Inner disk chemistry offers a valuable window onto disk evolution and planet formation. Key planet formation processes, including pebble drift, planetesimal and planet formation, dust traps, and snow lines, determine the delivery rates of oxygen and carbon to the inner disk. As a result, measurements of molecules sensitive to the gas-phase C/O ratio, in disks over a range of ages, can constrain the relative importance and time evolution of these processes. Here we report JWST/MIRI observations of T Tauri disks in the young cluster IC 348, extending to older ages previous studies of disks. Like younger disks, IC 348 sources show a broad range of molecular ratios, indicating diverse planet formation histories. However, the similar HCN/H_2O and C_2H_2/H_2O flux ratio distributions of IC 348 (2–5 Myr old) and Taurus (1–2 Myr old) sources imply little to no evolution in the inner disk C/O ratio over this time interval, even as disk masses decline by a factor of 5 on average. This result contradicts the general prediction of increasing C/O ratio with time in models of disk chemical evolution, indicating the need to better understand the interplay between (and efficiencies of) planet formation and disk evolution processes. We also find that the cold-to-warm water flux ratios show no evolution and do not correlate with the hydrocarbon-to-water ratios. These results suggest that most inner T Tauri disks are not dominated by rapid icy pebble drift and avoid the ”meter-size barrier problem” once thought to be an obstacle to planet formation.

This work aims at providing fundamental general tools for the analysis of water spectra as observed in protoplanetary disks with JWST-MIRI. We analyze 25 high-quality spectra from the JDISC Survey reduced with asteroid calibrators as presented in K. M. Pontoppidan et al. (2024). First, we present a spectral atlas to illustrate the clustering of H2O transitions from different upper-level energies (E-u) and identify single (unblended) transitions that provide the most reliable measurements. With that, we demonstrate two important excitation effects: the opacity saturation of ortho-para line pairs that overlap, and the subthermal excitation of excitation of v = 1-1 lines scattered across the v = 0-0 rotational band. Second, we define a shorter list of fundamental lines spanning E-u = 1500-6000 K to develop simple line-ratio diagnostic diagrams for the radial temperature distribution of water in inner disks, which are interpreted using discrete temperature components and power-law radial gradients. Third, we report the detection of disk-rotation Doppler broadening of molecular lines, which confirms the radial distribution of water emission including, for the first time, the radially extended approximate to 170-220 K reservoir close to the snowline. The combination of measured line ratios and broadening suggests that drift-dominated disks have shallower temperature gradients with an extended cooler disk surface enriched by ice sublimation. We also report the first detection of an H2O-rich inner disk wind from narrow blueshifted absorption in the ro-vibrational lines. We summarize these findings and tools into a general recipe to make the study of water in planet-forming regions reliable, effective, and sustainable for samples of >100 disks.

The JWST Disk Infrared Spectral Chemistry Survey (JDISCS) aims to understand the evolution of the chemistry of inner protoplanetary disks using the Mid-InfraRed Instrument (MIRI) on the James Webb Space Telescope (JWST). With a growing sample of >30 disks, the survey implements a custom method to calibrate the MIRI Medium Resolution Spectrometer (MRS) to contrasts of better than 1:300 across its 4.9-28 micron spectral range. This is achieved using observations of Themis-family asteroids as precise empirical reference sources. High spectral contrast enables precise retrievals of physical parameters, searches for rare molecular species and isotopologues, and constraints on the inventories of carbon- and nitrogen-bearing species. JDISCS also offers significant improvements to the MRS wavelength and resolving power calibration. We describe the JDISCS calibrated data and demonstrate its quality using observations of the disk around the solar-mass young star FZ Tau. The FZ Tau MIRI spectrum is dominated by strong emission from warm water vapor. We show that the water and CO line emission originates from the disk surface and traces a range of gas temperatures of ~500-1500 K. We retrieve parameters for the observed CO and H2O lines, and show that they are consistent with a radial distribution represented by two temperature components. A high water abundance of n(H2O)~10^-4 fills the disk surface at least out to the 350 K isotherm at 1.5 au. We search the FZ Tau environs for extended emission detecting a large (radius of ~300 au) ring of emission from H2 gas surrounding FZ Tau, and discuss its origin.

