Long-range atmospheric transport (LRAT) of carbonaceous aerosols from biomass burning (BB) can influence urban air quality, complicating downwind source attribution. Routine monitoring (e.g., PM2.5 bulk concentration) struggles to distinguish BB emissions from the complex, high background mixture of anthropogenic emissions typically found in urban areas. Therefore, a key challenge is distinguishing a unique, reliable BB tracer suitable for long-term urban monitoring, particularly when BB signatures are diluted from transport or masked by urban sources. Here, a three-year BB tracer study evaluated three unique approaches in Houston, TX with a complex mixture of local sources and frequent impacts from LRAT of BB and Saharan dust. The BB tracer approaches 1) absorption and scattering & Aring;ngstr & ouml;m exponents (i.e., aerosol optical), 2) NOAA hazard mapping system smoke product (i.e., satellite observation), and 3) PM2.5/CO ratios (i.e., BB emission ratios) identified BB influence at varying rates due to fundamental methodological differences (i.e., composition, concentration, and remote sensing). The aerosol optical approach identified BB influence on similar to 1 out of 5 days, compared to similar to 3 in 5 days of smoke aloft for satellite observations. The emission ratio approach indicated BB similar to 2 in 5 days, with periods of dust misclassified as BB. Using the aerosol optical approach as a conservative estimate, the average PM2.5 during BB-influenced days was 10.5 +/- 4.0 mu g m(-3) exceeding the 2024 annual PM2.5 standard of 9 mu g m(-3). This study provides a framework for identifying BB influence, improving understanding of its contribution to urban air quality, and thereby supporting effective monitoring and management.

Houston, Texas, with its large-scale industrial activities, serves as a national hub for petrochemical processing and chemical feedstock production, making it a unique emission region for volatile organic compounds (VOCs) and production-related emissions. These emissions can be associated with industrial activities, including solvent usage and production to manufacture consumer products such as volatile chemical products. To support the Houston-based Dept. of Energy’s Atmospheric Measurement Radiation program-led Tracking Aerosol Convection ExpeRiment (TRACER) projects, VOCs were measured at the San Jacinto Battleground State Historic Site during September 2021 and 2022. The observed VOC mixing ratios reveal unique emission signatures for select VOCs, including benzene, toluene, acetone, and isoprene. Routine nighttime enhancements of these compounds exceeded the urban background, with mixing ratios increasing by up to 20 ppbv per hour and persisting for up to 6 h, suggesting that emissions from local industrial activities near the Houston Ship Channel (HSC) are impacting the site. For example, mixing ratios exceeding 15 ppbv for at least one VOC were observed on 58% of nights (n = 32 nights), with 19 nights (~35%) having two or more VOCs with mixing ratios above 15 ppbv. For select peak emission events, the NOAA dispersion model estimated plume transport across parts of the urban system, suggesting that VOCs from the HSC may impact local air quality. This study highlights the importance of VOC-related emissions from industrial production and supply chains in contributing to total VOC emissions in urban areas like Houston, Texas.

We characterized optical properties (absorption, scattering, and backscattering coefficients, & Aring;ngstr & ouml;m exponents, single scattering albedo) of aerosols during dust events at an urban site in El Paso, Texas using in-situ, real-time measurements. Simultaneous measurements of particulate matter (PM10, PM2.5) and wind data from an adjacent Texas Commission on Environmental Quality Continuous Ambient Monitoring Station are used in this study. Data from both sites was obtained at 5-min resolution. Twenty-seven dust events (15 synoptic, 12 mesoscale) occurred during 24 days from April-June 2021. HYSPLIT and STILT back-trajectories indicated many dust events (similar to 46 %) originated from the west-southwest (favoring transport across dust source areas in the Chihuahuan Desert). Mean absorption & Aring;ngstr & ouml;m exponent values of El Paso dust (1.19 and 1.15 for synoptic and mesoscale events) were lower than published values for "pure" dust at other locations (generally accepted as greater than 2). Single scattering albedo values averaged 0.94 during synoptic and mesoscale dust events, confirming the scattering nature of mineral dust in the region. PM10 and PM2.5 concentrations averaged 191 and 41 mu g/m(3) during dust event periods versus 28 and 8.7 mu g/m(3) during non-event (background) periods. Absorption / scattering & Aring;ngstr & ouml;m exponent ratios of dust event aerosols were representative of large particles-black carbon mixture rather than a "pure" dust, suggesting mixing with urban aerosols, while many observations during non-event periods fall into the large particles-black carbon mixture and large particles-low absorption categories, suggesting that dust is a constant key component of the aerosols in El Paso. The 5-min time resolution revealed the evolution of complex aerosol events (e.g., brown carbon followed by dust, multiple dust events within one day, fireworks, advection of low-absorption gypsum dust from White Sands. New Mexico), emphasizing the importance of detecting and quantifying high intensity, short-duration events "lost" in 24-h or hourly air quality data.

