Aims. The increasing discovery of high-redshift AGNs in recent years imposes more stringent requirements on spectral analysis tools for deriving the properties of AGNs and their host galaxies from emission-line diagnostics. To address this need, we develop a new module for the popular SED-fitting tool Code Investigating GALaxy Emission (CIGALE), the [nebular_AGN] module, which enables the efficient and flexible simulation and fitting of emission lines originating from the broad-line regions (BLRs) and narrow-line regions (NLRs) of AGNs, and allows the estimation of the physical properties of these regions. Methods. We use the spectral synthesis code Cloudy to construct the database for the new module. Based on the X-ray and accretion disk continua implemented in CIGALE, we generate the incident radiation fields of the models. We then adopt the AGN geometry and dust settings implemented in CIGALE to define a flexible set of physical parameters for the gas clouds, thereby producing a comprehensive database for the [nebular_AGN] module. Results. We benchmark the [nebular_AGN] module using a quasar composite spectrum, an empirical metallicity calibration, and observational data from X-ray-selected AGNs. Our module can approximately reproduce the majority of quasar emission-line profiles, cover the key emission-line ratios observed in AGN samples, and provide an assessment of their physical properties. For specific combinations of parameters, the metallicity derived by our module is consistent with the empirical formula. We further compare our models with other photoionization models used to simulate AGN NLR emission, and perform a line-sensitivity study to identify the most effective diagnostic lines for each parameter in our module. Finally, we confirm that the dust attenuation law plays an important role in SED fitting.

Aims. This work aims to investigate the coevolution of metals and dust for 173 galaxies at 4.0 < z <= 11.4 spectroscopically observed by the NIRSpec instrument onboard the James Webb Space Telescope (JWST) in the Cosmic Evolution Early Release Science Survey (CEERS) project. More specifically, we want to study and analyse the properties of a sample of galaxies that show an extremely low dust attenuation and try to understand the possible physical processes at play in these galaxies. Methods. We developed a new version of the CIGALE code that accepts spectroscopic and photometric data. From a statistical comparison of the observations with the modelled spectra, we derived a set of physical parameters that allowed us to constrain the above physical processes. Results. Our analysis reveals a population of 49 extremely low-dust-attenuation galaxies (GELDAs) consistent with A(FUV) = 0.0 within 2 sigma(A_FUV) and M-star<10(9) M-circle dot. After stacking the spectra of the 49 GELDAs to increase the signal-to-noise ratio, we measured a very blue UV slope of beta(FUV)=-2.451 +/- 0.066 and a Balmer decrement of H alpha/H beta = 2.932 +/- 0.660 without underlying absorption and consistent with no dust attenuation; Case B assumes an underlying absorption of 2.5%. Furthermore, the proportion of GELDAs is much higher at z > 8.8 (83.3% of the total sample) than at z < 8.8 (26.3% of the total sample). This suggests that GELDAs became dominant in the early Universe. Assuming a prior far-infrared dust spectrum from the ALPINE sample, we performed an analysis of the properties of this galaxy population. The trends observed in the M-dust versus M-star diagram feature an upper and a lower sequence linked by objects that can be transitional. A comparison with models suggests that we might observe a critical transition at M-star approximate to 10(8.5) M-circle dot, corresponding to a critical metallicity of Z(crit) = 12+log(10)(O/H) approximate to 7.60 (i.e. Z/Z(circle dot)approximate to 0.1). At this point, galaxies transition from being dominated by stellar-dust production (mainly from supernovae) to grain growth through gas-dust accretion in the ISM. The observational critical metallicity Z(crit) derived in this paper is in good agreement with predictions from theoretical models for the onset of efficient grain growth. Furthermore, the mean gas-mass fraction of our entire sample at 4.0 < z < 11.4 is very high: f(gas)greater than or similar to 0.9. All of our galaxies, including GELDAs at all redshifts, contain a large amount of gas that was not expelled from the galaxies. Finally, the small size of the galaxies combined with the mass of gas lead to very high surface-gas densities - which put our sample below high-redshift sub-millimeter galaxies - at relatively low star formation efficiency. The population of high-redshift GELDAs would provide us with a natural and inherent explanation for the origin of the apparent tension between observations and theoretical models in the number density of bright galaxies at z greater than or similar to 9.

