The Kramers-Wannier duality is the prototypical example of a non-invertible symmetry, yet little is known about its fate away from criticality and out of equilibrium. We introduce the Kramers-Wannier entanglement asymmetry, a quantum-information measure that quantifies the breaking of this non-invertible symmetry in the transverse-field Ising chain. We first investigate its equilibrium properties, showing that it exhibits a striking crossover between the ordered and disordered phases together with a pronounced dip at the critical point that becomes increasingly sharp with subsystem size. We then study quantum quenches from both gapped phases to criticality and show that the Kramers-Wannier entanglement asymmetry decays to zero, signaling the dynamical restoration of the non-invertible symmetry. Remarkably, we uncover the emergence of a quantum Mpemba effect: under suitable conditions, states initially farther from equilibrium restore the Kramers-Wannier symmetry faster than states prepared closer to it. We provide both analytical and numerical evidence for this phenomenon and identify the mechanism responsible for its occurrence. Our work establishes entanglement asymmetry as a powerful probe of non-invertible symmetries beyond equilibrium and opens new perspectives on the dynamics of dualities in quantum many-body systems.
Integrable quantum systems evolving from non-equilibrium initial states do not thermalize to conventional Gibbs ensembles (GE). Instead, at long times they relax to generalized Gibbs ensembles (GGEs), which incorporate the full set of local and quasi-local conserved quantities. While GGEs have been extensively studied in the literature, a quantitative characterization of how different they are from ordinary GEs is still lacking. In this work, we address this question by employing the concept of athermality, which we define within quantum resource theory as the relative entropy between a given state and the closest thermal state. We compute the athermality for several quantum quenches in paradigmatic integrable models, including the free XY spin chain, the interacting Lieb-Liniger model, the XXZ spin chain, and the harmonic chain. We find that often the athermality becomes anomalously small when the post-quench Hamiltonian is critical in its ground state, despite probing physics at a finite energy density. We also prove that it systematically develops a singularity at criticality, which is inherited from the entropy of the GGE.
We study the fermionic non-Gaussianity in typical quantum states, focusing on Haar random states of qubits with or without a global U(1) symmetry. Using the Weingarten calculus, we derive analytical predictions for the non-Gaussianity, defined as the relative entropy between the reduced density matrix and its Gaussianized counterpart. We identify two regimes controlled by the ratio between the subsystem and the system size, ℓ/L. For ℓ/L < 1/2, the non-Gaussianity vanishes in the absence of symmetries, because typical reduced density matrices are exponentially close to the maximally mixed state. In the presence of a global U(1) symmetry, instead, it remains small but finite. By contrast, in the regime ℓ/L > 1/2, the non-Gaussianity becomes extensive. These results establish the typical scaling of fermionic non-Gaussianity in random states and analyze how this is modified by the presence of global symmetries.
We study the critical properties of random quantum circuits with a U(1) symmetry subject to local projective measurements that explicitly break this symmetry. We find that, at the measurement-induced phase transition, symmetry-breaking measurements act as a relevant perturbation at large scales, leading to the same universal critical properties as the corresponding monitored random circuit with non-symmetric unitary dynamics. In particular, we consider monitored U(1)-symmetric Haar-random circuits in the limit of large local Hilbert-space dimension, where the trajectory-averaged entanglement entropy can be exactly obtained in terms of a classical statistical mechanics model. In this model, the charge associated with the conservation law follows a symmetric simple exclusion process, in which symmetry-breaking measurements correspond to disordered defects that create and destroy charges. We prove that the charge correlation length remains finite for any measurement rate, ruling out a charge-sharpening transition, in contrast to the case of symmetry-preserving measurements. We further support our predictions at finite local Hilbert-space dimension through numerical finite-size scaling analyses of the entanglement transition in monitored U(1)-symmetric Haar and stabilizer random circuits.
Characterising the universal aspects of non-equilibrium quantum many-body dynamics is one of the key goals of this century's physics research. Progress, however, is hindered by the lack of general theoretical frameworks for studying interacting quantum matter far from equilibrium. A recent breakthrough has been the realization that several key non-equilibrium quantities, such as the rate of growth of entanglement or the fluctuations of conserved charges within finite subsystems, can be related to equilibrium properties through a space-time duality that effectively exchanges the roles of space and time. This observation effectively enables the study of non-equilibrium phenomena using tools and concepts borrowed from equilibrium statistical mechanics and thermodynamics. A first proof of principle of this framework, dubbed space-time duality approach (SDA), was provided by interacting integrable systems, where thermodynamic properties can often be characterized exactly, while dynamical quantities typically remain beyond analytical reach. Subsequent developments, however, revealed that the SDA suffered from an intrinsic ambiguity, restricting its applicability to homogeneous quenches and to charge fluctuations arising from symmetric initial states. Here we resolve this ambiguity from first principles and derive closed-form predictions for entanglement growth and charge fluctuations after general quantum quenches. We benchmark our results against the exact analytical solution of the Rule 54 quantum cellular automaton and extensive TEBD simulations of the XXZ chain. Moreover we show that, when specialised to the entanglement entropy, our framework naturally reproduces the predictions of the quasiparticle picture.