Situated at a land–sea interface, Houston, Texas, is a national hub for the petrochemical industry and has the second-fastest-growing metropolitan population in the United States. Addressing air quality in this region is uniquely challenging, due in part to its wide range of meteorological conditions (e.g., convection systems and temperature inversions) and continuum of volatile organic compound (VOC) and aerosol sources (e.g., anthropogenic and biogenic). As a result, Houston was chosen as the location for the Department of Energy's Atmospheric Radiation Measurement (ARM)-program-led Tracking Aerosol Convection ExpeRiment (TRACER), which investigated cloud and aerosol interactions in the deep convection over the area. Deployed as a key asset, ARM's tethered balloon system (TBS) was used to investigate questions related to the vertical distributions of aerosols and their formation, including their precursor species volatile organic compounds. Platforms like TBSs and uncrewed aerial vehicles (UAVs) can bridge the vertical gap between ground-based and crewed airplane measurement platforms to focus on near-surface characterization. However, there has been limited effort to modularize and integrate VOC samplers into instrument payloads on both aerial systems. In this study, lightweight and robust VOC samplers were designed and deployed on the TBS and a UAV to collect VOCs in flight. The modular design allowed for scalable adjustments to meet the unique platform requirements and enabled multiple flights per sampling day. Each sampler can autonomously collect VOCs on up to four sorbent tubes for subsequent thermal desorption–gas chromatography–mass spectrometry analysis. The low sampler mass (2.2 kg and 800 g, TBS and UAV, respectively) enables the combination of these VOC samplers with trace gas, aerosol, and meteorological sensors on aerial platforms. These profiles allow us to assess temporal changes in VOC magnitude and composition at multiple locations. Observations from TBS and UAV flights during TRACER are presented and future considerations for sampler design and deployments are discussed.

With respect to air quality, the San Antonio metropolitan area, with a population of 1.45 million and the second largest city in Texas, has been designated as non-attainment by the United States Environmental Protection Agency in recent years. Despite the operation of multiple stationary air quality monitoring sites by the Texas Commission on Environmental Quality, the in -situ measurements of submicron aerosol and its precursors in the region is limited. To better understand the formation of secondary organic aerosol (SOA) in the San Antonio urban core, we conducted observations of a range of trace gases, volatile organic compounds, submicron aerosol, and meteorological parameters in May 2017. Data from a High-Resolution Time -of -Flight Aerosol Mass Spectrometer (HR-ToF-AMS) show that organic aerosol (OA) was the dominant component of non-refractory submicron particulate matter (average +/- 1a, 55 +/- 32 %, 5.86 +/- 3.40 mu g m-3), followed by sulfate (33 +/- 23 %, 3.52 +/- 2.47 mu g m-3). Aerosol liquid water contents predicted by ISORROPIA-II greatly increase from Continental to Oceanic airmass history scenarios, while inorganic aerosol pH remains very acidic. Positive matrix factorization (PMF) analysis of the OA mass spectra indicates that two classes of oxygenated OA (less and more-oxidized OOA, LO and MO) together constituted the bulk of OA mass during the study period (MO-OOA: 44 +/- 39 %, 2.35 +/- 2.07 mu g m- 3; LO-OOA: 42 +/- 34 %, 2.22 +/- 1.77 mu g m-3), while the fraction of hydrocarbon-like OA was limited (13 +/- 21 %, 0.71 +/- 1.11 mu g m- 3). Using in -situ meteorological data and location-specific empirical coefficients, a zero-dimensional model that utilized PMF factors as proxies to calculate the net rate of formation of types of SOA has been developed; similar calculations were used to estimate the formation rate of particulate organonitrates (pON). The results from the model reveal the importance of pON formation in LO-OOA formation overnight and the influence of temperature and photochemistry during the day. The relationships between local atmospheric factors and the net rate of formation of MO-OOA are not statistically significant. These results emphasize how HR-ToF-AMS-PMF factors could be incorporated into chemistry modeling to evaluate quantitatively the rates of formation of SOA and reveal diurnal differences in SOA formation pathways in a major urban area in southern United States.