We present high-resolution spectra and spectroastrometric (SA) measurements of fundamental rovibrational CO emission from nine nearby (≲300 pc) protoplanetary disks where large inner dust cavities have been observed. The emission-line profiles and SA signals are fit with a slab disk model that allows the eccentricity of the disk and intensity of the emission to vary as power laws. Six of the sources are well fit with our model, and three of these sources show asymmetric line profiles that can be fit by adopting a nonzero eccentricity. The three other sources have components in either their line profile or SA signal that are not captured by our disk model. Two of these sources (V892 Tau and CQ Tau) have multi-epoch observations that reveal significant variability. CQ Tau and AB Aur have CO line profiles with centrally peaked components that are similar to line profiles which have been interpreted as evidence of molecular gas arising from a wide-angle disk wind. Alternatively, emission from a circumplanetary disk could also account for this component. The interpretations of these results can be clarified in the future with additional epochs that will test the variability timescale of these SA signals. We discuss the utility of using high-resolution spectroscopy for probing the dynamics of gas in the disk and the scenarios that can give rise to profiles that are not fit with a simple disk model.

We present an analysis of the JDISC JWST/MIRI-MRS spectrum of Sz~114, an accreting M5 star surrounded by a large dust disk with a shallow gap at $\sim 39$ au. The spectrum is molecular-rich: we report the detection of water, CO, CO$_2$, HCN, C$_2$H$_2$, and H$_2$. The only identified atomic/ionic transition is from [NeII] at 12.81 micron. A distinct feature of this spectrum is the forest of water lines with the 17.22 micron emission surpassing that of most mid-to-late M-star disks by an order of magnitude in flux and aligning instead with disks of earlier-type stars. Moreover, flux ratios of C$_2$H$_2$/H$_2$O and HCN/H$_2$O in Sz~114 also resemble those of earlier-type disks, with a slightly elevated CO$_2$/H$_2$O ratio. While accretional heating can boost all infrared lines, the unusual properties of Sz~114 could be explained by the young age of the source, its formation under unusual initial conditions (a large massive disk), and the presence of dust substructures. The latter delays the inward drift of icy pebbles and help preserve a lower C/O ratio over an extended period. In contrast, mid-to-late M-star disks--which are typically faint, small in size, and likely lack significant substructures--may have more quickly depleted the outer icy reservoir and already evolved out of a water-rich inner disk phase. Our findings underscore the unexpected diversity within mid-infrared spectra of mid-to-late M-star disks, highlighting the need to expand the observational sample for a comprehensive understanding of their variations and thoroughly test pebble drift and planet formation models.

Previous analyses of mid-infrared water spectra from young protoplanetary disks observed with the Spitzer-IRS found an anticorrelation between water luminosity and the millimeter dust disk radius observed with ALMA. This trend was suggested to be evidence for a fundamental process of inner disk water enrichment proposed decades ago to explain some properties of the solar system, in which icy pebbles drift inward from the outer disk and sublimate after crossing the snow line. Previous analyses of IRS water spectra, however, were uncertain due to the low spectral resolution that blended lines together. We present new JWST-MIRI spectra of four disks, two compact and two large with multiple radial gaps, selected to test the scenario that water vapor inside the snow line is regulated by pebble drift. The higher spectral resolving power of MIRI-MRS now yields water spectra that separate individual lines, tracing upper level energies from 900 to 10,000 K. These spectra clearly reveal excess emission in the low-energy lines in compact disks compared to large disks, demonstrating an enhanced cool component with T ≈ 170–400 K and equivalent emitting radius R eq ≈ 1–10 au. We interpret the cool water emission as ice sublimation and vapor diffusion near the snow line, suggesting that there is indeed a higher inward mass flux of icy pebbles in compact disks. Observation of this process opens up multiple exciting prospects to study planet formation chemistry in inner disks with JWST.

