Alleghanian phyllonites in a shear zone in southern New England were formed by the retrogression and hydration of a high-grade Acadian pelitic schist. The retrogression was locally incomplete, resulting in both heterogeneous mineralogy and mineral compositions, and in many arrested reaction textures. These features, documented by backscattered electron and element map imaging, and by Ar-40/Ar-39 dating, provide a record of the processes active as the schist was converted to a phyllonite. On the margins of the shear zone relic biotite and garnet grains survive but are partially replaced by chlorite. Relic high-grade muscovite flakes containing up to 35 % paragonite (pg) also persist but are entrained in swarms of pg-poor muscovite flakes producing folia with an anastomosing network of muscovite grains of variable composition. Single crystals of pg-rich muscovite are truncated by muscovite in successively younger cross-cutting folia that contain decreasing pg contents, falling to <5% pg in the youngest folia. In the core of the shear zone all high-grade minerals are destroyed, but recrystallization continues with earlier greenschist facies folia replaced by lower grade and pg-poorer muscovite in younger folia. Muscovite grains in truncated folia are commonly kinked and selective recrystallization of muscovite in kink bands to pg-poor-compositions demonstrates that strain energy helped drive recrystallization. The boundaries of these new pg-poor muscovite folia are sharp, and truncations indicate that grain boundary sliding (GBS) involved dissolution. GBS also enabled folding by flexural slip along muscovite grain boundaries. Fold amplitudes increased as chlorite dissolved from fold limbs precipitated in fold hinges producing crescent-shaped saddle-reef-like structures. Together these observations of truncation and replacement by dissolution and precipitation demonstrate that pressure solution and GBS facilitated both the formation of the phyllonitic shear zone and slip along it.

A suite of slate samples collected along a 2 km transect crossing the Lishan fault in central Taiwan were evaluated to assess the role of ductile deformation in natural graphitization at lower greenschist facies metamorphic conditions. The process of natural aromatization, or graphitization, of an organic precursor is well established as a thermally driven process; however, experimental studies have shown that the energy provided by deformation can substantially reduce the activation energy required for graphitization. This study provides a natural example of deformation-induced graphitization. A strain gradient approaching the Lishan fault was established by scanning electron microscope imaging and X-ray diffraction analysis of phyllosilicates and quartz that showed an increase in the strength of slaty cleavage development via dissolution-precipitation processes. Thermal conditions were constrained to be near isothermal using calcite-dolomite geothermometry. Raman spectroscopic results from carbonaceous material, including D1-full width-at-half-maximum (FWHM), G-FWHM, Raman band separation (RBS), and a lesser-known vibrational mode B2g-FWHM, showed robust linear trends across the same sampling transect. However, the G-FWHM parameter showed a trend opposite of that expected from thermally driven graphitization. The Raman results are interpreted to reflect a strain-driven reduction in graphite crystallite size (decrease in G-FWHM) but improvement in structural ordering in individual coherent domains. A multiple linear regression with an R2 value of 0.92 predicts the graphite D1-FWHM values from the XRD-derived ratio of muscovite populations and muscovite microstrain, demonstrating the concomitant recrystallization of silicates and carbonaceous material across the strain gradient, despite the disparate processes accommodating the deformation. This study demonstrates the role of deformation in natural graphitization and provides a new perspective on the use of graphite as a geothermometer in strongly deformed greenschist facies rocks.

The extrusion tectonic model for the southeastern margin of the Himalayan orogeny links the crustal shear activity along the Red River Shear Zone (RRSZ) to the opening of the South China Sea (SCS). The Day Nui Con Voi (DNCV) metamorphic massif in northern Vietnam strikes NW-SE, is bounded by the RRSZ to the south and continues along the strike where it meets the SCS. The DNCV is thus a critical area to document thermotectonic history in order to advance our understanding of the tectonic evolution of Indochina extrusion and its relationship to the opening of the SCS. Our new 40 Ar/ 39 Ar data combined with microstructural and petrological analyses constrained the timing of the left-lateral shearing of the RRSZ and revealed the thermal evolution of the DNCV metamorphic massif. Three ductile deformation events were observed. D 1 formed NNW-SSE striking upright folds under granulite to upper amphibolite facies conditions. D 2 was a horizontal to sub-horizontal folding event that occurred at amphibolite facies conditions. D 3 was a doming event that formed NW-SE striking up-right folds bounded by left-lateral shearing mylonite belts along the two limbs. The S/C fabrics were defined by muscovite fish, quartz + albite + K-feldspar aggregates, and muscovite folia. The D 3 doming event exhumed the DNCV metamorphic massif from amphibolite facies conditions to the lower greenschist facies conditions. The 40 Ar/ 39 Ar ages obtained from amphibole (∼26 Ma), phlogopite (∼25 Ma), muscovites (∼24-23 Ma), biotite (∼25-23 Ma), and K-feldspars (∼25-22 Ma) from different structural domains of the DNCV metamorphic massif indicated a rapid exhumation ∼26–22 Ma. We interpreted this as the time period for the D 3 event, with the onset of left-lateral shearing occurring around 24 Ma based on ages obtained from syn-kinematic muscovites. This age was much younger than the initiation of sea-floor spreading of the SCS (since 32 Ma) but coincided with the age for the ridge jump event in the SCS. Based on these new data, we proposed that extrusion tectonism cannot be the cause for the initial opening of the SCS. Rather, the extrusion of the Indochina block was temporally correlative with the southward ridge jump event of the already opened SCS.

We present a tectonic model for the generation of quartzofeldspathic veins and pegmatite dikes found in southern New England that proposes the following: (1) Hydraulic fracturing produces the initial fracture that opens to become a vein, and (2) oscillating differential stress produces a gradient in interstitial fluid pressure that draws the melt to the dilating walls of the fracture. Oscillating fluid pressures at the dike walls lead to oscillating rates of crystallization, and thus to alternating aplitic and pegmatitic textures in dikes as thin as a few centimeters. Excess alkalis and SiO2(aq) lower the solidus temperature of the granitic liquid and thus stabilize a per-alkaline silicate liquid without crystallization. This silicate liquid is capable of crystallizing only quartz, only feldspars, or both. Crystallization of this liquid lowers its pH and accounts for the mineralogical zoning consisting of quartz cores, feldspathic mantles, and muscovite-bearing margins common in many quartzofeldspathic veins.