Suburban land use is expanding in many parts of the United States and there is a need to better understand the potential water-quality impacts of this change. This study characterized groundwater quality in a sandy, water-table aquifer influenced by suburban development and compared the results to known patterns in water chemistry associated with natural, background conditions and agricultural effects. Samples for nutrients, major ions, and isotopes of N and O in NO were collected in 2011 beneath turfgrass from 29 shallow wells (median depth 3.7 m) and from 18 deeper wells (median depth 16.9 m) in a long-term suburban development. Nitrate (as N) concentrations in groundwater beneath turfgrass were highly variable (0.02-22.3 mg L) with a median of 2.7 mg L, which is higher than natural water chemistry (>0.4 mg L; Na-Cl-HCO water type), but significantly lower than concentrations beneath a nearby agricultural area (median 16.9 mg L; < .0001). Dissolved Fe concentrations in shallow suburban groundwater, attributed to chelated Fe in turfgrass fertilizers, were significantly higher ( < .005) than concentrations from the agricultural site, although a Ca-Mg-Cl-NO water type was dominant in both areas. A Na-Cl-NO water type indicated a septic-system source for nitrate in deep suburban groundwater (0.06-6.0 mg L; median 1.5 mg L). Isotopic data indicated denitrification; however, geochemical techniques were more helpful in identifying nitrate sources. Results indicate that suburban expansion into agricultural areas may significantly decrease overall nitrate concentrations in groundwater, but excessive turfgrass fertilization could result in localized contamination.

A numerical groundwater-flow model was used to characterize the source area and volume of Phillips Branch, a baseflow-dominated stream incising a highly permeable unconfined aquifer on the low relief Delmarva Peninsula, USA. Particle-tracking analyses indicate that the source area (5.51 km2) is ∼20% smaller than the topographically defined watershed (6.85 km2), and recharge entering ∼37% of the surface watershed does not discharge to Phillips Branch. Groundwater residence time within the source volume ranges from a few days to almost 100 years, with 95% of the volume “flushing” within 50 years. Artificial discharge from groundwater pumping alters the shape of the source area and reduces baseflow due to the interception of stream flow paths, but has limited impacts on the residence time of groundwater discharged as baseflow. In contrast, artificial recharge from land-based wastewater disposal substantially reduces the source area, lowers the range in residence time due to the elimination of older flow paths to the stream, and leads to increased discharge to adjacent surface-water bodies. This research suggests that, in this and similar hydrogeologic settings, the “watershed” approach to water-resource management may be limited, particularly where anthropogenic stresses alter the transport of soluble contaminants through highly permeable unconfined aquifers.