Context. Analyzing multiwavelength observations of galaxies from the far-ultraviolet to the millimeter domains provides a wealth of information on the physical properties of galaxies and their evolution across cosmic time. Existing or upcoming ground-based or space-borne facilities with enhanced sensitivities and resolutions open an unprecedented window on the galaxy evolution in the early Universe. However, the derivation of galaxy properties from nebular emission lines is not trivial because the interstellar medium in a galaxy may be patchy, and emission might originate both from starburst emission regions and from partially covered photon-dominated regions. Aims. We model both the nebular continuum emission and the line emission of the spectral energy distribution for galaxies exhibiting both a HII region-like emission and emission like that from a photon-dominated regions to account for the partial shielding of the starburst emission region by dense clouds. Methods. Nebular galactic emission was modeled from far-ultraviolet to millimeter ranges in a two-sector model with an HII region and a photon-dominated region. The partial overlap of the HII region by the photon-dominated region was accounted for by a covering factor. We generated grids of emission spectra using the Cloudy photoionization code for our two-sector model. Results. We compared our models with spectral lines from different samples of galaxies for which we mixed characteristic emission from starburst regions and denser regions. We show that the infrared line ratios can constrain the density, metallicity, photoionization parameter, and the covering factor. We also built infrared diagnostic diagrams based on different infrared line ratios in which the galaxy location contains information about its physical conditions. Conclusions. The two-sector model that couples starburst emission regions and photon-dominated regions can span the existing observations. We implement the resulting emission line libraries in the CIGALE galaxy spectral energy distribution code to help interpret spectrophotometric observations.

We investigate the coevolution of metals and dust for 173 galaxies at 4.010 by JWST. Besides, we observe that the metallicity of galaxies at z>8 presents a metal-to-stellar mass ratio larger than a few 10^-3, above a floor. This suggests a very fast rise of metals at high redshift, impacting the tentative detections of population III objects.

Context. Gas accretion and sublimation in various astrophysical conditions are crucial aspects of our understanding of the chemical evolution of the interstellar medium. To explain grain growth and destruction in warm media, ice mantle formation and sublimation in cold media, and gas line emission spectroscopy, astrochemical models must mimic the gas--solid abundance ratio. Ice-sublimation mechanisms determine the position of snow lines and the nature of gas emitted by and locked inside planetary bodies in star-forming regions. To interpret observations from the interplanetary and extragalactic interstellar mediums, gas phase abundances must be modelled correctly. Aims. We provide a collection of thermal desorption data for interstellar ice analogues, aiming to put constraints on the trapping efficiency of water ice, as well as data that can be used to evaluate astrochemical models. We conduct experiments on compact, amorphous H2O films, involving pure ices as well as binary and ternary mixtures. By manipulating parameters in a controlled way, we generate a set of benchmarks to evaluate both the kinetics and thermodynamics in astrochemical models. Methods. We conducted temperature-programmed desorption experiments with increasing order of complexity of ice analogues of various chemical compositions and surface coverages using molecular beams in ultrahigh vacuum conditions (1 x 10(-10) hPa) and low temperatures (10 K). We provide TPD curves of pure ices made of Ar, CO, CO2, NH3, CH3OH, H2O, and NH4+HCOO-, their binary ice mixtures with compact amorphous H2O, ternary mixtures of H2O:CH3OH:CO, and a water ice made in situ to investigate its trapping mechanisms. Results. Each experiment includes the experimental parameters, ice desorption kinetics for pure species, and the desorption yield (gas--solid ratio) for ice mixtures. From the desorption yields, we find common trends in the trapping of molecules when their abundance is compared to water: compact amorphous water ices are capable of trapping up to 20% of volatiles (Ar, CO, and CO2), similar to 3% of CH3OH, and similar to 5% NH3 in relation to the water content within the ice matrix; ammonium formate is not trapped in the water ice films, and compact amorphous water ice formed in situ has similar trapping capabilities to a compact amorphous water ice deposited using molecular beams. Conclusions. Deposited or formed in a very compact structure, amorphous water ice of less than 100 layers cannot trap a large fraction of other gases, including CO and CO2. These desorption yields offer insights into the availability of species that can react and form interstellar complex organic molecules during the warm-up phase of ice mantles. Furthermore, in order to be reliable, gas-grain astrochemical models should be able to reproduce the desorption kinetics and desorption yield presented in our benchmark laboratory experiments.