Abstract. Highly reactive volatile organic compounds (HRVOCs) from mobile and petrochemical sources are important players in atmospheric photochemistry that contribute to the formation of ozone (O3). In a typical elevated O3 episode, we applied a high-resolution large eddy simulation (LES), coupled with the Weather Research and Forecasting model with chemistry (WRF-LES-Chem) to understand the mechanism of high O3 production over the Houston area. Our modeling was constrained and evaluated using field measurements from the NASA Tracking Aerosol Convection Interactions ExpeRiment – Air Quality (TRACER-AQ) project, Texas Commission on Environmental Quality (TCEQ), and vertical column density observations from Pandora spectrometers. The modeling results show enhanced performance in the LES domain, compared to the mesoscale models in simulating key chemicals. O3 sensitivity in the Houston urban area demonstrates a nearly homogenous early morning VOC-limited regime and transits to a noontime NOX-limited regime. As the day progresses into the afternoon, the atmospheric oxidative capacity (AOC) increases with major contribution from hydroxyl (OH) radical (90 %). High concentrations of alkenes also increased O3 (8–10 %) contribution to AOC in the late afternoon. The OH reactivity (KOH) is dominated by isoprene (35.76 %), carbon monoxide (CO; 12.98 %), formaldehyde (HCHO; 12.21 %), and alkanes with C > 3 (6.29 %), thus accelerating the production of hydroperoxyl (HO2) and peroxy (RO2) radicals. The concentrations of short-lived VOCs such as HCHO and acetaldehyde from the oxidation of HRVOCs, increased in the afternoon, which elevated O3 production rates under a NOX-limited regime. The oxidation of isoprene also accelerated the production of HCHO and contributed to the production of HO2 radicals, thus leading to a high O3 production rate. This study suggests the possible impacts of NOX-O3-VOC sensitivity on O3 production rates in polluted urban areas with high emission of HRVOCs, and also provides insights on radical chemistry that drives the photochemical processes of O3 formation. Ultimately, the study underlines the need to control anthropogenic emissions such as alkenes and HCHO and also highlights the role of naturally emitted isoprene species in elevated urban O3 levels.