Quantum many-body systems display an extraordinary degree of complexity, yet many of their features are universal: they depend not on microscopic details, but on a few fundamental physical aspects such as symmetries. A central challenge is to distill these universal characteristics from model-specific ones. Random quantum states sampled from a uniform distribution, the Haar measure, provide a powerful framework for capturing this typicality. Here, we experimentally study the entanglement and symmetries of random many-body quantum states generated by evolving simple product states under ergodic Floquet models. We find excellent agreement with the predictions from the Haar-random state ensemble. First, we measure the Rényi-2 entanglement entropy as a function of the subsystem size, observing the Page curve. Second, we probe the subsystem symmetries using entanglement asymmetry. Finally, we measure the moments of partially transposed reduced density matrices obtained by tracing out part of the system in the generated ensembles, thereby revealing distinct entanglement phases. Our results offer an experimental perspective on the typical entanglement and symmetries of many-body quantum systems.
We study thermalisation and the possible occurrence of the Mpemba effect in a closed quantum setting that mimics the interaction of a system with thermal reservoirs coupled only at its boundaries. Specifically, we consider a tripartite geometry in which a finite chain, initially prepared at a finite temperature, is suddenly connected on both sides to two semi-infinite chains of the same nature held at a different temperature. These outer chains act as thermal baths, while the full system evolves unitarily under a homogeneous Hamiltonian. This setup provides a simple quantum realisation of a temperature quench and closely resembles the original scenario in which the classical Mpemba effect was first observed. We focus on two paradigmatic free-fermion models, the XX chain and the transverse-field Ising chain, which respectively preserve and break the global U(1) particle-number symmetry. As a probe of relaxation, we consider the Frobenius distance between the time-evolved reduced density matrix of the central subsystem and its stationary state, which is the thermal state at the bath temperature. Exploiting the free-fermionic structure of both models, the dynamics remains Gaussian and the Frobenius distance can be expressed exactly in terms of two-point correlation functions. Combining this representation with generalised hydrodynamics, we derive analytical predictions for the Frobenius distance in the hydrodynamic limit, providing a complete characterisation of the thermalisation process. Using these results, we investigate the possible occurrence of the Mpemba effect. We find that, despite the genuine non-equilibrium dynamics displayed by the system, no Mpemba effect arises in this setting. Our analysis identifies a broad class of boundary-driven thermalisation protocols in which relaxation is fully characterised analytically and exhibits no anomalous acceleration of equilibration.
The Mpemba effect refers to a counterintuitive phenomenon whereby a system initially prepared further from equilibrium may relax faster than one prepared closer to equilibrium. While extensively studied in classical nonequilibrium physics, its extension to isolated quantum systems only started in the last few years. In this contribution we review recent progress on the quantum Mpemba effect in closed many-body systems, emphasizing the role of reduced density matrix, entanglement and symmetry restoration. We discuss why and how the entanglement asymmetry provides a natural and experimentally accessible framework to characterize Mpemba-like behavior in unitary quantum evolution.
We investigate the dynamics of Entanglement Hamiltonians (EHs) in dissipative free-fermionic systems using a recent operator-based formulation of the quasiparticle picture. Focusing on gain and loss dissipation, we study the post-quench evolution and derive explicit expressions for the EH at the ballistic scale. In the long-time and weak-dissipation regime, the EH is shown to take the form of a time-dependent Generalized Gibbs Ensemble (t-GGE), with a structure that is universal across different initial states of the quench protocol. Within this framework, the emergence of the t-GGE is fully accounted for by the quasiparticle picture, and we argue that this description remains valid whenever the Lindbladian admits an appropriate coarse-grained representation.
We investigate the n-time cumulant generating function (or n-Full Counting Statistics, n-FCS) of extensive U(1) charges following a quantum quench. Exploiting space-time duality we characterise this function when evolving from initial states that are symmetric under the action of the charge. In particular, we show that if the correlations in time are sufficiently weak, e.g. the transport is ballistic, the n-FCS factorises into a sum of single-time FCS arranged in a time-shell structure. A direct implication of this structure is a drastic simplification of dynamical correlation functions: in the presence of time ordering they only depend on the smallest time entering the correlator. We support these findings with several analytical and numerical tests performed in free and interacting models.
