The Amazon shelf of South America is known to be highly contrasted in its surface carbon dioxide concentrations, from very high concentrations near the estuary, and very low concentrations downstream in the saltier Amazon plume, which results in a great contrast in carbon dioxide exchange with the atmosphere. During three cruises in 2020-2023 (Eurec4A-OA, Tara-Microbiomes legs 5, 6 and 7, Amaryllis), dissolved inorganic carbon (DIC) concentration, its isotopic composition (δ13C-DIC), the water isotopic composition (d18O-H2O and d2H-H2O), as well as inorganic nutrients and surface CO2 partial pressure (pCO2) were measured on the Amazon shelf of South America during three cruises in different seasons. These data are used to better understand mixing in the continuum between river water and open-ocean waters, and the biogeochemical processes taking place on the shelf close to the Amazon and Para river estuaries. The water isotopes are furthermore used to identify different freshwater origins.The accuracy of the data is discussed as well as its representativeness. The data are then combined to first identify large variations of the river freshwater sources, compatible with 2021 being a year of very large discharge, and 2023 a year of exceptional low discharge. In addition, the data mostly from August and September 2021 identify a smaller influence of sources and sinks of dissolved inorganic carbon in the mixing shelf region than what had been earlier observed during the Amasseds cruise data in November-December 1991, a much lower river discharge period. This indicates that there might be a larger seasonal and/or interannual variability of these processes than what was earlier assessed. Measured pCO2 data on the Amazon shelf in 2021 are then discussed in this context.

The Southern Ocean mitigates global surface warming by taking up a large portion of the carbon released by human activities. While models suggest this carbon sink should weaken as climate change increases upwelling of carbon-rich deep water, such a decline has not been observed over the past decades. Here, using circumpolar hydrographic observations, we reveal that Southern Ocean freshening since the 1990s has enhanced density stratification, which prevents these CO2-enriched waters from reaching the surface. Meanwhile, the surface layer has become thinner, allowing the CO2-rich circumpolar deep water to get closer to the surface, replacing winter water between 100 m and 200 m. In this layer, the CO2 fugacity increased by similar to 10 mu atm because of changing ocean dynamics since the 1990s. Our findings imply that the observed surface freshening temporarily buffered the model-predicted weakening of the Southern Ocean carbon sink, but that such a signal could potentially emerge if stratification weakened.

The air–sea CO2 flux in the coastal ocean is a critical component of the global carbon budget, yet it remains poorly understood due to limited data, the many sources and sinks of carbon, and their complex interactions. In August–November 2021, the Tara schooner collected over 14 000 km of CO2 fugacity (fCO2) measurements along the coast of South America, including in the Amazon River–ocean continuum (https://doi.org/10.5281/zenodo.13790064, Olivier et al., 2024a). The Amazon River and its oceanic plume exhibit complex interactions under the combined influence of many processes such as tides and bathymetry. Observations revealed a wide range of fCO2 values, from up to 3000 µatm in the river to a minimum of 42 µatm downstream of the plume, where values were notably lower than atmospheric levels. South of the estuary, the fCO2 of the North Brazil Current waters (0–9° S) exceeds 400 µatm, while along the Brazil Current (10–30° S), fCO2 is around 400 µatm and decreases with temperature and distance from the Equator. Due to its high variability in the coastal environment, in the dataset salinity emerged as the primary driver of fCO2 variability across this dynamic region. Despite strong variability, comparison with discrete samples of other carbonate parameters showed a mean difference of 2 µatm, within the range of uncertainties of the chemical formulas used for comparison. This dataset provides critical insights into the under-sampled region of the Brazilian coast, improving our understanding of coastal fCO2 dynamics and their role in the global carbon budget.

