A spin-triplet superconductor can harbor Majorana bound states that can be used in topological quantum computing. Recently, K2Cr3As3 and its variants with critical temperature Tc as high as 8 kelvin have emerged as a new class of superconductors with ferromagnetic spin fluctuations. Here, we report a discovery in K2Cr3As3 single crystal that the spin susceptibility measured by 75As Knight shift below Tc is unchanged with the magnetic field H0 applied in the ab plane but vanishes toward zero temperature when H0 is along the c axis, which unambiguously establishes this compound as a spin-triplet superconductor described by a vector order parameter d→ parallel to the c axis. Combining with point nodal gap, we show that K2Cr3As3 is a new platform for the study of topological superconductivity and its possible technical application.

Although superconductivity in the vicinity of antiferromagnetic (AFM) instability has been extensively explored in the last three decades or so, superconductivity in compounds with a background of ferromagnetic (FM) spin fluctuations is still rare. We report 75As nuclear quadrupole resonance measurements on the A2Cr3As3 family, which is the first group of Cr-based superconductors at ambient pressure, with A being alkali elements. From the temperature dependence of the spin-lattice relaxation rate (1/T1), we find that by changing A in the order of A=Na, Na0.75K0.25, K, and Rb, the system is tuned to approach a FM quantum critical point (QCP). This may be ascribed to the Cr2-As2-Cr2 bond angle that decreases towards 90 degrees, which enhances the FM interaction via the Cr2-As2-Cr2 path. Upon moving away from the QCP, the superconducting transition temperature Tsc increases progressively up to 8.0 K in Na2Cr3As3, which is in sharp contrast to the AFM case where Tsc usually shows a maximum around a QCP. The 1/T1 decreases rapidly below Tsc with no Hebel-Slichter peak, and ubiquitously follows a T5 variation below a characteristic temperature T*=0.6 Tsc, which indicates the existence of point nodes in the superconducting gap function commonly in the family. These results suggest that the A2Cr3As3 family is a possible solid-state analog of superfluid 3He.