Increasingly it is recognised that the breakup of East Gondwana and formation of the Indian Ocean has led to the creation of many microcontinents, including Elan Bank, Gulden Draak Rise, and Batavia Rise. Whether the central and southern sections of the Kerguelen Plateau contain additional Gondwanan microcontinents remains controversial. Continental crust residing in these regions is mainly inferred from geochemical and geophysical datasets but little to no direct sampling evidence corroborates this. Here, we characterise continental rocks trawled from banks and plateaus on the Central Kerguelen Plateau, using petrographic techniques and U-Pb zircon and apatite dating. Recovered granitoids and felsic gneisses have Paleoarchean (similar to 3.3 Ga) and Mesoproterozoic (similar to 1.44 Ga, similar to 1.19 Ga) zircon U-Pb crystallisation ages, as well as Mesoproterozoic (similar to 1.6 Ga, 1.15 Ga) and Cambrian (similar to 0.5 Ga) apatite U-Pb cooling ages. We interpret a microcontinent resides in the Central Kerguelen Plateau and must underly Heard Island, based on: (1) correlation of the U-Pb age groups of the recovered granitoid/gneissic rocks with conjugate Indian crust within East Gondwana, (2) regional geochemical and geophysical evidence for widely distributed microcontinental crust in the Kerguelen Plateau and (3) strong evidence supporting a local origin for the recovered rocks versus an ice-rafted Antarctic origin. Based on a volcanic rim preserved on a gneissic sample, we interpret portions of the Central Kerguelen Plateau microcontinent were entrained as xenoliths during the recent volcanic eruptions associated with Heard Island. A ridge jump of the Southeast Indian Ridge between 115-102 Ma likely formed the Central Kerguelen Plateau microcontinent and we speculate that related ridge jumps formed a near continuous ribbon of microcontinents along the Indian margin during the breakup of East Gondwana.

Heard Island, an active sub-Antarctic intraplate volcanic island on the Kerguelen Plateau, is mostly covered by glaciers. The amphitheatre shaped summit of the active volcanic centre, Big Ben (2813 m), has been interpreted to be the product of a significant volcanic landslide. Here we present the first offshore geomorphological and geological evidence supporting a volcanic landslide on Big Ben, including: (1) the seafloor to the southwest of Heard resembling a landslide deposit, covering at least 467 km2, (2) the spatial correlation between the onshore landslide scar and the offshore deposit and (3) the consistency in lithologies and compositions of rocks sampled from the deposit with the onshore in situ lithologies. 40Ar/39Ar geochronology constrains the maximum age of the volcanic landslide to 18.0 ± 1.4 ka, post the Last Glacial Maximum. Finally, we assess the risk of volcanic landslide at Heard Island in the future.

AbstractThe McDonald Islands, together with Heard Island and the Kerguelen Archipelago, are volcanic islands on the mostly submerged Kerguelen Plateau, and the products of the long‐lived Kerguelen mantle plume (at least 130 Myr; Coffin et al., 2002, https://doi.org/10.25919/jw5f‐ad35). The first multibeam bathymetry data acquired around the Heard and McDonald islands reveal > 70 sea knolls surrounding the McDonald Islands and three sea knolls north of Heard Island. Rocks dredged from McDonald Islands sea knolls include fresh vesicular phonolitic lavas, phonolitic obsidian, phonolitic pillow fragments, and one basanite. These are the first phonolites sampled from the seafloor on the Kerguelen Plateau. Dredging of one sea knoll north of Heard Island recovered basaltic lavas. Lavas from the sea knolls are young, returning 40Ar/39Ar plateau ages of 73.7 ± 15.1 ka to 7.0 ± 2.7 ka for McDonald Islands sea knoll phonolites and 9.0 ± 1.3 ka for the Heard Island sea knoll. We define a new magma series, the McDonald Series, characterized by low εHf (−3.9 to −4.4) and lower Δ207Pb/204Pb (4.5–4.8) and Δ208Pb/204Pb (79–85) than all other lavas on the Kerguelen Plateau. This newly defined series is the product of a relatively young (Pleistocene‐Holocene) phase of volcanism produced by a distinct component of the Kerguelen mantle plume. We propose that McDonald Series phonolites together with 53.4 Ma lavas previously dredged from Ninetyeast Ridge provide evidence for zonation of the Kerguelen mantle plume.