Accurate assessment of anthropogenic carbon dioxide (CO2) emissions and their redistribution among the atmosphere, ocean, and terrestrial biosphere in a changing climate is critical to better understand the global carbon cycle, support the development of climate policies, and project future climate change. Here we describe and synthesize datasets and methodologies to quantify the five major components of the global carbon budget and their uncertainties. Fossil CO2 emissions (EFOS) are based on energy statistics and cement production data, while emissions from land-use change (ELUC) are based on land-use and land-use change data and bookkeeping models. Atmospheric CO2 concentration is measured directly, and its growth rate (GATM) is computed from the annual changes in concentration. The global net uptake of CO2 by the ocean (SOCEAN, called the ocean sink) is estimated with global ocean biogeochemistry models and observation-based fCO2 products (fCO2 is the fugacity of CO2). The global net uptake of CO2 by the land (SLAND, called the land sink) is estimated with dynamic global vegetation models. Additional lines of evidence on land and ocean sinks are provided by atmospheric inversions, atmospheric oxygen measurements, and Earth system models. The sum of all sources and sinks results in the carbon budget imbalance (BIM), a measure of imperfect data and incomplete understanding of the contemporary carbon cycle. All uncertainties are reported as ±1σ. For the year 2023, EFOS increased by 1.3 % relative to 2022, with fossil emissions at 10.1 ± 0.5 GtC yr−1 (10.3 ± 0.5 GtC yr−1 when the cement carbonation sink is not included), and ELUC was 1.0 ± 0.7 GtC yr−1, for a total anthropogenic CO2 emission (including the cement carbonation sink) of 11.1 ± 0.9 GtC yr−1 (40.6 ± 3.2 GtCO2 yr−1). Also, for 2023, GATM was 5.9 ± 0.2 GtC yr−1 (2.79 ± 0.1 ppm yr−1; ppm denotes parts per million), SOCEAN was 2.9 ± 0.4 GtC yr−1, and SLAND was 2.3 ± 1.0 GtC yr−1, with a near-zero BIM (−0.02 GtC yr−1). The global atmospheric CO2 concentration averaged over 2023 reached 419.31 ± 0.1 ppm. Preliminary data for 2024 suggest an increase in EFOS relative to 2023 of +0.8 % (−0.2 % to 1.7 %) globally and an atmospheric CO2 concentration increase by 2.87 ppm, reaching 422.45 ppm, 52 % above the pre-industrial level (around 278 ppm in 1750). Overall, the mean of and trend in the components of the global carbon budget are consistently estimated over the period 1959–2023, with a near-zero overall budget imbalance, although discrepancies of up to around 1 GtC yr−1 persist for the representation of annual to semi-decadal variability in CO2 fluxes. Comparison of estimates from multiple approaches and observations shows the following: (1) a persistent large uncertainty in the estimate of land-use change emissions, (2) low agreement between the different methods on the magnitude of the land CO2 flux in the northern extra-tropics, and (3) a discrepancy between the different methods on the mean ocean sink. This living-data update documents changes in methods and datasets applied to this most recent global carbon budget as well as evolving community understanding of the global carbon cycle. The data presented in this work are available at https://doi.org/10.18160/GCP-2024 (Friedlingstein et al., 2024).

The ocean critically mitigated global surface warming by taking up a large portion of the additional carbon released to the climate system by human activities. The strength of this carbon sink depends on ocean dynamics and its interaction with the natural carbon cycle, both of which are critically altered by the ongoing climatic changes, making detailed global monitoring essential. However, the vastness and variability of the ocean makes collecting enough long-term CO2 observations challenging.During The Ocean Race, Team Malizia collected underway temperature, salinity and CO2 fugacity data all around the globe, creating a unique dataset that enhances our understanding of oceanic carbon dynamics. This dataset shows the potential of racing sailboats as new platforms global-scale ocean CO2 monitoring. Using these vessels enables data collection across diverse and often hard-to-reach regions, offering a new approach to addressing knowledge and data gaps in the carbon cycle.Here, we present key findings from this dataset, including a case study from the North Atlantic where a storm event triggered significant CO2 release. This observation provides new insights on the mechanisms driving the CO2 flux between the ocean and atmosphere in this region. These findings underscore the value of racing sailboats in revealing new insights into the ocean’s carbon sink and highlight their role as promising tools for carbon cycle research in an era of climate change.

The Southern Ocean considerably influences the global climate by exchanging heat and carbon between the deep ocean and the surface. Historically, it mitigated surface warming by absorbing 70% of excess heat and over 10% of human-induced CO2 emissions. The future of this role is strongly linked to salinity changes, as salinity controls, through its influence on the density stratification, the vertical exchange of water masses, heat and carbon. A strong freshening of the Southern Ocean surface waters in the decades before 2016 has resulted in increased surface density stratification all around Antarctica. This enhanced stratification reduces the mixing between deep and surface waters, and in particular the vertical mixing of carbon-rich deep waters into the surface layer. By comparing post-2010 hydrographic sections in the GLODAP database to the climatology, we observe consistent and significant anomalies in the biogeochemical properties of the top 500 m of all the sectors of the Southern Ocean. While the surface layer is freshening, salinity, temperature, dissolved inorganic carbon (DIC) and total alkalinity (TA) increase in the subsurface layer. We find that this increase results from the shallowing of upper circumpolar deep water south of 50°S. We investigate the variability in properties of the surface and subsurface layers over the last decade, as well as the impact of such changes on the potential fugacity of CO2 to better understand how the change in stratification may impact the air-sea CO2 flux.