CI Tau is currently the only T Tauri star with an inner protoplanetary disk that hosts a planet, CI Tau b, that has been detected by a radial velocity survey. This provides the unique opportunity to study disk features that were imprinted by that planet. We present multiepoch spectroscopic data, taken with NASA IRTF in 2022, of the 12 CO and hydrogen Pf β line emissions spanning nine consecutive nights, which is the proposed orbital period of CI Tau b. We find that the star’s accretion rate varied according to that nine-day period, indicative of companion-driven accretion. Analysis of the 12 CO emission lines reveals that the disk can be described with an inner and an outer component spanning orbital radii 0.05–0.13 au and 0.15–1.5 au, respectively. Both components have eccentricities of about 0.05 and arguments of periapsis that are oppositely aligned. We present a proof-of-concept hydrodynamic simulation that shows that a massive companion on a similarly eccentric orbit can recreate a similar disk structure. Our results allude to such a companion being located at an orbital distance of around 0.14 au. However, this planet’s orbital parameters may be inconsistent with those of CI Tau b, whose high eccentricity is likely not compatible with the low disk eccentricities inferred by our model.

The Orbiting Astronomical Satellite for Investigating Stellar Systems (OASIS) is a NASA Astrophysics MIDEX-class mission concept, with the stated goal of Following water from galaxies, through protostellar systems, to Earth’s oceans. This paper details the protoplanetary disk science achievable with OASIS. OASIS’s suite of heterodyne receivers allow for simultaneous, high spectral resolution observations of water emission lines spanning a large range of physical conditions within protoplanetary disks. These observations will allow us to map the spatial distribution of water vapor in disks across evolutionary stages and assess the importance of water, particularly the location of the midplane water snowline, to planet formation. OASIS will also detect the H2 isotopologue HD in 100+ disks, allowing for the most accurate determination of total protoplanetary disk gas mass to date. When combined with the contemporaneous water observations, the HD detection will also allow us to trace the evolution of water vapor across evolutionary stages. These observations will enable OASIS to characterize the time development of the water distribution and the role water plays in the process of planetary system formation.

We present an overview and first results from a M-band spectroscopic survey of planet-forming disks performed with iSHELL on the Infrared Telescope Facility, using two slits that provide resolving power R ≈ 60,000–92,000 (5–3.3 km s−1). iSHELL provides a nearly complete coverage at 4.52–5.24 μm in one shot, covering >50 lines from the R and P branches of 12CO and 13CO for each of multiple vibrational levels, and providing unprecedented information on the excitation of multiple emission and absorption components. Some of the most notable new findings of this survey are: (1) the detection of two CO Keplerian rings at <2 au (in HD 259431), (2) the detection of H2O rovibrational lines at 5 μm (in AS 205 N), and (3) the common kinematic variability of CO lines over timescales of 1–14 yr. By homogeneously analyzing this survey together with a previous survey of cooler stars, we discuss a unified view of CO spectra where emission and absorption components scan the disk surface across radii from a dust-free region within dust sublimation out to ≈10 au. We classify two fundamental types of CO line shapes interpreted as emission from Keplerian rings (double-peak lines) and a disk surface plus a low-velocity part of a wind (triangular lines), where CO excitation reflects different emitting regions (and their gas-to-dust ratio) rather than just the irradiation spectrum. A disk+wind interpretation for the triangular lines naturally explains several properties observed in CO spectra, including the line blueshifts, line shapes that turn into narrow absorption at high inclinations, and the frequency of disk winds as a function of the stellar type.

We reanalyze the multi-epoch direct detections of HD 88133 b and ups And b that were published in Piskorz et al. 2016 and Piskorz et al. 2017, respectively. Using simulations to attempt to reproduce the detections, we find that with the 6 and 7 $L$ band Keck/NIRSPEC epochs analyzed in the original works, the planets would not have been detectable unless they had unreasonably large radii. HD88133 and ups And both have fairly large stellar radii, which contributed to the difficulty in detecting the planets. We take this opportunity to consider how these planets may have been detectable with the small number of epochs originally presented by running simulations both with the upgraded NIRSPEC instrument and with near-zero primary velocities, as recommended by Buzard et al. 2021. While 7 $L$ band NIRSPEC2.0 epochs with near-zero primary velocities would have allowed a strong ($10.8\sigma$) detection of ups And b, many more than 6 $L$ band epochs would have been required for a strong detection of HD88133b, which could be due in part to both this system's large stellar radius and low stellar temperature. This work stresses the importance of careful analytic procedures and the usefulness of simulations in understanding the expected sensitivity of high-resolution spectroscopic data.

