Binaries are known to play a key role in the mass loss and dynamical environments of evolved stars. Stellar and substellar companion interactions produce complex wind morphologies including rotating/expanding disks, bipolar outflows, and spiral wind patterns; however, the connection between these many structures and the gas-phase chemistry they harbor is not well constrained. To expand the sample of chemical inventories in interacting systems, we present a detailed spectroscopic case study of the binary C-rich asymptotic giant branch (AGB) star V Hya. Using spatially resolved Atacama Large Millimeter/submillimeter Array observations at Bands 3, 6, and 7, we characterize the rotational emission lines and distributions of molecules in its surrounding disk undergoing dynamical expansion (DUDE). We detect emission from over 15 molecules and isotopologues toward this source, and present resolved maps for the brightest tracers of carbonaceous chemistry (e.g., CCH, C4H, HC5N, HNC, and CH3CN ). Employing LTE and non-LTE models of emission from the DUDE, we estimate the abundance distributions for optically thin species, and compare them with prototypical carbon-rich AGB envelopes. We find that the average abundances of detected species are within a factor of similar to 5 from sources with similar mass-loss rates; however, the distribution of daughter species in V Hya is much more compact, with carbon chain species (CCH, C4H, and HC3N) appearing with abundances >10-7 even in the innermost sampled regions (200 au) of the disk.

Polycyclic aromatic hydrocarbons (PAHs) are organic molecules containing adjacent aromatic rings. Infrared emission bands show that PAHs are abundant in space, but only a few specific PAHs have been detected in the interstellar medium. We detected 1-cyanopyrene, a cyano-substituted derivative of the related four-ring PAH pyrene, in radio observations of the dense cloud TMC-1, using the Green Bank Telescope. The measured column density of 1-cyanopyrene is similar to 1.52x1012 cm-2, from which we estimate that pyrene contains up to 0.1% of the carbon in TMC-1. This abundance indicates that interstellar PAH chemistry favors the production of pyrene. We suggest that some of the carbon supplied to young planetary systems is carried by PAHs that originate in cold molecular clouds.

Polycyclic aromatic hydrocarbons (PAHs) are thought to be the most abundant class of molecules in space, yet their interstellar lifecycle is poorly understood due to difficulties detecting individual PAHs. Here, we present the discovery of 1-cyanopyrene, a 4-ring PAH, in the dense cloud TMC-1 using the 100-m Green Bank Telescope. We derive an abundance of 1.52 x 10^12 cm^-2, estimating that pyrene accounts for up to 0.03-0.3 TMC-1 and up to 1 from asteroid Ryugu, which suggests a cold, interstellar origin. The abundance indicates pyrene is an "island of stability" in interstellar PAH chemistry, and suggests that the carbon supplied to planetary systems, carried by PAHs, originates in cold clouds.

V510 Pup (IRAS 08005-2356) is a binary post-AGB system with a fast molecular outflow that has been noted for its puzzling mixture of carbon- and oxygen-rich features in the optical and infrared. To explore this chemical dichotomy and relate it to the kinematics of the source, we present an ACA spectral line survey detailing fourteen newly detected molecules in this pre-planetary nebula. The simultaneous presence of CN/C2H/HC3N and SO/SO2 support the previous conclusion of mixed chemistry, and their line profiles indicate that the C- and O-rich material trace distinct velocity structures in the outflow. This evidence suggests that V510 Pup could harbor a dense O-rich central waist from an earlier stage of evolution, which persisted after a fast C-rich molecular outflow formed. By studying the gas phase composition of this unique source, we aim to reveal new insights into the interplay between dynamics and chemistry in rapidly evolving post-AGB systems.

We report observations of the Didymos–Dimorphos binary asteroid system using the Atacama Large Millimeter/submillimeter Array (ALMA) and the Atacama Compact Array (ACA) in support of the Double Asteroid Redirection Test mission. Our observations on UT 2022 September 15 provided a preimpact baseline and the first measure of Didymos–Dimorphos’s spectral emissivity at λ = 0.87 mm, which was consistent with the handful of siliceous and carbonaceous asteroids measured at millimeter wavelengths. Our postimpact observations were conducted using four consecutive executions each of ALMA and the ACA spanning from T+3.52 to T+8.60 hr, sampling thermal emission from the asteroids and the impact ejecta. We scaled our preimpact baseline measurement and subtracted it from the postimpact observations to isolate the flux density of millimeter-sized grains in the ejecta. Ejecta dust masses were calculated for a range of materials that may be representative of Dimorphos’s S-type asteroid material. The average ejecta mass over our observations is consistent with 1.3–6.4 × 10 7 kg, with the lower and higher values calculated for amorphous and crystalline silicates, respectively. Owing to the likely crystalline nature of S-type asteroid material, the higher value is favored. These ejecta masses represent 0.3%–1.5% of Dimorphos’s total mass and are in agreement with lower limits on the ejecta mass based on measurements at optical wavelengths. Our results provide the most sensitive measure of millimeter-sized material in the ejecta and demonstrate the power of ALMA for providing supporting observations to spaceflight missions.

