R.E. Schmidt | AMiner学者主页

Looking for compounds Cs2MF4 the cesium richest composition we found at M(II) = Co, Ni was Cs7M4F15. X-ray single crystal work revealed a layer structure (P21/c, Z=2), built up from face-sharing double octahedra M2F9 which are mutually connected via three of their vertices. Some interatomic distances are given in Table I, along with data of six novel compounds Ba2AM2F9 (R3m, Z=3). The puckered layer structure of the latter consists of single octahedra, sharing three corners in a fac-position. It derives from the hexagonal perovskite structure of CsCoF3 by omitting the central cations within the groups of three face-sharing octahedra.

1985Journal of Fluorine Chemistry（1985）引用：3

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1Structural and magnetic studies on new cesium and barium fluorometallates of 3d transition elements

D. Babel, E. Herdtweck,H. Holler,R.E. Schmidt,S. Kummer

Looking for compounds Cs2MF4 the cesium richest composition we found at M(II) = Co, Ni was Cs7M4F15. X-ray single crystal work revealed a layer structure (P21/c, Z=2), built up from face-sharing double octahedra M2F9 which are mutually connected via three of their vertices. Some interatomic distances are given in Table I, along with data of six novel compounds Ba2AM2F9 (R3m, Z=3). The puckered layer structure of the latter consists of single octahedra, sharing three corners in a fac-position. It derives from the hexagonal perovskite structure of CsCoF3 by omitting the central cations within the groups of three face-sharing octahedra.