Physical processes that redistribute or remove angular momentum from protoplanetary disks can drive mass accretion onto the star and affect the outcome of planet formation. Despite ubiquitous evidence that protoplanetary disks are engaged in accretion, the process(es) responsible remain unclear. Here we present evidence for redshifted molecular absorption in the spectrum of a Class I source that indicates rapid inflow at the disk surface. High-resolution mid-infrared spectroscopy of GV Tau N reveals a rich absorption spectrum of individual lines of C2H2, HCN, NH3, and H2O. From the properties of the molecular absorption, we can infer that it carries a significant accretion rate (M)(abs) similar to 10(-8)-10(-7) M-circle dot yr(-1), comparable to the stellar accretion rates of active T Tauri stars. Thus, we may be observing disk accretion in action. The results may provide observational evidence for supersonic "surface accretion flows," which have been found in MHD simulations of magnetized disks. The observed spectra also represent the first detection of NH3 in the planet formation region of a protoplanetary disk. With NH3 only comparable in abundance to HCN, it cannot be a major missing reservoir of nitrogen. If, as expected, the dominant nitrogen reservoir in inner disks is instead N-2, its high volatility would make it difficult to incorporate into forming planets, which may help to explain the low nitrogen content of the bulk Earth.

Orbiting Astronomical Satellite for Investigating Stellar Systems (OASIS) is a space-based, MIDEX-class mission concept that employs a 17-meter diameter inflatable aperture with cryogenic heterodyne receivers, enabling high sensitivity and high spectral resolution (resolving power ≥106) observations at terahertz frequencies. OASIS science is targeting submillimeter and far-infrared transitions of H2O and its isotopologues, as well as deuterated molecular hydrogen (HD) and other molecular species from 660 to 80 μm, which are inaccessible to ground-based telescopes due to the opacity of Earth’s atmosphere. OASIS will have <20x the collecting area and ~5x the angular resolution of Herschel, and it complements the shorter wavelength capabilities of the James Webb Space Telescope. With its large collecting area and suite of terahertz heterodyne receivers, OASIS will have the sensitivity to follow the water trail from galaxies to oceans, as well as directly measure gas mass in a wide variety of astrophysical objects from observations of the ground-state HD line. OASIS will operate in a Sun-Earth L1 halo orbit that enables observations of large numbers of galaxies, protoplanetary systems, and solar system objects during the course of its 1-year baseline mission. OASIS embraces an overarching science theme of “following water from galaxies, through protostellar systems, to oceans.” This theme resonates with the NASA Astrophysics Roadmap and the 2010 Astrophysics Decadal Survey, and it is also highly complementary to the proposed Origins Space Telescope’s objectives.

HD 141569 is a Herbig Ae/Be star that straddles the boundary between the transition disks and debris disks. It is a low dust mass disk that reveals numerous structural elements (e.g., gaps and rings) that may point to young planets. It also exhibits a reservoir of CO gas observed at both millimeter and IR wavelengths. Previous observations reported a possible asymmetry in the CO gas emission. Herein the IR rovibrational emission lines are analyzed and modeled both spectroscopically and spectroastrometrically. We find emission features from both 12CO and 13CO isotopologues heated to a temperature of approximately 200 K in the radial extent of 13–60 au. We do not see evidence of the previously reported asymmetry in CO emission, our results being consistent with a Keplerian, axisymmetric emitting region. This raises the question of whether the emission profile may be evolving in time, possibly as a result of an orbiting feature in the inner disk such as a planet.

We present the largest survey of spectrally resolved mid-infrared water emission to date, with spectra for 11 disks obtained with the Michelle and TEXES spectrographs on Gemini North. Water emission is detected in 6 of 8 disks around classical T Tauri stars. Water emission is not detected in the transitional disks SR 24 N and SR 24 S, in spite of SR 24 S having pre-transitional disk properties like DoAr 44, which does show water emission (Salyk et al. 2015). With R~100,000, the TEXES water spectra have the highest spectral resolution possible at this time, and allow for detailed lineshape analysis. We find that the mid-IR water emission lines are similar to the "narrow component" in CO rovibrational emission (Banzatti & Pontoppidan 2015), consistent with disk radii of a few AU. The emission lines are either single peaked, or consistent with a double peak. Single-peaked emission lines cannot be produced with a Keplerian disk model, and may suggest that water participates in the disk winds proposed to explain single-peaked CO emission lines (Bast et al. 2011, Pontoppidan et al. 2011). Double-peaked emission lines can be used to determine the radius at which the line emission luminosity drops off. For HL Tau, the lower limit on this measured dropoff radius is consistent with the 13 AU dark ring (ALMA partnership et al. 2015). We also report variable line/continuum ratios from the disks around DR Tau and RW Aur, which we attribute to continuum changes and line flux changes, respectively. The reduction in RW Aur line flux corresponds with an observed dimming at visible wavelengths (Rodriguez et al. 2013).

