(vinylchloride) (PVC) compound we have studied the free radical polymerization and grafting of decyl methacrylate (DMA) onto PVC in the presence of a lead stabilizer. The influence of different parameters has been investigated and homogeneous PVC-g-PDMA copolymers have been obtained. Their molecular weights and the glass transition temperatures were consistent with the grafted nature of the copolymers.

Les acrylates dithiocarboxyliques contrairement à leur homologue thiocarbonylé homopolymérisent difficilement par voie radicalaire pour donner des polymères à faible masse molaire. La copolymérisation est par contre facile et les essais conduits avec quelques monomères usuels ont permis de calculer les paramètres e et Q d'Alfrey-Price ainsi que les coefficients de reactivité pour les différents coupes étudiés. Les acrylates dithiocarboxyliques complètent la gamme des monomères dithiocarboxylés dont l'étude commencée il y a quelques années, a permis d'accéder à une nouvelle classe de polymères fonctionnalisés.

Des acrylates porteurs de groupes dithiocarboxyliques sont obtenus avec des rendements élevés par action du chlorure d'acryloyle sur le sel de sodium d'hydroxy dithiobenzoates d'alkyl. Parmi les differentes méthodes de synthèses de dithiobenzoates hydroxylés utilisées, les meilleurs résultats ont été obtenus par réaction du sulfure de carbone sur un phénate alcalin dans le DMSO et à partir d'hydroxy benzonitriles et thiols par une séquence d'hydrochloration-sulfuration.

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNucleophilic substitution by benzodithioate anionsChantal Bonnans-Plaisance and Jean-Claude Gressier Cite this: J. Chem. Educ. 1988, 65, 1, 93Publication Date (Print):January 1, 1988Publication History Received3 August 2009Published online1 January 1988Published inissue 1 January 1988https://doi.org/10.1021/ed065p93Request reuse permissions Article Views385Altmetric-Citations3LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (2 MB) Get e-Alertsclose Get e-Alerts

AbstractQuartäre Ammoniumsalze von Dithiobenzoesäuren reagieren mit Alkyl‐ bzw. Arylhalogeniden oder ‐dihalogeniden unter Bildung von symm. oder unsymm. Dithio‐ bzw. Bisdithioestern.

The synthesis and the characterization of poly (methyl methacrylate) (PMMA) grafted to poly(vinyl chloride) (PVC) through benzodithioate groups are studied. Unlike results generally obtained with conventional free-radical initiators for systems involving PVC and MMA, high conversions, and grafting efficiencies are achieved with azobis-isobutyronitrile. The paper describes the synthesis of p-vinylbenzodithioate-containing PVC and the dependence of the characteristics of PVC-g-PMMA on the composition of the reaction mixture. Characterization of the graft copolymers includes UV and IR spectroscopy, GPC, and microstructure analysis by removal of PMMA side chains by aminolysis of dithioesters groups. Intrinsic viscosity, glass transition temperature, and thermal sensitivity were investigated to confirm the grafted nature of the copolymer.

Die Makromolekulare Chemie, Rapid CommunicationsVolume 4, Issue 6 p. 387-391 Article Substitution of chlorine in poly(vinyl chloride) by phenylthiocarbonylthio groups Chantal Bonnans-Plaisance, Laboratoire de Physicochimie et Photochimie Organiques, Université du Maine, 72017 Le Mans, FranceSearch for more papers by this authorJean-Claude Gressier, Corresponding Author Laboratoire de Physicochimie et Photochimie Organiques, Université du Maine, 72017 Le Mans, France Jean-Claude Gressier, Laboratoire de Physicochimie et Photochimie Organiques, Université du Maine, 72017 Le Mans, France Guy Levesque, Laboratoire des Composés Thio-organiques, Université, 14032 Caen, FranceSearch for more papers by this authorGuy Levesque, Corresponding Author Laboratoire de Physicochimie et Photochimie Organiques, Université du Maine, 72017 Le Mans, France Jean-Claude Gressier, Laboratoire de Physicochimie et Photochimie Organiques, Université du Maine, 72017 Le Mans, France Guy Levesque, Laboratoire des Composés Thio-organiques, Université, 14032 Caen, FranceSearch for more papers by this author Chantal Bonnans-Plaisance, Laboratoire de Physicochimie et Photochimie Organiques, Université du Maine, 72017 Le Mans, FranceSearch for more papers by this authorJean-Claude Gressier, Corresponding Author Laboratoire de Physicochimie et Photochimie Organiques, Université du Maine, 72017 Le Mans, France Jean-Claude Gressier, Laboratoire de Physicochimie et Photochimie Organiques, Université du Maine, 72017 Le Mans, France Guy Levesque, Laboratoire des Composés Thio-organiques, Université, 14032 Caen, FranceSearch for more papers by this authorGuy Levesque, Corresponding Author Laboratoire de Physicochimie et Photochimie Organiques, Université du Maine, 72017 Le Mans, France Jean-Claude Gressier, Laboratoire de Physicochimie et Photochimie Organiques, Université du Maine, 72017 Le Mans, France Guy Levesque, Laboratoire des Composés Thio-organiques, Université, 14032 Caen, FranceSearch for more papers by this author First published: June 1983 https://doi.org/10.1002/marc.1983.030040607Citations: 14AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinked InRedditWechat Citing Literature Volume4, Issue6June 1983Pages 387-391 RelatedInformation