Using data from the GOTHAM (GBT Observations of TMC-1: Hunting for Aromatic Molecules) survey, we report the first astronomical detection of the C10H- anion. The astronomical observations also provided the necessary data to refine the spectroscopic parameters of C10H-. From the velocity stacked data and the matched filter response, C10H- is detected at >9σ confidence level at a column density of 4.04e11 cm-2. A dedicated search for the C10H radical was also conducted towards TMC-1. In this case, the stacked molecular emission of C10H was detected at a 3.2σ confidence interval at a column density of 2.02e11 cm-2. However, since the determined confidence level is currently <5σ, we consider the identification of C10H as tentative. The full GOTHAM dataset was also used to better characterize the physical parameters including column density, excitation temperature, linewidth, and source size for the C4H, C6H and C8H radicals and their respective anions, and the measured column densities were compared to the predictions from a gas/grain chemical formation model and from a machine learning analysis. Given the measured values, the C10H-/C10H column density ratio is 2.0 - the highest value measured between an anion and neutral species to date. Such a high ratio is at odds with current theories for interstellar anion chemistry. For the radical species, both models can reproduce the measured abundances found from the survey; however, the machine learning analysis matches the detected anion abundances much better than the gas/grain chemical model, suggesting that the current understanding of the formation chemistry of molecular anions is still highly uncertain.

We report a systematic study of all known methyl carbon chains toward TMC-1 using the second data release of the GOTHAM survey, as well as a search for larger species. Using Markov Chain Monte Carlo simulations and spectral line stacking of over 30 rotational transitions, we report statistically significant emission from methylcyanotriacetylene (CH3C7N) at a confidence level of 4.6σ, and use it to derive a column density of ∼1011 cm−2. We also searched for the related species, methyltetraacetylene (CH3C8H), and place upper limits on the column density of this molecule. By carrying out the above statistical analyses for all other previously detected methyl-terminated carbon chains that have emission lines in our survey, we assess the abundances, excitation conditions, and formation chemistry of methylpolyynes (CH3C2n H) and methylcyanopolyynes (CH3C2n-1N) in TMC-1, and compare those with predictions from a chemical model. Based on our observed trends in column density and relative populations of the A and E nuclear spin isomers, we find that the methylpolyyne and methylcyanopolyyne families exhibit stark differences from one another, pointing to separate interstellar formation pathways, which is confirmed through gas–grain chemical modeling with nautilus.

We present laboratory rotational spectroscopy of five isomers of cyanoindene (2-, 4-, 5-, 6-, and 7-cyanoindene) using a cavity Fourier-transform microwave spectrometer operating between 6-40 GHz. Based on these measurements, we report the detection of 2-cyanoindene (1H-indene-2-carbonitrile; 2-C_9H_7CN) in GOTHAM line survey observations of the dark molecular cloud TMC-1 using the Green Bank Telescope at centimeter wavelengths. Using a combination of Markov Chain Monte Carlo (MCMC), spectral stacking, and matched filtering techniques, we find evidence for the presence of this molecule at the 6.3σ level. This provides the first direct observation of the ratio of a cyano-substituted polycyclic aromatic hydrocarbon (PAH) to its pure hydrocarbon counterpart, in this case indene, in the same source. We discuss the possible formation chemistry of this species, including why we have only detected one of the isomers in TMC-1. We then examine the overall hydrocarbon:CN-substituted ratio across this and other simpler species, as well as compare to those ratios predicted by astrochemical models. We conclude that while astrochemical models are not yet sufficiently accurate to reproduce absolute abundances of these species, they do a good job at predicting the ratios of hydrocarbon:CN-substituted species, further solidifying -CN tagged species as excellent proxies for their fully-symmetric counterparts.

