La presente invention concerne des procedes se rapportant generalement a la preparation et l'introduction d'un melange de fluides dans un volume confine, et plus specifiquement dans un volume annulaire situe entre deux colonnes de tubage orientees de facon concentrique a l'interieur d'un puits produisant un fluide d'hydrocarbure. Les melanges de fluides de l'invention se pretent particulierement bien a la gestion de la pression dans des volumes localises. Les melanges de fluides comprennent au moins un monomere polymerisable et au moins un inhibiteur. Les traitements et procedes de l'invention permettent de conserver, de transporter et/ou d'injecter le melange de fluides dans des volumes localises, par exemple dans un volume localise defini par des colonnes de tubage de puits concentriques.

Abstract In deepwater or other sub-sea completed wells, fluids, usually spacers or drilling fluid, are commonly trapped in casing annuli above the top-of-cement and below the wellhead. When these trapped fluids are heated by the passage of warm produced fluids, thermal expansion can create very high pressures (10,000 -12,000 psi or more) and cause the collapse of casing and tubing strings.1,2,4,12,15 Mitigation methods such as vacuum insulated tubing to limit heat transfer,6,7,14 nitrogen-based foam spacers to give highly compressible trapped fluids,8,9,10,11 crushable urethane foam,3 etc. are somewhat successful but are either very expensive, logistically troublesome or have unacceptable failure rates. This paper continues the discussion of a new approach which has created a water-based spacer fluid that will be used just ahead of the cement. The spacer contains perhaps 10-30% of emulsified liquid methyl methacrylate monomer (MMA). Upon polymerization, the MMA phase shrinks by 20%, creating room for the remaining fluid to thermally expand without creating catastrophic pressure. The polymerization is triggered by heat and a chemical initiator. The target temperature can be controlled by choosing an appropriate type and concentration of chemical initiator. Premature polymerization during spacer placement can be prevented by an appropriate type, and amount, of inhibitor. The initial lab work and a mid-scale field trial of this technology were reported in detail in SPE/IADC 104698.1 This paper covers the development and field testing (land) of all the equipment and processes necessary to apply the technology in deep water.

Abstract In deepwater or other sub-sea completed wells, fluids, usually spacers or drilling fluid, are commonly trapped in casing annuli above the top-of-cement and below the wellhead. When these trapped fluids are heated by the passage of warm produced oil and gas, thermal expansion can create very high pressures (10,000-12,000 psi or more) and cause the collapse of casing and tubing strings.1,3,11,14 Mitigation methods such as vacuum insulated tubing to limit heat transfer,5,6,13 nitrogen foam spacers to give highly compressible trapped fluids,7,8,9,10 crushable urethane foam insulation,2 etc. are somewhat successful but are either very expensive, logistically troublesome or have unacceptable failure rates. This paper covers a new approach which has created a water-based spacer fluid that will be used just ahead of the cement. The spacer contains perhaps 20-40% of emulsified methyl methacrylate monomer (MMA). Upon polymerization, the MMA phase shrinks by 20%, creating room for the remaining fluid to thermally expand without creating catastrophic pressure. The polymerization is triggered by heat and the target temperature can be controlled by an appropriate type and concentration of chemical initiator. Premature polymerization during spacer placement can be prevented by an appropriate type, and amount, of inhibitor. A spacer formulation (viscosifier, emulsifiers, MMA, weighting agent, inhibitor, etc.) has been developed which covers the range of densities expected in deepwater wells. A matrix of bench top tests has determined the types and amounts of initiator and inhibitor needed to adjust the temperature of the polymerization to the range of temperatures expected in the field. These results have been confirmed in an advanced pressure-volume-temperature (PVT) cell that closely simulates downhole conditions. A successful mid-scale field trial has been conducted in a 500-ft test well using normal oilfield casing, drillpipe, pumps, etc. A method was devised to add the initiator on-the-fly as the spacer is pumped downhole. Safe handling procedures have been developed for mud plant mixing, transportation, and rigsite application. The new spacer will be tested in an onshore well in the near future, and then in several deepwater wells prior to commercialization.