The nucleus of comet 67P/Churyumov-Gerasimenko exhibits a broad spectral reflectance feature around 3.2 µm, which is omnipresent in all spectra of the surface, and whose attribution has remained elusive since its discovery. Based on laboratory experiments, we have shown that most of this absorption feature is due to ammonium (NH4+) salts mixed with the dark surface material. The depth of the band is compatible with semi-volatile ammonium salts being a major reservoir of nitrogen in the comet, which could dominate over refractory organic matter and volatile species. These salts may thus represent the long-sought reservoir of nitrogen in comets, possibly bringing their nitrogen-to-carbon ratio in agreement with the solar value. Moreover, the reflectance spectra of several asteroids are compatible with the presence of NH4+ salts at their surfaces. The presence of such salts, and other NH4+-bearing compounds on asteroids, comets, and possibly in proto-stellar environments, suggests that NH4+ may be a tracer of the incorporation and transformation of nitrogen in ices, minerals and organics, at different phases of the formation of the Solar System.

Infrared (IR), sub-millimetre (sub-mm) and millimetre (mm) databases contain a huge quantity of high quality data. However, a large part of these data are photometric, and are thought not to be useful to derive a quantitative information on the nebular emission of galaxies. The aim of this project is first to identify galaxies at z > 4-6, and in the epoch of reionization from their sub-mm colours. We also aim at showing that the colours can be used to try and derive physical constraints from photometric bands, when accounting for the contribution from the IR fine structure lines to these photometric bands. We model the flux of IR fine structure lines with CLOUDY, and add them to the dust continuum emission with CIGALE. Including or not emission lines in the simulated spectral energy distribution (SED) modifies the broad band emission and colours. The introduction of the lines allows to identify strong star forming galaxies at z > 4 - 6 from the log10 (PSW_250um/PMW_350um) versus log10 (LABOCA_870um/PLW_500um) colour-colour diagramme. By comparing the relevant models to each observed galaxy colour, we are able to roughly estimate the fluxes of the lines, and the associated nebular parameters. This method allows to identify a double sequence in a plot built from the ionization parameter and the gas metallicity. The HII and photodissociation region (PDR) fine structure lines are an essential part of the SEDs. It is important to add them when modelling the spectra, especially at z > 4 - 6 where their equivalent widths can be large. Conversely, we show that we can extract some information on strong IR fine structure lines and on the physical parameters related to the nebular emission from IR colour-colour diagrams.

The microphysics of molecular hydrogen formation has an influence on galactic-scale star-formation rates over cosmic time. H 2 is the cooling agent needed to initiate the cloud collapse regulating the star-formation efficiency. H 2 formation is inefficient in the gas phase under typical interstellar conditions, requiring dust grain surfaces to act as catalysts. Small carbonaceous grains with sizes from roughly 4 to 100–200 Å, including polycyclic aromatic hydrocarbons (PAHs), have been shown to increase the H 2 formation rates due to their large surface-to-volume ratios. H 2 formation rates on PAHs were previously thought to reduce above temperatures of 50 K and H atom recombination was believed to be highly efficient only below 20 K. Until now, both laboratory experiments and theoretical modelling have suggested that H 2 cannot form on grains with temperatures above 100 K. Here we report evidence, through direct laboratory measurements, of the highly efficient formation of H 2 at temperatures up to 250 K on carbonaceous surfaces mimicking interstellar dust. By pushing their formation towards warmer temperatures, the H 2 molecules could start contributing substantially to the cooling of warmer gas (temperatures of roughly 50–250 K). This will have a marked impact on our understanding of H 2 formation in nearby galaxies and its efficiency in high-redshift galaxies where the Cosmic Microwave Background already pushes dust temperatures to more than 20 K.