As criteria pollutants from anthropogenic emissions have declined in the US in the last 2 decades, biomass burning (BB) emissions are becoming more important for urban air quality. Tracking the transported BB emissions and their impacts is challenging, especially in areas that are also burdened by anthropogenic sources like the Texas Gulf Coast. During the Corpus Christi and San Antonio (CCSA) field campaign in spring 2021, two long-range-transport BB events (BB1 and BB2) were identified. The observed patterns of an absorption Ångström exponent (AAE), a high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) BB tracer (f60), equivalent black carbon (eBC), acetonitrile and carbon monoxide (CO) during BB1 and BB2 indicated differences in the mixing of transported BB plumes with local anthropogenic sources. The combined information from HYSPLIT backward-trajectory (BT) and satellite observations revealed that BB1 had mixed influence of transported smoke plumes from fires in central Mexico, the Yucatán Peninsula and the central US, whereas BB2 was influenced by fires in the central US. The estimated transport times of smoke from the Mexican fires and the central US fires to our study site were not too different (48–54 and 24–36 h, respectively), and both events appeared to have undergone similar levels of atmospheric processing, as evident in the elemental ratios of bulk organic aerosol (OA). We observed an aging trend for f44 vs. f60 and f44 vs. f43 as a function of time during BB2 but not during BB1. Positive matrix factorization (PMF) analysis of OA showed that BB1 had a mixture of organics from aged BB emissions with an anthropogenic marine signal, while the oxidized organic compounds from aged BB emissions dominated the aerosols during BB2. The size distribution of aerosol composition revealed distinct characteristics between BB1 and BB2, where BB1 was found to be externally mixed, exhibiting a combination of BB and anthropogenic marine aerosols. On the other hand, BB2 exhibited internal mixing dominated by aged BB aerosol. Our analysis from mobile and stationary measurements highlights that both CO and acetonitrile are likely impacted by local sources even during the BB events and specifically that acetonitrile cannot be used as a unique BB tracer for dilute BB plumes in an industrially influenced location. A suitable volatile organic compound (VOC) tracer would need to be emitted in high concentrations during BB, resistant to degradation during transport, unique to BB and able to be measured in the field. This study effectively demonstrates that AAE and aerosol BB tracers served as precise and effective tracers in these complex emission scenarios. Network deployment of multiwavelength photometers holds promise for enhancing our understanding of BB impacts on air quality and supporting informed decision-making for effective mitigation strategies in locations with mixed sources and influence of dilute BB plumes. To demonstrate the relevance of such an aerosol optical network, we provide evidence of the potential regional impacts of these transported BB events on urban O3 levels using measurements from the surface air quality monitoring network in Texas.

In June 2020, a record level of Saharan dust was transported across the Atlantic Ocean impacting air quality in the Caribbean Basin and the United States (US). Satellite images showed the transport, while a series of ground based monitoring stations captured the surface impacts as the Saharan dust was transported to the Caribbean basin and then moved into the Southern (Houston, Texas; WL), Eastern (Bone, North Carolina; APP) and Midwestern (Bondville, Illinois; BND) US. The present study characterizes the Saharan dust event (SDE) using a comprehensive set of satellite observations and in-situ measurements of particulate matter (PM), and aerosol optical properties (AOPs; & sigma;scat: scattering coefficient, & sigma;abs: absorption coefficient, SAE: scattering & ANGS;ngstro & BULL;m exponent and AAE: absorption & ANGS;ngstro & BULL;m exponent). The Saharan dust intrusion was identified at each site by a marked increase in & sigma;scat, and AAE and a simultaneous decrease in SAE. A maximum hourly average PM2.5 concentration and & sigma;scat (525 nm) of 97.5 & mu;gm- 3 and 190 Mm-1 was observed at WL during the SDE. The maximum hourly average & sigma;scat (550 nm) for PM10 size cut of 215 and 66.9 Mm-1 was observed at APP and BND, respectively, during the SDE. The AAE at each site reached above 1.3 with an average value of 1.39 & PLUSMN; 0.35, 3.34 & PLUSMN; 0.56 and 1.65 & PLUSMN; 0.27 at WL, APP, and BND, respectively, during the SDE, whereas the average SAE dropped below 0.5 at WL and APP and below 0.9 at BND. The results demonstrated that the identification of SDE using AOPs depends largely on the location of the measurement, which determines the background characteristics of a site. The results suggest that other intensive AOPs like asymmetry parameter (g) and single scattering albedo & ANGS;ngstro & BULL;m exponent (SSAAE) can also be exploited to characterize SDE. Aerosol radiative forcing (ARF) estimates indicate that the SDE resulted in the heating of the atmosphere (+5.37 to +11.8 W m-2) at the rate of 0.11-0.24 K day- 1 at the US sites. This atmospheric heating from transported Saharan dust can alter the regional atmospheric dynamics and is relevant to understand potential changes in regional climate.