Island-arc basalts (IAB) from convergent plate margins tend to have both higher iron oxidation states (higher Fe3+/Fe2+) and higher H2O contents than the mid-ocean ridge basalts (MORB) produced by seafloor spreading, which raises the question of whether these two characteristics are causally related. Back-arc basin basalts (BABB) may help with this question, in that they are products of seafloor spreading, like MORB, but sourced from supra-subduction mantle, like IAB. Here we examine the relationship between Fe3+/Fe2+ (determined by XANES spectroscopy) and H2O contents in BABB glasses from the North Fiji Basin (NFB). The glasses cover a range of compositions from 6.1 to 8.5 wt% MgO, and from 0.16 to 1.6 wt% H2O, and have also been analysed for trace elements and Sr-Nd-Pb-isotopes. Measured Fe3+/Fe2+ range from MORB-like to slightly higher values and are positively correlated with H2O and heavy-halogen contents (Cl, Br and I). The correlation is due to lower Fe2+ rather than higher Fe3+ compared to the MORB array. This suite of BABBs is not significantly enriched in trace elements other than H2O and the heavy halogens, with MORB-like Ba/Th and other incompatible-element ratios, suggesting that the H2O and halogens may have come from dehydration of subducted lithospheric serpentinites under subsolidus conditions. Na2O is unusually variable for a suite of samples from such a limited area, and is not correlated with H2O, precluding a relationship between H2O and degree of melting. The link between H2O and low Fe2+ may be explained by H2O-rich fluids entering the transcrustal magma plumbing system, where they increase the proportion of olivine and augite to plagioclase crystallizing during the crustal evolution of the magmas. In this situation, relatively small additions of H2O can have an enhanced effect on major-element chemistry if the crustal evolution proceeds by cycles of replenish-mix-tap-crystallize (RMTX) rather than by simple fractional crystallization without repeated replenishment and tapping. The absence of any increase in Fe3+ with H2O, together with the lack of any correlation between H2O and Fe3+/Fe2+ in MORB glasses generally, suggest that various mechanisms, including more extensive olivine fractionation, were responsible for elevating Fe3+/Fe2+ in H2O-rich basalts from convergent margin settings. Proxy methods based on concentrations of elements with redox-variable partition coefficients (V, Eu) are not sensitive enough to record the subtle variations in Fe3+/Fe2+ observable by XANES spectroscopy.

The Sanchakou intrusive complex (containing quartz diorite, porphyritic granodiorite, granodiorite, fine-grained granodiorite, diorite porphyry and hornblende gabbro) is located at the eastern part of the Dananhu-Tousuquan island arc belt, Eastern Tianshan. Zircon U-Pb ages suggest that the above six units were emplaced at 446-238 Ma. The Sanchakou intrusive complex therefore provides a unique opportunity to gain a better understanding of the Paleozoic-Mesozoic magmatism and its evolution in the Eastern Tianshan. The granitoids form a subduction related talc-alkaline to low K (tholeiitic) magmatic series, characterized by enrichment in LILE and depletion in HFSE. They have low initial Sr-87/Sr-86, high epsilon(Nd)(t) and epsilon(Hf)(t) values. As well as the above geochemical features, the quartz diorite, porphyritic granodiorite and fine-grained granodiorite have low Nb/U and Ta/U values, relatively high Mg-#, Ti/Zr and Ti/Y values, indicating a potential role of the subducted slab in their petrogenesis. The granodiorite units have low Nb/U, Ta/U and Mg-# values, and high (La/Yb)(N) values, suggesting an origin from the melting of juvenile lower crust. The Sanchakou diorite porphyry has positive epsilon(Nd)(t) and epsilon(Hf)(t), low SiO2 and (Sr-87/Sr-86),, and high MgO, Mg-#, Ti/Y and Ti/Zr values, indicating it was likely sourced from depleted mantle. The Mesozoic hornblende gabbro has low SiO2, relatively high TiO2, MgO, Al2O3 and (La/Yb)(N), and minor depletion in Nb-Ta, implying an E-MORB-like mantle source. Integrating available tectonic, stratigraphic and geochemical data, we propose that the Sanchakou quartz diorite, porphyritic granodiorite, granodiorite and fine-grained granodiorite were formed in a double-side subduction system. The younger Permian diorite porphyry was produced in a post-collisional extensional setting and the Triassic hornblende gabbro was likely formed in an intraplate environment. (C) 2021 International Association for Gondwana Research. Published by Elsevier B.V. All rights reserved.