The nature and evolution of high-redshift dusty star-forming galaxies (high-z DSFGs) remain an open question. Their massive gas reservoirs play an important role in driving the intense star-formation rates hosted in these galaxies. We aim to estimate the molecular gas content of high-z DSFGs by using various gas mass tracers such as the [CI], CO, [CII] emission lines and the dust content. These tracers need to be well calibrated as they are all limited by uncertainties on factors such as aCO, XCI, aCII and GDR, thereby affecting the determination of the gas mass accurately. The main goal of our work is to check the consistency between the gas mass tracers and cross-calibrate the uncertain factors. We observe the two [CI] line transitions for 29 SPT-SMGs with the ALMA-ACA. Additionally, we also present new APEX observations of [CII] line for 9 of these galaxies. We find a nearly linear relation between the infrared luminosity and [CI] luminosity if we fit the starbursts and main-sequence galaxies separately. We measure a median [CI]-derived excitation temperature of 34.5+/-2.1 K. We probe the properties of the interstellar medium (ISM) such as density and radiation field intensity using [CI] to mid- or high-J CO lines and [CI] to infrared luminosity ratio, and find similar values to the SMG populations in literature. Finally, the gas masses estimated from [CI], CO, dust, and [CII] do not exhibit any significant trend with the infrared luminosity or the dust temperature. We provide the various cross-calibrations between these tracers. Our study confirms that [CI] is a suitable tracer of the molecular gas content, and shows an overall agreement between all the classical gas tracers used at high redshift. However, their absolute calibration and thus the gas depletion timescale measurements remain uncertain.

Aims. The Kennicutt-Schmidt (KS) relation between the gas and the star formation rate (SFR) surface density (Σ gas − Σ SFR ) is essential to understand star formation processes in galaxies. To date, it has been measured up to z ∼ 2.5 in main-sequence galaxies. In this Letter our aim is to put constraints at z ∼ 4.5 using a sample of four massive main-sequence galaxies observed by ALMA at high resolution. Methods. We obtained ∼0.3″-resolution [CII] and continuum maps of our objects, which we then converted into gas and obscured SFR surface density maps. In addition, we produced unobscured SFR surface density maps by convolving Hubble ancillary data in the rest-frame UV. We then derived the average Σ SFR in various Σ gas bins, and estimated the uncertainties using a Monte Carlo sampling. Results. Our galaxy sample follows the KS relation measured in main-sequence galaxies at lower redshift, and is slightly lower than the predictions from simulations. Our data points probe the high end both in terms of Σ gas and Σ SFR , and gas depletion timescales (285–843 Myr) remain similar to z ∼ 2 objects. However, three of our objects are clearly morphologically disturbed, and we could have expected shorter gas depletion timescales (≲100 Myr) similar to merger-driven starbursts at lower redshifts. This suggests that the mechanisms triggering starbursts at high redshift may be different than in the low- and intermediate- z Universe.

Context. Protostellar jets are an important agent of star formation feedback, tightly connected with the mass-accretion process. The history of jet formation and mass ejection provides constraints on the mass accretion history and on the nature of the driving source. Aims. characterize the time-variability of the mass-ejection phenomena at work in the class 0 protostellar phase in order to better understand the dynamics of the outflowing gas and bring more constraints on the origin of the jet chemical composition and the mass-accretion history. Methods. Using the NOrthern Extended Millimeter Array (NOEMA) interferometer, we have observed the emission of the CO 2–1 and SO N J = 4 –4 3 rotational transitions at an angular resolution of 1 . 0 (cid:48)(cid:48) (820 au) and 0 . 4 (cid:48)(cid:48) (330 au), respectively, toward the intermediate-mass class 0 protostellar system CepE.

The luminosity functions at z < 4 - 5 suggest that most galaxies have a relatively low stellar mass (logM_star = 10) and a low dust attenuation (A_FUV = 1.0). The physical properties of these objects are quite homogeneous. We used an approach where we combined their rest-frame far-infrared and submillimeter emissions and utilized the universe and the redshift as a spectrograph to increase the amount of information in a collective way. From a subsample of 27 ALMA-detected galaxies at z > 4.5, we built an infrared spectral energy distribution composite template. It was used to fit, with CIGALE, the 105 galaxies (detections and upper limits) in the sample from the FUV to the FIR. The derived physical parameters provide information to decipher the nature of the dust cycle and of the stellar populations in these galaxies. The derived IR composite template is consistent with the galaxies in the studied sample. A delayed star formation history with tau_main = 500 Myrs is slightly favored by the statistical analysis as compared to a delayed with a final burst or a continuous star formation history. The position of the sample in the star formation rate (SFR)- M_star diagram is consistent with previous papers. The redshift evolution of the log M_star versus A_FUV relation is in agreement with evolution in the redshift of this relation. This evolution is necessary to explain the cosmic evolution of the average dust attenuation of galaxies. Evolution is also observed in the L_dust/ L_FUV (IRX) versus UV slope beta_FUV diagram: younger galaxies have bluer beta_FUV. We modeled the shift of galaxies in the IRX versus the beta_FUV diagram with the mass-weighted age as a free parameter, and we provide an equation to make predictions.