We investigate the dynamics of the nu=1 quantum symmetric simple exclusion process starting from spatially inhomogeneous initial states. This one-dimensional system of free fermions has time-dependent stochastic hopping amplitudes that are uniform in space. We focus on two paradigmatic setups: domain-wall melting and the expansion of a trapped gas. Both are investigated by extending the framework of quantum generalized hydrodynamics (QGHD) to account for the underlying stochastic dynamics. We derive the evolution of the local quasiparticle occupation function, which characterizes the system at large space-time scales, and analyze the resulting entanglement spreading. By incorporating quantum fluctuations of the occupation function and employing conformal field theory techniques, we obtain the exact contribution to the entanglement entropy for each individual noise realization. Averaging over these realizations then yields the full entanglement statistics in the hydrodynamic regime. Our theoretical predictions are confirmed by exact numerical calculations. The results presented here constitute the first application of QGHD to stochastic quantum systems, demonstrating that this framework can be successfully extended beyond purely unitary dynamics to include stochastic effects.
We investigate a class of local quantum quenches in which the conformal boundary condition of a (1+1)-dimensional conformal field theory is abruptly changed. We derive a remarkably simple and universal expression for the time evolution of one-point functions on the half-line. This result provides a direct description of the propagation of the disturbance generated by the quench and, in turn, allows us to determine the dynamics of bipartite entanglement for subsystems adjacent to the boundary. We show that, once the subsystem becomes fully causally connected to the quench event, the entanglement entropy undergoes a sharp finite jump whose magnitude is universally given by the logarithm of the ratio of the boundary g-factors associated with the initial and final boundary conditions. We benchmark these analytical predictions against Matrix Product State simulations of the critical Ising spin chain, finding excellent agreement. The numerical analysis further allows us to investigate the time evolution of the spin-flip entanglement asymmetry, revealing how the symmetry-breaking perturbation emitted from the boundary propagates through the system. Our results uncover universal dynamical signatures of boundary quenches and establish a direct connection between nonequilibrium entanglement dynamics and boundary critical phenomena.
Fermionic Gaussian states are a fundamental tool in many-body physics, faithfully representing non-interacting quantum systems and allowing for efficient numerical simulations. Given a many-body wave function, it is therefore interesting to ask how much it differs from that of a Gaussian state, as quantified by the notion of non-Gaussianity. In this work, we relate measures of non-Gaussianity with the Shannon entropy of the particle-number distribution, coinciding with the particle-number asymmetry for pure states. We derive a lower bound on the relative entropy of non-Gaussianity in terms of the exponential of the Shannon entropy, and study numerically its tightness for large system sizes. Our bound is non-trivial for large values of the asymmetry and relies on the concentration of the particle-number distribution of (mixed) fermionic Gaussian states. Since the Shannon entropy of the particle-number distribution is often efficient to compute or experimentally measure, our results can be viewed as a practical way to lower bound non-Gaussianity, highlighting a non-trivial interplay with particle-number asymmetry.
We study the out-of-equilibrium dynamics of entanglement fluctuations in the nu = 1 quantum symmetric simple exclusion process, a free-fermion chain with hopping amplitudes that are stochastic in time but homogeneous in space. Previous work showed that the average entanglement growth after a quantum quench can be explained in terms of pairs of entangled quasiparticles performing random walks, leading to diffusive entanglement spreading. By incorporating the noise-induced statistical correlations between the quasiparticles, we extend this description to the full-time probability distribution of the entanglement entropy. Our generalized quasiparticle picture allows us to compute the average time evolution of a generic function of the reduced density matrix of a subsystem. We also apply our result to the entanglement asymmetry. This allows us to investigate the restoration of particle-number symmetry in the dynamics from initial states with no well-defined particle number. Regarding the possible existence of the quantum Mpemba effect, our analysis indicates that its occurrence is an extremely fine-tuned phenomenon, requiring very specific conditions and therefore being rather difficult to observe in practice.
We study the dynamics of the cumulants of the entanglement Hamiltonian in interacting integrable models following global quantum quenches. Building on recent results based on space-time duality, we show that these cumulants are exactly given by the cumulants of currents of suitable conserved charges evaluated in the macrostate selected by the initial state. This establishes a direct connection between entanglement dynamics and transport, providing a transport counterpart to the quasiparticle picture that successfully describes the evolution of the von Neumann entropy. In the free-fermion and conformal limits, our results reduce to the difference between the current cumulants carried by right- and left-moving excitations, recovering previously known expressions. In interacting integrable models, where a decomposition into independent right and left movers is no longer meaningful at the operator level, a similar structure survives at the level of the entanglement spectrum, yielding a unified description of entanglement Hamiltonian fluctuations across free, conformal, and interacting integrable systems.