Abstract. The air-sea CO2 flux in the coastal ocean is a key component of the global carbon budget. However, due to the scarcity of data, the many sources and sinks of carbon and their complex interactions in these waters remain poorly understood. In 2021, the Tara schooner collected 14,000 km of CO2 fugacity (fCO2) measurements along the coast of South America, including in the Amazon River-Ocean continuum (https://doi.org/10.5281/zenodo.13790065, Olivier et al., 2024a). The interactions between the Amazon River and its oceanic plume are complex, and under a combined influence of many processes such as tides and bathymetry. Downstream of the Amazon River plume, the fCO2 is low compared with that of the atmosphere, reaching a minimum of 42 μatm. In the river, fCO2 reaches up to 3000 μatm. South of the estuary, the waters of the North Brazil Current have a fCO2 exceeding 400 μatm. Along the Brazil Current, fCO2 is around 400 μatm and decreases, as does temperature, as the schooner sails away from the equator. Nevertheless, in all the data collected in this coastal environment, salinity varies greatly, and therefore describes best the variability of fCO2. Despite the strong variability and uncertainties in the data, comparison with discrete samples of other carbonate parameters shows that the mean differences (2 µatm) are within the range of uncertainties related to the chemical formula used for the comparison. This data set helps to fill the gap in our knowledge of the behavior of fCO2 in the under-sampled region of the Brazilian coast.

Total alkalinity (AT) and dissolved inorganic carbon (CT) in the oceans are important properties with respect to understanding the ocean carbon cycle and its link to global change (ocean carbon sinks and sources, ocean acidification) and ultimately finding carbon-based solutions or mitigation procedures (marine carbon removal). We present a database of more than 44 400 AT and CT observations along with basic ancillary data (spatiotemporal location, depth, temperature and salinity) from various ocean regions obtained, mainly in the framework of French projects, since 1993. This includes both surface and water column data acquired in the open ocean, coastal zones and in the Mediterranean Sea and either from time series or dedicated one-off cruises. Most AT and CT data in this synthesis were measured from discrete samples using the same closed-cell potentiometric titration calibrated with Certified Reference Material, with an overall accuracy of ±4 µmol kg−1 for both AT and CT. The data are provided in two separate datasets – for the Global Ocean and the Mediterranean Sea (https://doi.org/10.17882/95414, Metzl et al., 2023), respectively – that offer a direct use for regional or global purposes, e.g., AT–salinity relationships, long-term CT estimates, and constraint and validation of diagnostic CT and AT reconstructed fields or ocean carbon and coupled climate–carbon models simulations as well as data derived from Biogeochemical-Argo (BGC-Argo) floats. When associated with other properties, these data can also be used to calculate pH, the fugacity of CO2 (fCO2) and other carbon system properties to derive ocean acidification rates or air–sea CO2 fluxes.

The North Brazil Current (NBC) flows offshore of the mouth of the Amazon River and seasonally sheds anticyclonic rings (NBC rings) that propagate northwestward and interact with the Amazon River plume (ARP). Mesoscale features have a high temporal variability that is hard to monitor from current weekly and monthly sea surface salinity (SSS) satellite fields. Novel SSS fields with a higher temporal resolution analyzed together with satellite geostrophic currents, chlorophyll-a, and wind speed and in-situ data from the "Microbiomes cruise" on the SV Tara in August-September 2021 revealed a late summer freshwater pathway, which was not well documented in earlier studies. By combining these datasets, we improved the characterization of summer ARP pathways. In 2021, the ARP was a succession of freshwater patches cut off from the main plume by the NBC rings. A patch of about 200.000 km(2) with salinity <33.5 pss was observed in September 2021, bringing 0.5 Sv of Amazon water northwestward in a period where the mean ocean currents lead to eastward transport. This patch was shallow, very stratified, and it created a surface steric-height anomaly that was identified as an anticyclonic feature in altimetric sea level products. Once separated from the NBC retroflection, it was mainly driven by Ekman currents. Other similar patches were observed during the 2021 summer, leading to a strong intermittency of the ARP transport. They strongly contributed to make 2021 the year with the largest northwestward freshwater transport in late summer within the 2010-2021 time-period investigated. This freshwater transport pathway is important for all plume-related phenomena, and show the ability of combined SMOS and SMAP data to accurately represent the day-to-day SSS variability.