HD 100546 is a Herbig Ae/Be star surrounded by a disk with a large central region that is cleared of gas and dust (i.e., an inner hole). High-resolution near-infrared spectroscopy reveals a rich emission spectrum of fundamental rovibrational CO emission lines whose time variable properties point to the presence of an orbiting companion within the hole. The Doppler shift and spectroastrometric signal of the CO v = 1−0 P26 line, observed from 2003 to 2013, are consistent with a source of excess CO emission that orbits the star near the inner rim of the disk. The properties of the excess emission are consistent with those of a circumplanetary disk. In this paper, we report follow-up observations that confirm our earlier prediction that the orbiting source of excess emission would disappear behind the near side of the inner rim of the outer disk in 2017. We find that while the hot band CO lines remained unchanged in 2017, the v = 1−0 P26 line and its spectroastrometric signal returned to the profile observed in 2003. With these new observations, we further constrain the origin of the emission and discuss possible ways of confirming the presence of an orbiting planetary companion in the inner disk.

We report the detection of hot H 2 O and OH emission from the Herbig Ae/Be star HD 101412 using the Cryogenic Infrared Echelle Spectrograph on the Very Large Telescope. Previous studies of Herbig Ae/Be stars have shown the presence of OH around some of these sources, but H 2 O has proven more elusive. While marginal water emission has been reported in the mid-infrared, and a few Herbig Ae/Be stars show water emission in the far-infrared, water emission near 2.9 μ m has not been previously detected. We apply slab models to the rovibrational OH, H 2 O, and CO spectra of this source and show that the molecules are consistent with being cospatial. We discuss the possibility that the detection of the CO overtone bandhead emission, detection of water emission, and the large line to continuum contrast of the OH lines may be connected to its high inclination and the λ Boö nature of this star. If the low abundance of refractories results from the selective accretion of gas relative to dust, the inner disk of HD 101412 should be strongly dust-depleted, allowing us to probe deeper columns of molecular gas in the disk, enhancing its molecular emission. Our detection of C- and O-bearing molecules from the inner disk of HD 101412 is consistent with the expected presence, in this scenario, of abundant volatiles in the accreting gas.

We present analysis of commissioning M-band data acquired with the infrared echelle spectrograph (iSHELL) on NASA's Infrared Telescope Facility. In this paper we describe the delivered performance of the instrument for these M-band observations and the data reduction process. The feasibility of using iSHELL for spectro-astrometry is tested on the Herbig Ae/Be star HD. 179218 and we show that sub-milliarcsecond fidelity is achievable.

We present high-resolution spectroscopy of mid-infrared molecular emission from two very active T Tauri stars, AS 205 N. and DR Tau. In addition to measuring high signal-to-noise line profiles of water, we report the first spectrally resolved mid-infrared line profiles of HCN emission from protoplanetary disks. The similar line profiles and temperatures of the HCN and water emission indicate that they arise in the same volume of the disk atmosphere, within 1-2 au of the star. The results support the earlier suggestion that the observed trend of increasing HCN/water emission with disk mass is a chemical fingerprint of planetesimal formation and core accretion in action. In addition to directly constraining the emitting radii of the molecules, the high-resolution spectra also help break degeneracies between temperature and column density in deriving molecular abundances from low-resolution mid-infrared spectra. As a result, they can improve our understanding of the extent to which inner disks are chemically active. Contrary to predictions from HCN excitation studies carried out for AS 205 N, the mid-infrared and near-infrared line profiles of HCN are remarkably similar. The discrepancy may indicate that HCN is not abundant beyond a few au or that infrared pumping of HCN does not dominate at these distances.