Biochar has attracted much attention for remediating the sites contaminated with heavy metals and radionuclides due to its lowcost and high adsorption affinity. However, little is known about howcolloidal biochar influences U(VI) transport in the environment. In this study, column experiments were conducted to investigate the individual and co-transport of U(VI) and biochar colloids (BC) in quartz sand heterogeneous media. Results showed that the transport of U(VI) in the individual transport system was pH-dependent and insensitive to ionic strength, whereas the individual BC transportwasmore sensitive to the changes in ionic strength compared to those in pH, indicating that electrostatic interaction plays a major role during BC transport but chemical interaction dominates U(VI) transport. In the presence of BC, the transport of U(VI) was significantly facilitated because of U(VI) adsorption on BC. The existence of low concentration of U(VI) (2.5 x 10(-6) M), however, did not affect the breakthrough curves (BTCs) of BC, except for the co-transport at relatively high ionic strength (100 mM) where BC transport was impeded due to the decrease of colloid suspension stability. Colloid size exclusion effect was evidenced by the evolution of particle size and zeta potential of the effluents. The transport of BC in both the individual and co-transport systems could be described by a two-site kinetic attachment/detachment model. This work implies that a risk assessment of BC facilitated heavy metal transport should be carefully considered when biochar is applied to the remediation of heavy metal contaminated sites. (c) 2021 Published by Elsevier B.V.

Abstract China is considering Beishan granitic formation (Gansu Province, China) as the site for high-level radioactive waste (HLW) repositories. Thus, it is crucial to understand the transport behavior of radionuclide in Beishan granitic media under disposal conditions. In this context, the co-transport of U(VI) (as the representative of radionuclides) and bentonite colloid (BC, from erosion of compacted bentonite) in particulate Beishan granite was studied as a function of important in-situ factors, such as BC concentration, ionic strength, pH and flow rate. We found that the increase of BC concentration (BC = 240–480 mg/L) did not affect the transport of individual BC, whereas it significantly facilitated the transport of U(VI). The increase of ionic strength (I = 0.001–0.01 M NaCl) or decrease of pH (pH = 7.50–5.40) obviously inhibited the BC transport, where these inhibiting effects were relatively slight for the transport of U(VI). The increase of flow rate significantly facilitated both the transport of BC and U(VI). Finally, a two-site kinetic attachment/detachment model was applied to describe the breakthrough curves of individual and co-transport of BC. The experimental and modeling results of this study have a significant implication on the safety assessment of HLW repositories built in granitic formation.

Dissolved silicic acid in the environment has strong affinity for actinides (An), but An(III)-silicate colloids have been scarcely investigated. In this study, Eu(III)-silicate colloids, an analogue to An(III)-silicate, were prepared and the aggregation kinetics of the colloids was investigated as a function of Eu content (Si/Eu molar ratio), pH, background electrolyte (NaCl, NaNO3, NaClO4, KCl and CsCl) and fulvic acid (FA). Results indicated that the colloids with higher Si/Eu molar ratio exhibited higher stability under the same conditions. The stability of the colloids increased with increasing aqueous pH (7.1-9.4) and decreasing ionic strength, and the inhibition effect of monovalent electrolytes on the colloid stability followed the order of Na+ < K+ < Cs+ and Cl- < NO3- < ClO4-. In addition, the presence of FA significantly increased the stability of the colloids. The dependence of the stability on the chemical conditions in all cases could be illustrated by DLVO theory. Disaggregation kinetics showed that the aggregation process of the colloids was not fully reversible, because a time-dependent size memory effect led to a bigger mean size of disaggregated colloids as compared to the initial ones. The present work provides detailed insight in the formation and stability of An(III)-silicate colloids under the alkaline conditions relevant to geological disposal of radioactive waste, which is critical for understanding the behavior of this type of colloids in the environment.