The emergence of hydrogel ionotronics has significantly extended the applications of soft electronics by allowing intimate interfaces between electronic units and biological/engineered surfaces for better sensing and communication with surrounding stimuli. However, hydrogel ionotronic devices that combine high stretchability, self healing, good water retention, and biocompatibility are still desired. Here, we report a biocompatible ionic hydrogel made of polyvinyl alcohol, silk fibroin, and borax. In this ionic hydrogel, polyvinyl alcohol and borax offer the high stretchability and conductivity, respectively, while silk fibroin improves the stability of the hydrogel and increases water uptake by the gels. The hydrogel features strain larger than 5000%, good water retention, self-healing, and tunable conductivity and adhesive capabilities. We also demonstrate the use of the hydrogel as a sensing platform to monitor human body motion for applications in health management, soft robotics, and human machine interfaces.

Living organisms produced nanopolymers (nanobiopolymers for short), such as nanocellulose, nanochitin, nanosilk, nanostarch, and microbial nanobiopolymers, having received widely scientific and engineering interests in recent years. Compare with petroleum-based polymers, biopolymers are sustainable and biodegradable. The unique structural features that stem from nanosized effects, such as ultrahigh aspect ratio and length-diameter ratio, further endow nanobiopolymers with high transparence and versatile processability. To fabricate these nanobiopolymers, a variety of mechanical, chemical, and synthetic biology techniques have been developed. The applications of the isolated nanobiopolymers have been extended from polymer fillers into wide emerging high-tech fields, such as biomedical devices, bioplastics, display panels, ultrafiltration membranes, energy storage devices, and catalytic supports. Accordingly, in the review, the authors first introduce isolation techniques to fabricate nanocellulose, nanochitin, nanosilk, and nanostarch. Then, the authors summarized the nanobiopolymers produced from biosynthetic pathway, including microbial polyamides, polysaccharides, and polyesters. On the other hand, most of these techniques require high energy consumption and usage of chemical reagents. In this regard, life cycle assessment offered a quantitative route to precisely evaluate and compare environmental benefits of different artificial isolation approaches, which are also summarized in the second section of the review.

Wind energy, considered as one of the most promising clean and sustainable energy sources, has drawn more and more attraction. Here we first designed and fabricated a self-powered printer system consisting of a transparent wind-driven triboelectric nanogenerator (TENG) serving as a power supply unit and a handheld printer as an output unit. The wind-driven TENG can generate an output voltage, a short-circuit current and a power up to 130V, 15 μA and 2mW, respectively. An electric field is obtained by applying a rectified voltage signal which is generated from the TENG between the substrate electrode and the syringe, compelling the charged ink droplet falling down onto the printing substrate. Additionally, the handheld printer system can realize color printing as well as printing conductive circuit by scavenging mouth-blown wind energy. The self-powered printer not only realizes the transition from TENG in lab into practical applications, but also provides an innovative idea of mobile devices without an electric power supply.

Multifunctional bionanocomposite foams with 3D interconnected networks showing advantageous mechanical properties, thermal insulation, underwater oleophobicity, and biocompatibility, were made from a chitosan matrix reinforced with nanofibrillated cellulose (NFC). The density of the NFC-chitosan nanocomposite foams can be controlled by varying the NFC/chitosan weight ratio and solid content of the suspension in the fabrication process. The mechanical properties and thermal stability of the nanocomposite foams were significantly improved by increasing the ratio of NFC, and effective thermal insulating performance was exhibited for temperature extremes at 0 degrees C and 70 degrees C. Moreover, the NFC-chitosan nanocomposite foams showed a highly efficient oil/water separation capacity even at a severe temperature of 90 degrees C. In addition, the nanocomposite foams possessed good biocompatibility toward L929 mouse fibroblasts. Therefore, the bionanocomposite foams are available for a number of applications, including as disposable and high-performance filtration media for water purification, packaging, and biological scaffolds.