Highly three dimensional turbulent boundary layers developed over herring-bone type riblet surface are investigated at moderate Reynolds number using particle image velocimetry (PIV) in all three orthogonal planes. Non-simultaneous measurements are performed to capture large fields of view (FOV) of more than 9δ in streamwise, 3δ in spanwise and 1.3δ in wall-normal direction in the respective planes. Observations of the instantaneous velocity fields reveal an extreme modification and rearrangement of the large-scale turbulence structures due to the unique surface topology. The utility of the multi-plane PIV diagnosis is that it uncovers structural modifications to the turbulent boundary layer that would have otherwise not been obvious from single point hot-wire anemometry. Distinct events observed in these multiple orientations are used to create a broader picture of this complicated flow. The new understanding of how turbulent boundary layers behave under the influence of threedimensional secondary flow will be utilised to (re)tailor a passive surface for flow control purposes.