It is shown experimentally that a cornea represents a 213 nm UV inhomogeneous material both at depth and around a surface in relation to UV effective absorption coefficient and local laser depth ablation rate, which should be taken into account for a more exact planning of a profile of removed cornea collagen material during eye vision correction.
The laser-induced phase separation of charcoal particles on additive-free cotton linters cellulose paper was investigated by electron and optical microscopy, colorimetry, and diffuse reflectance FT-IR. The fibre bundles were vaporised in depth of several 10 μm above destruction fluence thresholds using visible 532 nm radiation. This is in contrast to mid-ultraviolet 213 nm radiation, where only the top fibre bundles were modified and partially evaporated. The colorimetric lightness results generally represented the cleaning status, whereas the colorimetric yellowing data represented irreversible chemical and/or photochemical changes. Charcoal-contaminated paper treated with visible and mid-ultraviolet radiation exhibited yellowing, whereas uncontaminated did not. This suggests that the electron-rich plasma generated by the evaporation of the particles heats the adjacent substrate and also excludes oxygen. Mid-ultraviolet, in contrast to visible radiation, shows particle removal always accompanied by paper destruction. IR spectroscopy results suggest cross-linking by ether bonds near the destruction threshold, but do not prove the formation of oxidation products and double bonds as the basis of the yellowing. A “cleaning window” between the cleaning threshold (0.1 J/cm2) and the paper destruction threshold (2.9 J/cm2) with a pulse number of 2 is provided by visible 532 nm laser treatment.
Ancient leather samples from original upholstered furniture were treated with nanosecond Nd:YAG laser radiation with wavelengths of 1,064, 532, and 266 nm. The novel approach was the simultaneous application of these wavelengths. It opened new approaches for laser cleaning leather. Extensive diagnostics such as absorbance of different layers of leather, chemical composition and microscopic inspection studies before and after cleaning were conducted. Advantageous results with simultaneous UV–IR (266nm + 1,064nm) radiation are presented and discussed.
In the present study, a newly developed one-beam IR–UV laser cleaning system is presented. This system may be used for different applications in diverse fields, such as outdoors stonework conservation and canvas paintings restoration. The simultaneous use of the fundamental radiation of a Q-switched Nd:YAG laser at 1064nm and its third harmonic at 355nm was found appropriate to clean pollution crusts, while ensuring that no discoloration (“yellowing”) would occur. The optimum ratio of UV to IR wavelengths in the final cleaning beam was investigated. In parallel, the same system was tested in diverse applications, such as the removal of bonding glues from duplicated canvases. The optimum laser parameters were investigated both on technical samples as well as on original paintings.
Investigations on optimization of methods of laser cleaning of metal artworks by pulses of microsecond and nanosecond duration on wavelengths of 1064nm and 1320nm of Nd:YAG-Lasers were fulfilled. Comparison of results of cleaning under different conditions was done.