Recent dredging of a 100 km long ridge along the northernmost part of the Louisiade Plateau (LP) recovered serpentinized peridotites, MORB (mid‐ocean‐ridge basalt) and volcaniclastic breccia–conglomerates. Clinopyroxene, Cr‐spinel and bulk rocks show that the serpentinites are harzburgites to dunites, whereas hornblende phenocrysts from volcaniclastic rocks reflect hydrous, andesitic volcanism. The association of MORB, depleted mantle rocks and fingerprints of hydrous arc magmatism is typical of supra‐subduction zone ocean lithosphere formed above a nascent subduction zone. Seismic and high‐resolution bathymetry data reveal structures consistent with an extensive east–west elongated ophiolite estimated to have obducted onto the LP between 53 and 80 Ma. This represents a major eastwards continuation of the Papuan Ultramafic Belt and forms a crucial link with ophiolites farther south in New Caledonia, providing support for major subduction initiation events in marginal basins along the northern and eastern margins of Australia and Zealandia in the Palaeocene–Eocene.

The mostly submarine Hunter Ridge, located in the SW Pacific records a ~12 Myr to present history of magmatism related to the opening of the North Fiji Basin and subduction of oceanic lithosphere of the South Fiji Basin. Although the Hunter Ridge is probably composed primarily of an older Vitiazrelated basement, young volcanic features are present from Matthew Island to Kadavu Island. Some dredged volcanic rocks from these features have low-FeO and high-Mg# affinities, ranging from picrites to high-Mg# andesites and dacites. Elevated Sr (500 - 3400 ppm) and Sr/Y (50 - 240) coupled to fractionated (adakitic) rare-earth element patterns (La/Yb = 5 - 40, Gd/Yb = 1.5 - 5.7) indicate a garnet signature derived from the melting of eclogite-facies basalt. Pacific-type MORB Nd-Hf-Pb isotopic ratios of these rocks contrast with the Indian-type MORB nature of the underlying North Fiji mantle but match closely the subducted South Fiji ocean crust. Low values of Th/La (< 0.15), Ba/La (< 22), unradiogenic Sr-87/Sr-86 (0.7026 - 0.7032) and Pacific-MORB Nd-Hf-Pb isotopic ratios indicate that sediment is a minor contributor to the source. The isotopic data clearly connect Hunter Ridge arc rocks of all compositions (picrites, low-to medium K2O arc lavas, basalts, high-Mg# andesites and dacites) to source components predominantly within the subducting plate. Unradiogenic Sr-87/Sr-86 (0.7026 - 0.7029) at high Sr abundances (700 - 1400 ppm) are common in hot-slab localities and are interpreted to reflect flux melting of MORB under eclogite-facies conditions driven by dehydration in the underlying mantle of the subducting plate. Such an adakitic slab-melt component can be detected in more common (nonadakitic) arc rocks along the Hunter Ridge and Vanuatu arc as well. Evidence of slab melting along the western Pacific indicates that melting of subducting oceanic lithosphere is likely a common occurrence at convergent margins. (C) 2022 The Author(s). Published by Elsevier B.V.

Lava samples from the Christmas Island Seamount Province (CHRISP) record an extreme range in enriched mantle (EM) type Sr-Nd-Pb-Hf isotope signatures. Here we report osmium isotope data obtained on four samples from the youngest, Pliocene petit-spot phase (Upper Volcanic Series, UVS; ~4.4 Ma), and four samples from the earlier, Eocene (Lower Volcanic Series, LVS; ~40 Ma) shield building phase of Christmas Island. Osmium concentrations are low (5–82 ppt) with initial Os isotopic values (187Os/188Osi) ranging from (0.1230–0.1679). Along with additional new geochemical data (major and trace elements, Sr-Nd-Pb isotopes, olivine δ18O values), we demonstrate the following: (1) The UVS is consistent with melting of shallow Indian mid-ocean ridge basalt (MORB) mantle enriched with both lower continental crust (LCC) and subcontinental lithospheric mantle (SCLM) components; and (2) The LVS is consistent with recycling of SCLM components related to Gondwana break-up. The SCLM component has FOZO or HIMU like characteristics. One of the LVS samples has less radiogenic Os (γOs –3.4) and provides evidence for the presence of ancient SCLM in the source. The geochemistry of the Christmas Island lava series supports the idea that continental breakup causes shallow recycling of lithospheric and lower crustal components into the ambient MORB mantle.