In the western tropical Atlantic Ocean close to the Amazon plume, a large loss rate of Argo-float profiles took place, that is, instances of profiles that should have happened but were not transmitted. We find that APEX and SOLO floats were not ascending to the surface in the presence of low surface practical salinity, typically on the order of 32.5 or less, because of limitations on the surface buoyancy range for those floats. This results in an overall loss of profiles from these floats that is on the order of 6% averaged over the year, with a peak of 12% in July. We also find aborted descents/incorrect grounding detections for ARVOR/PROVOR floats when surface salinity is low and the descending float reaches a strong halocline (2.6% of all the profiles in the June-August season). Altogether, the whole Argo set includes a maximum loss rate of roughly 6% in July. We find a pattern of loss that fits the surface salinity seasonal cycle and the occurrence of low surface salinity investigated from a high-resolution daily satellite salinity product in 2010-21. The agreement is even better when considering surface density instead of surface salinity, with the temperature contribution to density inducing a shift in the maximum occurrence of these events by 1 month relative to the cycle of very low salinity events. Because of changes in the float technology, the loss rate that targets the lowest surface salinities was very large until 2010, with an overall decrease afterward.

The Amazon shelf of South America is known to be highly contrasted in its surface carbon dioxide concentrations, from very high concentrations near the estuary, and very low concentrations downstream in the saltier Amazon plume, which results in a great contrast in carbon dioxide exchange with the atmosphere. During three cruises in 2020-2023 (Eurec4A-OA, Tara-Microbiomes legs 5, 6 and 7, Amaryllis), dissolved inorganic carbon (DIC) concentration, its isotopic composition (δ13C-DIC), the water isotopic composition (d18O-H2O and d2H-H2O), as well as inorganic nutrients and surface CO2 partial pressure (pCO2) were measured on the Amazon shelf of South America during three cruises in different seasons. These data are used to better understand mixing in the continuum between river water and open-ocean waters, and the biogeochemical processes taking place on the shelf close to the Amazon and Para river estuaries. The water isotopes are furthermore used to identify different freshwater origins. The accuracy of the data is discussed as well as its representativeness. The data are then combined to first identify large variations of the river freshwater sources, compatible with 2021 being a year of very large discharge, and 2023 a year of exceptional low discharge. In addition, the data mostly from August and September 2021 identify a smaller influence of sources and sinks of dissolved inorganic carbon in the mixing shelf region than what had been earlier observed during the Amasseds cruise data in November-December 1991, a much lower river discharge period. This indicates that there might be a larger seasonal and/or interannual variability of these processes than what was earlier assessed. Measured pCO2 data on the Amazon shelf in 2021 are then discussed in this context.

EUREC4A-OA is a large international project, connecting experts of ocean and atmosphere observations and modelling to enhance the understanding of key ocean and air-sea processes at the and to improve the skill of forecasts and future projections.The core of EUREC4A-OA has been a one-month (Jan/Feb 2020) field study in the western tropical North Atlantic Ocean where high-resolution, synchronized observational data have been collected using cutting-edge technology on ships, airplanes and autonomous vehicles. EUREC4A-OA investigates heat, momentum, water and CO2 transport within the ocean and exchanges across the air/sea interface using innovative high-resolution ocean observations and a hierarchy of numerical simulations. EUREC4A-OA focuses on ocean dynamics at the small-scale (0.1–100 km) and related atmospheric boundary layer processes. EUREC4A-OA is centered on the tropics where the primary external time scale affecting air-sea exchange is the diurnal cycle. However, the internal ocean and atmosphere dynamics convolute the diurnal, synoptic, seasonal and longer time scales to climate variability.The talk will present some of the results we obtained so far from the observations collected during the field experiment and from numerical simulations. The analyses carried out revealed with unprecedented detail the particular characteristics of the ocean small-scale dynamics, enlightening that such scales are also very active in the tropical regions and not only over the mid and higher latitudes ocean. Observations and models also unveil that the ocean small scales is important in contributing to the exchanges of heat, freshwater and CO2 between the ocean and the atmosphere. Moreover, the evaluation of the intensity of the coupling between the ocean and the atmosphere assessed from data and high-resolution simulations show that they are very important and intimately linked with the 3D structure of the small-scale ocean dynamics. The project has also provided preliminary results in terms of parametrization of different processes influencing the ocean and atmosphere exchanges that have been uncovered by the EUREC4A-OA field experiment. Notably a better representation of the small-scale freshwater patches due to precipitation has been introduced in the French Earth-System model that improves the overall simulations of air-sea interactions and clouds. A similar parametrization is now been introduced to take into account these physical processes in air-sea fluxes of CO2.