Context. Broadband optical constants of astrophysical ice analogues in the infrared (IR) and terahertz (THz) ranges are required for modeling the dust continuum emission and radiative transfer in dense and cold regions, where thick icy mantles are formed on the surface of dust grains. Such data are still missing from the literature, which can be attributed to the lack of appropriate spectroscopic systems and methods for laboratory studies. Aims. In this paper, the THz time-domain spectroscopy (TDS) and the Fourier-transform IR spectroscopy (FTIR) are combined to study optical constants of CO and CO2 ices in the broad THz-IR spectral range. Methods. The measured ices were grown at cryogenic temperatures by gas deposition on a cold silicon window. We developed a method to quantify the broadband THz-IR optical constants of ices, based on the direct reconstruction of the complex refractive index of ices in the THz range from the TDS data and the use of the Kramers-Kronig relation in the IR range for the reconstruction from the FTIR data. Uncertainties introduced by the Kramers-Kronig relations were eliminated by merging the THz and IR spectra. Finally, the reconstructed THz-IR response was analyzed using classical models of complex dielectric permittivity. Results. The complex refractive index of CO and CO2 ices deposited at the temperature of 28 K was obtained in the range of 0.312.0 THz and fitted using the analytical Lorentz model. Based on the measured dielectric constants, opacities of the astrophysical dust with CO and CO2 icy mantles were computed. Conclusions. The method developed in this work can be used for a model-independent reconstructions of optical constants of various astrophysical ice analogs in a broad THz-IR range. Such data can provide important benchmarks for interpreting broadband observations from existing and future ground-based facilities and space telescopes. The reported results will be useful in modeling sources that exhibit a drastic molecular freeze-out, such as the central regions of prestellar cores and mid-planes of protoplanetary disks, as well as CO and CO2 snow lines in disks.

Modern and future surveys effectively provide a panchromatic view for large numbers of extragalactic objects. Consistently modeling these multiwavelength survey data is a critical but challenging task for extragalactic studies. The Code Investigating GALaxy Emission (cigale) is an efficient python code for spectral energy distribution (SED) fitting of galaxies and active galactic nuclei (AGNs). Recently, a major extension of cigale (named x-cigale) has been developed to account for AGN/galaxy X-ray emission and improve AGN modeling at UV-to-IR wavelengths. Here, we apply x-cigale to different samples, including Cosmological Evolution Survey (COSMOS) spectroscopic type 2 AGNs, Chandra Deep Field-South X-ray detected normal galaxies, Sloan Digital Sky Survey quasars, and COSMOS radio objects. From these tests, we identify several weaknesses of x-cigale and improve the code accordingly. These improvements are mainly related to AGN intrinsic X-ray anisotropy, X-ray binary emission, AGN accretion-disk SED shape, and AGN radio emission. These updates improve the fit quality and allow for new interpretation of the results, based on which we discuss physical implications. For example, we find that AGN intrinsic X-ray anisotropy is moderate, and can be modeled as LX(θ)∝1+cosθ , where θ is the viewing angle measured from the AGN axis. We merge the new code into the major branch of cigale, and publicly release this new version as cigale v2022.0 on https://cigale.lam.fr.