instrumented and is capturing solar insolation and power data that can be used for research purposes. Additional information on LISF is available here: https://www.bnl.gov/lisf/. A network of nine high-definition (HD cameras) and 32 pyranometers are deployed within the LISF for the purpose of monitoring the location and characteristics of clouds and available global horizontal irradiance at the surface across the region. Information collected by this network every 30 s is currently used in BNL’s solar NowCasting algorithm, which forecasts near-term solar energy availability accounting for the behavior of clouds. The most important parameters for forecasting the near-term solar energy availability are accurate estimations of their horizontal extend, horizontal motion, and cloud base height. Currently, images from nearly located cameras are used to estimate the cloud base height. In order to evaluate the potential of this method for estimating the cloud base height, we decided to deploy a Vaisala ceilometer at the LISF.

We measured submicron aerosols (PM1) at a beachfront site in Texas in Spring 2021 to characterize the "background" aerosol chemical composition advecting into Texas and the factors controlling this composition. Observations show that marine "background" aerosols from the Gulf of Mexico were highly processed and acidic; sulfate was the most abundant component (on average 57% of total PM1 mass), followed by organic material (26%). These chemical characteristics are similar to those observed at other marine locations globally. However, Gulf "background" aerosols were much more polluted; the average non-refractory (NR-) PM1 mass concentration was 3-70 times higher than that observed in other clean marine atmospheres. Anthropogenic shipping emissions over the Gulf of Mexico explain 78.3% of the total measured "background" sulfate in the Gulf air. We frequently observed haze pollution in the air mass from the Gulf, with significantly elevated concentrations of sulfate, organosulfates, and secondary organic aerosol associated with sulfuric acid. Analysis suggests that aqueous oxidation of shipping emissions over the Gulf of Mexico by peroxides in the particles might potentially be an important pathway for the rapid production of acidic sulfate and organosulfates during the haze episodes under acidic conditions.

San Antonio has been designated as ozone nonattainment under the current National Ambient Air Quality Standards (NAAQS). Ozone events in the city typically occur in two peaks, characterized by a pronounced spring peak followed by a late summer peak. Despite higher ozone levels, the spring peak has received less attention than the summer peak. To address this research gap, we used the Weather Research and Forecasting (WRF)-driven GEOS-Chem (WRF-GC) model to simulate San Antonio's ozone changes in the spring month of May from 2017 to 2021 and quantified the respective contributions from changes in anthropogenic emissions and meteorology. In addition to modeling, observations from the San Antonio Field Studies (SAFS), the Texas Commission on Environmental Quality (TCEQ) Continuous Ambient Monitoring Stations (CAMS), and the spaceborne TROPOspheric Monitoring Instrument (TROPOMI) are used to examine and validate changes in ozone and precursors. Results show that the simulated daytime mean surface ozone in May 2021 is 3.8 ± 0.6 ppbv lower than in May 2017, which is slightly less than the observed average differences of -5.3 ppbv at CAMS sites. The model predicted that the anthropogenic emission-induced changes contribute to a 1.4 ± 0.5 ppbv reduction in daytime ozone levels, while the meteorology-induced changes account for a 2.4 ± 0.6 ppbv reduction over 2017-2021. This suggests that meteorology plays a relatively more important role than anthropogenic emissions in explaining the spring ozone differences between the two years. We additionally identified (1) reduced NO2 and HCHO concentrations as chemical reasons, and (2) lower temperature, higher humidity, increased wind speed, and a stronger Bermuda High as meteorological reasons for lower ozone levels in 2021 compared to 2017. The quantification of the different roles of meteorology and ozone precursor concentrations helps understand the cause and variation of ozone changes in San Antonio over recent years.