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPolymer-supported transition-metal complexes. 2. Synthesis and Moessbauer investigation of copolymers containing polynuclear iron carbonyl complexesJ. C. Gressier, G. Levesque, H. Patin, and F. VarretCite this: Macromolecules 1983, 16, 10, 1577–1581Publication Date (Print):October 1, 1983Publication History Published online1 May 2002Published inissue 1 October 1983https://pubs.acs.org/doi/10.1021/ma00244a005https://doi.org/10.1021/ma00244a005research-articleACS PublicationsRequest reuse permissionsArticle Views109Altmetric-Citations11LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts

The synthesis of appropriate monomers bearing alkylidyne tricobaltnonacarbonyl cluster or sulfido tricobalt heptacarbonyl cluster is described. Organometallic copolymers are obtained by free-radical copolymerisation with other vinyl monomers. Direct metallation of macromolecules containing the dithioester or the thioamide functional groups was also studied. We show that the copolymerisation method is more convenient for the synthesis of pure materials containing a variable amount of definite cluster units. The potentiality of these new organometallic polymers with regard to homogeneous catalysis and for the modification of electrode surfaces is also discussed.

Les polythioamides aromatiques sont accessibles par polycondensation des bis(dithioesters) d'alkyle et/ou de carboxyméthyle avec des diamines aromatiques ou aliphatiques en milieu aqueux ou organique. Nous avons précisé l'influence du noyau aromatique sur le comportement du polymère en solution et sur quelques caractéristiques thermiques des polycondensats. Leur stabilité thermique est sensiblement améliorée par rapport à celle des composés aliphatiques, surtout lorsque cycle et groupements fonctionnels sont conjugués entre eux.

Chemischer InformationsdienstVolume 13, Issue 14 Heterocyclic Compounds ChemInform Abstract: 4,5-DIHYDROIMIDAZOLES FROM DITHIOCARBOXYLIC ESTERS, THIOCARBOXAMIDES, OR NITRILES G. LEVESQUE, G. LEVESQUESearch for more papers by this authorJ.-C. GRESSIER, J.-C. GRESSIERSearch for more papers by this authorM. PROUST, M. PROUSTSearch for more papers by this author G. LEVESQUE, G. LEVESQUESearch for more papers by this authorJ.-C. GRESSIER, J.-C. GRESSIERSearch for more papers by this authorM. PROUST, M. PROUSTSearch for more papers by this author First published: April 6, 1982 https://doi.org/10.1002/chin.198214197AboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat No abstract is available for this article. Volume13, Issue14April 6, 1982 RelatedInformation

Les bis(n-dodécyle dithiocarboxylates) sont accessibles en deux étapes à partir des dinitriles avec des rendements souvent excellents; ces composés sont cristallisés, stables et stockables et leur haute pureté permet de les utiliser pour la polycondensation avec les diamines. Les tétrathioadipates se dégradent facilement en milieu basique pour donner, entre autres, un dithioester conjugué suivant une réaction comparable à la cyclisation, de Dieckmann des diesters, et leur cas a été étudié en détail.