We used active galactic nuclei (AGNs) with X-ray luminosities, LX, 2 − 10 keV ∼ 1042.5 − 44 erg s−1, from the COSMOS-Legacy survey that lie within the UltraVISTA region and cross-matched them with the LEGA-C catalogue. The latter provides measurements of the calcium break, Dn4000, and Hδ Balmer line that allow us to study the stellar populations of AGNs and compare them with a galaxy reference catalogue. Our samples consist of 69 AGNs and 2176 non-AGN systems, within 0.6 < z < 1.3, that satisfy the same photometric selection criteria. We constructed the spectral energy distributions (SEDs) of both population and used the CIGALE code to investigate the effect of the two indices in the SED fitting process. Our analysis shows that the inclusion of Dn4000 and Hδ allows CIGALE to better constrain the ages of the stellar populations. Furthermore, we find an increase of the estimated stellar masses by ∼0.2 dex, in particular for systems with young stars (Dn4000 < 1.5), when the two indices are included in the SED fitting. We then compare the Dn4000 and Hδ of AGNs with sources in the reference catalogue, accounting for the different stellar mass of the two populations. Our analysis reveals that low-to-moderate LX AGNs tend to reside in galaxies with older stellar populations and are less likely to have experienced a recent star formation burst compared to galaxies in the control sample. Finally, we compared the two populations as a function of their morphology (bulge-dominated, BD, versus non-BD) and compactness (mass-to-size ratio). A similar fraction of AGN and non-AGN systems are classified as non-BD (∼70%). Our analysis shows that BD AGN tend to have younger stellar populations compared to BD non-AGN systems. On the other hand, non-BD AGNs have, on average, older stellar populations and are less likely to have experienced a burst compared to non-BD sources in the reference sample. Furthermore, AGNs tend to prefer more compact systems compared to non-AGNs.

High-redshift dusty star-forming galaxies with very high star formation rates (500−3000 M⊙ yr−1) are key to understanding the formation of the most extreme galaxies in the early Universe. Characterising the gas reservoir of these systems can reveal the driving factor behind the high star formation. Using molecular gas tracers such as, high-J CO lines, neutral carbon lines, and the dust continuum, we can estimate the gas density and radiation field intensity in their interstellar media. In this paper, we present high resolution (∼0.4″) observations of CO(7−6), [CI](2−1), and dust continuum of three lensed galaxies from the South pole telescope – sub-millimetre galaxies (SPT-SMG) sample at z ∼ 3 with the Atacama Large Millimetre/submillimetre Array. Our sources have high intrinsic star formation rates (> 850 M⊙ yr−1) and rather short depletion timescales (< 100 Myr). Based on the L[CI](2−1)/LCO(7 − 6) and L[CI](2−1)/LIR ratios, our galaxy sample has similar radiation field intensities and gas densities compared to other submillimetre galaxies. We performed visibility-based lens modelling on these objects to reconstruct the kinematics in the source plane. We find that the cold gas masses of the sources are compatible with simple dynamical mass estimates using ULIRG-like values of the CO-H2 conversion factor αCO, but not Milky Way-like values. We find diverse source kinematics in our sample: SPT0103−45 and SPT2147−50 are likely rotating disks, while SPT2357−51 is possibly a major merger. The analysis presented in the paper could be extended to a larger sample to determine better statistics of morphologies and interstellar medium properties of high-z dusty star-forming galaxies.

Aims. Dust is observed in the polar regions of nearby active galactic nuclei (AGN) and it is known to contribute substantially to their mid-IR emission and to the obscuration of their UV to optical emission. We aim to carry out a statistical test to check whether this component is a common feature based on an analysis of the integrated spectral energy distributions of these composite sources. Methods. We selected a sample of 1275 broad-line AGN in the XMM-XXL field, with optical to infrared photometric data. These AGN are seen along their polar direction and we expect a maximal impact of dust located around the poles when it is present. We used X-CIGALE, which introduces a dust component to account for obscuration along the polar directions, modeled as a foreground screen, and an extinction curve that is chosen as it steepens significantly at short wavelengths or is much grayer. By comparing the results of different fits, we are able to define subsamples of sources with positive statistical evidence in favor of or against polar obscuration (if present) and described using the gray or steep extinction curve. Results. We find a similar fraction of sources with positive evidence for and against polar dust. Applying statistical corrections, we estimate that half of our sample could contain polar dust and among them, 60% exhibit a steep extinction curve and 40% a flat extinction curve; although these latter percentages are found to depend on the adopted extinction curves. The obscuration in the V-band is not found to correlate with the X-ray column density, while A(V)/N-H ratios span a large range of values and higher dust temperatures are found with the flat, rather than with the steep extinction curve. Ignoring this polar dust component in the fit of the spectral energy distribution of these composite systems leads to an overestimation of the stellar contribution. A single fit with a polar dust component described with an SMC extinction curve efficiently overcomes this issue but it fails at identifying all the AGN with polar dust obscuration.