In recent years, many questions have arisen regarding the chemistry of photochemical products in the carbon-rich winds of evolved stars. To address them, it is imperative to constrain the distributions of such species through high angular resolution interferometric observations covering multiple rotational transitions. We used archival ALMA observations to map rotational lines involving high energy levels of cyanoacetylene (HC$_3$N) toward the inner envelope (radius <8"/1000 AU) of the carbon star IRC+10216. The observed lines include the J=28-27, J=30-29, and J=38-37, transitions of HC$_3$N in its ground vibrational state. In contrast to previous observations of linear carbon chains toward this AGB star which show extended, hollow emission at 15"-20" radii (e.g. C$_4$H, C$_6$H, HC$_5$N), the maps of the HC$_3$N lines here show compact morphologies comprising various arcs and density enhancements, with significant emission from gas clumps at an angular distance of ~3" (350 AU) from the central AGB star. We compared visibility sampled non-LTE radiative transfer models with the observed brightness distributions, and derive a fractional abundance with respect to H$_2$ of $10^{-8}$ for HC$_3$N at the radii probed by these lines. These results are consistent with enhanced photochemistry occurring in warm (~200 K) regions of the circumstellar envelope. After application of a specialized chemical model for IRC+10216, we find evidence that the enhanced HC$_3$N abundances in the inner wind are most likely due to a solar-type binary companion initiating photochemistry in this region.

We have conducted an extensive search for nitrogen-, oxygen-, and sulfur-bearing heterocycles toward Taurus Molecular Cloud 1 (TMC-1) using the deep, broadband centimeter-wavelength spectral line survey of the region from the GOTHAM large project on the Green Bank Telescope. Despite their ubiquity in terrestrial chemistry, and the confirmed presence of a number of cyclic and polycyclic hydrocarbon species in the source, we find no evidence for the presence of any heterocyclic species. Here, we report the derived upper limits on the column densities of these molecules obtained by Markov Chain Monte Carlo (MCMC) analysis and compare this approach to traditional single-line upper limit measurements. We further hypothesize why these molecules are absent in our data, how they might form in interstellar space, and the nature of observations that would be needed to secure their detection.

We report the discovery of two unsaturated organic species, trans -(E)-cyanovinylacetylene and vinylcyanoacetylene, using the second data release of the GOTHAM deep survey toward TMC-1 with the 100 m Green Bank Telescope. For both detections, we performed velocity stacking and matched filter analyses using Markov Chain Monte Carlo simulations, and for trans -(E)-cyanovinylacetylene, three rotational lines were observed at low signal-to-noise (∼3 σ ). From this analysis, we derive column densities of 2 × 10 11 and 3 × 10 11 cm −2 for vinylcyanoacetylene and trans -(E)-cyanovinylacetylene, respectively, and an upper limit of <2 × 10 11 cm −2 for trans -(Z)-cyanovinylacetylene. Comparisons with G3//B3LYP semiempirical thermochemical calculations indicate abundances of the [H 3 C 5 N] isomers are not consistent with their thermodynamic stability, and instead their abundances are mainly driven by dynamics. We provide a discussion on how these species may be formed in TMC-1, with reference to related molecules like vinyl cyanide (CH 2 = CHC ≡ N). As part of this discussion, we performed the same analysis for ethyl cyanide (CH 3 CH 2 C ≡ N), the hydrogenation product of CH 2 = CHC ≡ N. This analysis provides evidence—at 4. 2σ significance—of an upper limit to the column density of <4 × 10 11 cm −2 ; an order of magnitude lower than previous upper limits toward this source.

Unidentified infrared emission bands are ubiquitous in many astronomical sources. These bands are widely, if not unanimously, attributed to collective emissions from polycyclic aromatic hydrocarbon (PAH) molecules, yet no single species of this class has been identified in space. Using spectral matched filtering of radio data from the Green Bank Telescope, we detected two nitrile-group-functionalized PAHs, 1- and 2-cyanonaphthalene, in the interstellar medium. Both bicyclic ring molecules were observed in the TMC-1 molecular cloud. In this paper, we discuss potential in situ gas-phase PAH formation pathways from smaller organic precursor molecules.

Cold carbon chemistry in the interstellar medium is well-known for its efficient production of linear carbon chain

We report a search for the diatomic hydrides SiH, PH, and FeH along the line of sight toward the chemically rich circumstellar envelopes of IRC+10216 and VY Canis Majoris. These molecules are thought to form in high-temperature regions near the photospheres of those stars, and may then further react via gas-phase and dust-grain interactions leading to more complex species, but have yet to be constrained by observation. We used the German Receiver for Astronomy at Terahertz Frequencies spectrometer on the Stratospheric Observatory for Infrared Astronomy to search for rotational emission lines of these molecules in four spectral windows ranging from 600 to 1500 GHz. Although none of the targeted species was detected in our search, we report their upper limit abundances in each source and discuss how they influence the current understanding of hydride chemistry in dense circumstellar media. We attribute the nondetections of these hydrides to their compact source sizes, high barriers of formation, and proclivity to react with other molecules in the winds.