Abstract. Total alkalinity (AT) and total dissolved inorganic carbon (CT) in the oceans are important properties to understand the ocean carbon cycle and its link with climate change (ocean carbon sinks and sources) or global change (ocean acidification). We present a data-base of more than 44 400 AT and CT observations in various ocean regions obtained since 1993 mainly in the frame of French projects. This includes both surface and water columns data acquired in open oceans, coastal zones and in the Mediterranean Sea and either from time-series or punctual cruises. Most AT and CT data in this synthesis were measured from discrete samples using the same closed-cell potentiometric titration calibrated with Certified Reference Material, with an overall accuracy of ± 4 µmol kg-1 for both AT and CT. Given the lack of observations in the Indian and Southern Oceans, we added sea surface underway AT and CT data obtained in 1998–2018 in the frame of OISO cruises and in 2019 during the CLIM-EPARSES cruise measured onboard using the same technique. Separate datasets for the global ocean, and for the Mediterranean Sea are provided in a single format (https://doi.org/10.17882/95414, Metzl et al., 2023) that offers a direct use for regional or global purposes, e.g. AT/Salinity relationships, long-term CT estimates, constraint and validation of diagnostics CT-AT reconstructed fields or ocean carbon and coupled climate/carbon models simulations, as well as data derived from BG-ARGO floats. When associated with other properties, these data can also be used to calculate pH, fugacity of CO2 (fCO2) and other carbon systems properties to derive ocean acidification rates or air-sea CO2 fluxes.

The need of a mission ensuring the continuation of L-band measurements from space with increased spatial resolution with respect to the current generation of sensors is discussed. The status of the SMOS-High Resolution (HR) mission project, currently under a Phase A study at CNES, is presented.

The key processes driving the air–sea CO2 fluxes in the western tropical Atlantic (WTA) in winter are poorly known. WTA is a highly dynamic oceanic region, expected to have a dominant role in the variability in CO2 air–sea fluxes. In early 2020 (February), this region was the site of a large in situ survey and studied in wider context through satellite measurements. The North Brazil Current (NBC) flows northward along the coast of South America, retroflects close to 8∘ N and pinches off the world's largest eddies, the NBC rings. The rings are formed to the north of the Amazon River mouth when freshwater discharge is still significant in winter (a time period of relatively low run-off). We show that in February 2020, the region (5–16∘ N, 50–59∘ W) is a CO2 sink from the atmosphere to the ocean (−1.7 Tg C per month), a factor of 10 greater than previously estimated. The spatial distribution of CO2 fugacity is strongly influenced by eddies south of 12∘ N. During the campaign, a nutrient-rich freshwater plume from the Amazon River is entrained by a ring from the shelf up to 12∘ N leading to high phytoplankton concentration and significant carbon drawdown (∼20 % of the total sink). In trapping equatorial waters, NBC rings are a small source of CO2. The less variable North Atlantic subtropical water extends from 12∘ N northward and represents ∼60 % of the total sink due to the lower temperature associated with winter cooling and strong winds. Our results, in identifying the key processes influencing the air–sea CO2 flux in the WTA, highlight the role of eddy interactions with the Amazon River plume. It sheds light on how a lack of data impeded a correct assessment of the flux in the past, as well as on the necessity of taking into account features at meso- and small scales.

In February 2020, a 120-km-wide freshwater plume was documented by satellite and in situ observations near the Demerara Rise (7 degrees N/54 degrees W-56 degrees W). It was initially stratified in the upper 10 m with a freshwater content of 2-3 m of Amazon water distributed down to 40 m. On February 2nd, ship transects indicate an inhomogeneous shelf structure with a propagating front in its midst, whereas minimum salinity close to 30 pss was observed close to the shelf break on February 5th. The salinity minimum eroded in time but was still observed 13-16 days later with 33.3 pss minimum value up to 400 km from the shelf break. At this time, the mixed layer depth was close to 20 m. The off-shelf flow lasted 10 days, contributing to a plume area extending over 100,000 km(2) and associated with a 0.15 Sv (10(6) m(3) s(-1)) freshwater transport. The off-shelf plume was steered northward by a North Brazil Current ring up to 12 degrees N and then extended westward toward the Caribbean Sea. Its occurrence followed 3 days of favorable wind direction closer to the Amazon estuary, which contributed to north-westward freshwater transport on the shelf. Other such events of freshwater transport in January-March are documented since 2010 in salinity satellite products in 7 out of 10 years, and in 6 of those years, they were preceded by a change in wind direction between the Amazon estuary and the Guianas favoring the north-westward freshwater transport toward the shelf break.