We perform a spectral energy distribution fitting analysis on a COSMOS photometric sample covering the ultra-violet up to the far-infrared wavelengths and including emission lines from the Fiber Multi-Object Spectrograph survey. The sample consists of 182 objects with Hαand [OIII]λ5007 emission line measurements lying in a redshift range of 1.40 < z < 1.68. We obtain robust estimates of the stellar mass and star-formation rate spanning over a range of 109.5 − 1011.5M⊙and 101 − 103M⊙yr−1from the Bayesian analysis performed with CIGALE and using continuum photometry and Hαfluxes. Combining photometry and spectroscopy gives secure estimations of the amount of dust attenuation for both continuum and line emissions. We obtain a median attenuation ofAHα = 1.16 ± 0.19 mag andA[OIII] = 1.41 ± 0.22 mag. Hαand [OIII]λ5007 attenuations are found to increase with stellar mass, confirming previous findings with Hα. A difference of 57% in the attenuation experienced by emission lines and continuum is found to be in agreement with the emission lines being more attenuated than the continuum emission. Implementation of new CLOUDY HII-region models in CIGALE enables good fits of the Hα, Hβ, [OIII]λ5007 emission lines with discrepancies smaller than 0.2 dex in the predicted fluxes. Fitting the [NII]λ6584 line is found challenging due to well-known discrepancies in the locus of galaxies in the [NII]-BPT diagram at intermediate and high redshifts. We find a positive correlation between SFR andL[OIII]λ5007 after correcting for dust attenuation and we derive the linear relation log10(SFR/M⊙yr−1)=log10(L[OIII]/ergs s−1)−(41.20 ± 0.02). Leaving the slope as a free parameter leads to log10(SFR/M⊙yr−1)=(0.83 ± 0.06)log10(L[OIII]/ergs s−1)−(34.01 ± 2.63). The spread in the relation is driven by differences in the gas-phase metallicity and ionization parameter accounting for a 0.24 dex and 1.1 dex of the dispersion, respectively. We report an average value of logU ≈ −2.85 for this sample of galaxies. Including HII-region models to fit simultaneously photometric data and emission line fluxes is paramount to analyses of upcoming data sets from large spectroscopic surveys of the future, such as MOONS and PFS.

Context. The nitrogen reservoir in planetary systems is a long-standing problem. Some of the N-bearing molecules are probably incorporated into the ice bulk during the cold phases of the stellar evolution, and may be gradually released into the gas phase when the ice is heated, for example in active comets. The chemical nature of the N-reservoir should greatly influence how, when, and in what form N returns to the gas phase, or is incorporated into the refractory material forming planetary bodies. Aims. We present the study of the thermal desorption of two ammonium salts, ammonium formate and ammonium acetate, from a gold surface and from a water ice substrate. Methods. Temperature-programmed desorption experiments and Fourier transform infrared reflection spectroscopy were conducted to investigate the desorption behavior of ammonium salts. Results. Ammonium salts are semi-volatile species releasing neutral species as major components upon desorption, namely ammonia and the corresponding organic acid (HCOOH and CH3COOH), at temperatures higher than the temperature of thermal desorption of water ice. Their desorption follows a first-order Wigner-Polanyi law. We find the first-order kinetic parameters A = 7.7 ± 0.6 × 1015 s−1 and Ebind = 68.9 ± 0.1 kJ mol−1 for ammonium formate and A = 3.0 ± 0.4 × 1020 s−1 and Ebind = 83.0 ± 0.2 kJ mol−1 for ammonium acetate. The presence of a water ice substrate does not influence the desorption kinetics. Ammonia molecules locked in salts desorb as neutral molecules at temperatures much higher than previously expected, and that are usually attributed to refractory materials. Conclusions. The ammonia snow line has a smaller radius than the water snow line. As a result, the NH3/H2O ratio content in Solar System bodies can be a hint to where they formed and subsequently migrated.