We study the dynamics of entanglement asymmetry in random unitary circuits (RUCs). Focusing on a local U(1) charge, we consider symmetric initial states evolved by both local one-dimensional circuits and geometrically non-local RUCs made of two-qudit gates. We compute the entanglement asymmetry of subsystems of arbitrary size, analyzing the relaxation time scales. We show that the entanglement asymmetry of the whole system approaches its stationary value in a time independent of the system size for both local and non-local circuits. For subsystems, we find qualitative differences depending on their size. When the subsystem is larger than half of the full system, the equilibration time scales are again independent of the system size for both local and non-local circuits and the entanglement asymmetry grows monotonically in time. Conversely, when the subsystems are smaller than half of the full system, we show that the entanglement asymmetry is non-monotonic in time and that it equilibrates in a time proportional to the quantum-information scrambling time, providing a physical intuition. As a consequence, the subsystem-equilibration time depends on the locality of interactions, scaling linearly and logarithmically in the system size, respectively, for local and non-local RUCs. Our work confirms the entanglement asymmetry as a versatile and computable probe of symmetry in many-body physics and yields a phenomenological overview of entanglement-asymmetry evolution in typical non-integrable dynamics.
The essence of the Mpemba effect is that nonequilibrium systems may relax faster the further they are from their equilibrium configuration. In the quantum realm, this phenomenon arises in closed systems dynamics and is witnessed by features of symmetry and entanglement. Here, we study the quantum Mpemba effect in charge-preserving random circuits, combining extensive numerical simulations and analytical arguments. We show that the more asymmetric certain classes of initial states (tilted ferromagnets) are, the faster they restore symmetry and reach the grand-canonical ensemble. Conversely, other classes of states (tilted antiferromagnets) do not show the Mpemba effect. We provide a simple and general mechanism underlying the effect, based on the spreading of nonconserved operators in terms of conserved densities. Grounded only in locality, unitarity, and symmetry, our analysis clarifies the emergence of Mpemba physics in chaotic quantum systems.
Symmetry-resolved entanglement, capturing the refined structure of quantum entanglement in systems with global symmetries, has attracted a lot of attention recently. In this manuscript, introducing the notion of symmetry-resolved generalized entropies, we aim to develop a computational framework suitable for the study of excited state symmetry-resolved entanglement as well as the dynamical evolution of symmetry-resolved entanglement in symmetry-preserving out-of-equilibrium settings. We illustrate our framework using the example of (1+1)-d free massless compact boson theory, and benchmark our results using lattice computation in the XX chain. As a byproduct, our computational framework also provides access to the probability distribution of the symmetry charge contained within a subsystem and the corresponding full counting statistics.
We consider the effect of projective measurements on the quench dynamics of the bipartite entanglement entropy in one-dimensional free fermionic systems. In our protocol, we consider projective measurements of a U (1) conserved charge, the particle number, on some large subsystem, and study the entanglement entropies between the same subsystem and its complement. We compare the dynamics emanating from two classes of initial states, one which is an eigenstate of the charge and another which is not. Moreover, we consider the effects of a single measurement as well as multiple which are periodically performed. Using the quasiparticle picture, we obtain analytic expressions for the behaviour of the entanglement, which admit a transparent physical interpretation. In general, we find that measurements introduce two distinct types of corrections to the entanglement, which can be interpreted separately as classical and quantum contributions. The classical contribution is independent of the measurement outcome and scales logarithmically with the variance of the charge distribution. In contrast, the quantum contribution depends on the specific measurement outcome and can be significant for individual realisations; however, it becomes negligible when averaged over all possible outcomes. Our expressions reduce to previously known results for symmetry-resolved entanglement and full counting statistics in some relevant limits, and are confirmed by an exact calculation performed on the Néel initial state.
The entanglement asymmetry measures the extent to which a symmetry is broken within a subsystem of an extended quantum system. Here, we analyse this quantity in Haar random states for arbitrary compact, semi-simple Lie groups, building on and generalising recent results obtained for the U(1) symmetric case. We find that, for any group, the average entanglement asymmetry vanishes in the thermodynamic limit when the subsystem is smaller than its complement. When the subsystem and its complement are of equal size, the entanglement asymmetry jumps to a finite value, indicating a sudden transition of the subsystem from a fully symmetric state to one devoid of any symmetry. For larger subsystem sizes, the entanglement asymmetry displays a logarithmic scaling with a coefficient fixed by the dimension of the group. We also investigate the fluctuations of the entanglement asymmetry, which tend to zero in the thermodynamic limit. We check our findings against exact numerical calculations for the SU(2) and SU(3) groups. We further discuss their implications for the thermalisation of isolated quantum systems and black hole evaporation.