Pesticides registered with the U.S. EPA for mosquito control are called adulticides and are released directly into the atmosphere as aerosols to target flying mosquitos. This adulticide application approach is different from traditional (agricultural) pesticide applications, yet the fate and transport of adulticides in large metropolitan areas is largely unknown. The Houston Metropolitan Area encompasses eight counties, many of which require county-level mosquito control programs that utilize adulticides. Malathion and permethrin are the primary adulticides used by Harris County (HC) in Houston, TX, USA. Houston, like many other metropolitan areas, has an urban atmosphere supporting the oxidation of both gas and particle phase pollutants. During the summer mosquito season of 2016, we collected atmospheric total suspended particulate matter (PM) samples at Jones Forest (JF), located in Montgomery County (directly north of HC) to investigate the atmospheric transport and oxidation of adulticides in an urban atmosphere. Despite HC alternating the adulticide treatment schedule, we measured permethrin, malathion, and malaoxon (oxidation product of malathion), throughout the sampling campaign. These consistent measurements, in conjunction with 12 h backward trajectories, support the conclusion that JF is influenced by other county-level mosquito-control programs and agricultural pesticide use. This cross-county transport may impact adulticide effectiveness by supporting pesticide resistance in mosquito populations due to repeated exposures to pesticides. This study highlights the need for mosquito control collaborations between counties, especially in areas of urban expansion overlapping with agricultural activities.

Changing urban emission landscapes and increasing population make it imperative to understand the driving forces for air quality in growing urban areas. Recent field studies in an industrial area in Houston and a semiurban area in San Antonio reveal unique emission signatures for these two growing Texas cities. A comparison of benzene, toluene, xylenes, isoprene, and methyl ethyl ketone (MEK) was conducted for these two Texas locations and previous studies in other megacities. It was found that San Antonio had similar emission ratios as these megacities for benzene, toluene, and xylenes (1.10, 4.57, and 3.60 pptv ppbv−1 of CO, respectively), likely indicating a similar traffic emission source. Isoprene and MEK were of biogenic origin in San Antonio. However, analysis of emission ratios, diurnal trends, and comparison with emission inventories indicated that benzene, toluene, and MEK were likely associated with fugitive and stack emissions in the industrial corridor in Houston. Isoprene in Houston appeared to have mixed fugitive and biogenic sources in Houston, based on diurnal trends and emission ratio. The peak nighttime concentrations for benzene, toluene, xylene, isoprene, and MEK observed during the campaign were 66, 533, 21, 138, and 731 ppbv, respectively, in the Houston site. The emission ratio for xylenes (3.37 pptv ppbv−1 of CO) for the Houston site was similar to Paris, London, and Mexico City, despite emission inventories indicating high fugitive and stack emissions. The conditional probability function (CPF) analysis closely matched the direction of the industrial sources with the highest recorded emission levels as listed in the emission inventory for the Houston site. The estimated ozone production efficiency (OPE) for the industrial area in Houston indicated volatile organic compound (VOC)–limited conditions in the morning, which transitioned to nitrogen oxide (NOx)–limited conditions in the afternoon. Texas cities have complex emission scenarios, and future efforts to mitigate ozone and particulate matter may have to consider a variety of emission reduction strategies.

The population of Texas has increased rapidly in the past decade. The San Antonio Field Study (SAFS) was designed to investigate ozone (O3) production and precursors in this rapidly changing, sprawling metropolitan area. There are still many questions regarding the sources and chemistry of volatile organic compounds (VOCs) in urban areas like San Antonio which are affected by a complex mixture of industry, traffic, biogenic sources and transported pollutants. The goal of the SAFS campaign in May 2017 was to measure inorganic trace gases, VOCs, methane (CH4), and ethane (C2H6). The SAFS field design included two sites to better assess air quality across the metro area: an urban site (Traveler's World; TW) and a downwind/suburban site (University of Texas at San Antonio; UTSA). The results indicated that acetone (2.52 ± 1.17 and 2.39 ± 1.27 ppbv), acetaldehyde (1.45 ± 1.02 and 0.93 ± 0.45 ppbv) and isoprene (0.64 ± 0.49 and 1.21 ± 0.85 ppbv; TW and UTSA, respectively) were the VOCs with the highest concentrations. Additionally, positive matrix factorization showed three dominant factors of VOC emissions: biogenic, aged urban mixed source, and acetone. Methyl vinyl ketone and methacrolein (MVK + MACR) exhibited contributions from both secondary photooxidation of isoprene and direct emissions from traffic. The C2H6:CH4 demonstrated potential influence of oil and gas activities in San Antonio. Moreover, the high O3 days during the campaign were in the NOx-limited O3 formation regime and were preceded by evening peaks in select VOCs, NOx and CO. Overall, quantification of the concentration and trends of VOCs and trace gases in a major city in Texas offers vital information for general air quality management and supports strategies for reducing O3 pollution. The SAFS campaign VOC results will also add to the growing body of literature on urban sources and concentrations of VOCs in major urban areas.

Environmental chambers are a commonly used tool for studying the production and processing of aerosols in the atmosphere. Most are located indoors and most are filled with air having prescribed concentrations of a small number of reactive gas species. Here we describe portable chambers that are used outdoors and filled with mostly ambient air. Each all-Teflon® 1 m3 Captive Aerosol Growth and Evolution (CAGE) chamber has a cylindrical shape that rotates along its horizontal axis. A gas-permeable membrane allows exchange of gas-phase species between the chamber and surrounding ambient air with an exchange time constant of approximately 0.5 h. The membrane is non-permeable to particles, and those that are injected into or nucleate in the chamber are exposed to the ambient-mirroring environment until being sampled or lost to the walls. The chamber and surrounding enclosure are made of materials that are highly transmitting across the solar ultraviolet and visible wavelength spectrum. Steps taken in the design and operation of the chambers to maximize particle lifetime resulted in averages of 6.0, 8.2, and 3.9 h for ∼ 0.06, ∼ 0.3, and ∼ 2.5 µm diameter particles, respectively. Two of the newly developed CAGE chamber systems were characterized using data acquired during a 2-month field study in 2016 in a forested area north of Houston, TX, USA. Estimations of measured and unmeasured gas-phase species and of secondary aerosol production in the chambers were made using a zero-dimensional model that treats chemical reactions in the chamber and the continuous exchange of gases with the surrounding air. Concentrations of NO, NO2, NOy, O3, and several organic compounds measured in the chamber were found to be in close agreement with those calculated from the model, with all having near 1.0 best fit slopes and high r2 values. The growth rates of particles in the chambers were quantified by tracking the narrow modes that resulted from injection of monodisperse particles and from occasional new particle formation bursts. Size distributions in the two chambers were measured intermittently 24 h d−1. A bimodal diel particle growth rate pattern was observed, with maxima of about 6 nm h−1 in the late morning and early evening and minima of less than 1 nm h−1 shortly before sunrise and sunset. A pattern change was observed for hourly averaged growth rates between late summer and early fall.

San Antonio, the second-most populous city in Texas and the seventh-most populous city in the United States (US), has been designated a marginal non-attainment area by the US Environmental Protection Agency with respect to the 2015 ozone (O3) National Ambient Air Quality Standard. While stationary air quality monitoring sites are operated in the region by the Texas Commission on Environmental Quality (TCEQ), there are limited in situ field measurements for O3 and its precursors in the urban core. To better understand O3 dynamics in San Antonio, a suite of meteorological and gas instruments was deployed during May 2017. We incorporate field measurements from two campaign sites and one TCEQ stationary monitoring site into a zero-dimensional O3 model to characterize the local formation and destruction rates of O3, hydroxyl radical (OH) reactivity of volatile organic compounds (VOCs), O3 production efficiency, and O3 formation regime in the urban core and directly downwind of San Antonio. Upwind/downwind differences indicate the importance of photochemical processing of VOCs with carbon-carbon double bonds. San Antonio was mostly in a nitrogen oxide (NOX)-sensitive regime throughout the daytime during the campaign period, with O3 formation peaking at noon in the city center and early afternoon at the downwind region. Formaldehyde (HCHO), isoprene, and alkenes dominated VOC reactivity, with alkenes and isoprene from San Antonio's core (upwind) likely contributing to the downwind formation of HCHO and enhancing its OH reactivity. However, their direct impact on downwind O3 production was not observed. Model results suggest further strengthening NOX emission controls to decrease O3 formation in San Antonio.