In order to better understand the global halogen cycle and the behaviour of halogens during subduction, we investigated the concentrations of F, Cl, Br and I in suites of rare submarine glasses formed during subduction initiation on the Hunter Ridge (N. Fiji Basin) and from the northernmost part of the Tonga Arc. Additional submarine glasses from mature arcs and backarcs including the Tonga arc (Volcano A), North Fiji, Lau, Manus and Woodlark Basins were also investigated. The aim was to constrain the relative abundances of all four halogens (F/Cl, Br/Cl and I/Cl) in subducted components in proto-arc, arc and backarc lavas for the first time. This enables an assessment of slab-fluid evolution from incipient arcs to mature backarcs, and a comparison of halogens in slab-fluids with possible subduction inputs and other mantle outputs. The various arc and backarc lavas investigated are strongly enriched in Cl, Br and I relative to Nb, and weakly enriched in F compared to Pr, demonstrating metasomatism of incipient sub-arc mantle and sub-arc/backarc mantle by slab-components with strikingly similar ranges of F/Cl (0.11 +/- 0.09), Br/Cl (0.0028 +/- 0.0008) and I/Cl (0.000013-0.001) (2 standard deviations). The F/Cl ratio, which is much higher than seawater and other surface fluids, is attributed to enhanced mobility of F in saline fluids in sub-arc environments, with slab-melts ascribed an additional minor role. The slab-fluid Br/Cl and I/Cl ratios are strikingly similar to altered oceanic crust and seafloor serpentinites, and distinctly different from sediment pore waters, sediments and most forearc serpentinites. The median Br/Cl and I/Cl ratios of slab fluids in sub-arc and sub-backarcs are also indistinguishable from median mid-ocean ridge and ocean island basalt values, which have I/Cl ratios lower than estimated for the primitive mantle. The data are interpreted to indicate that sedimentary volatile components present in sediments and forearc serpentinites are efficiently returned to the surface through forearc regions. In contrast, halogens in altered ocean crust and lithospheric serpentinites are recycled through magmatic arcs and into the deeper mantle with the result that the mantle's I/Cl ratio has decreased over time. Mass balance considerations suggest that serpentinisation of the lithospheric mantle at the slab-bend immediately prior to subduction is more significant than estimated previously and is driven by seawater-derived fluids without sedimentary components. Lithospheric serpentinites are likely to represent a dominant source of halogens and other volatiles, including noble gases, in the Earth's mantle. (C) 2019 Elsevier B.V. All rights reserved.

The Matthew and Hunter (M&H) area, in the South-West Pacific, was formerly interpreted as a transform boundary at the southern termination of the New Hebrides Subduction Zone. But new data collected during three voyages of RV Southern Surveyor (2004-2009), combined with detailed analysis of seismicity and GPS kinematics, shows it is a distinct subduction zone initiated only 2 Ma ago. In fact, M&H is the youngest known volcanically-active intra-oceanic subduction system. We demonstrate that the M&H subduction zone is a modern example of an immature subduction system at the particular stage of pre-arc, near-trench magmatism. It is not yet forming an arc but the proto-forearc. Indeed volcanism occurs much closer to the trench than volcanism at mature subduction zones. Also M&H hosts an exceptionally diverse range of magma compositions, which erupted contemporaneously and are spatially juxtaposed. Pb isotopic compositions and contents of LILE and REE indicate melting of upwelling asthenospheric mantle (Indian MORB) and subducted oceanic crust (Pacific MORB of the South Fiji Basin) and the mixing of these two components. It is worth noting that the present day proto-forearc of the M&H subduction zone corresponds to an area where highly contrasting terranes are juxtaposed: remnants of the old Vitiaz Arc crust, domains of classical backarc basin type oceanic accretion, and what we call Subduction Initiation Terranes (SITER). Such live observations of a growing forearc are rare. They should give insights into the study of fossil forearcs such as SSZ ophiolites but also the IBM forearc.

Abstract The final lithospheric breakup of the Australian‐Antarctic rift system remains controversial due to sparse geological constraints on the nature of the basement along the ocean‐continent transition (OCT) zones. We present new interpretations of multichannel seismic reflection transects and new petrological data of dredged mantle rocks along the East Antarctic margin (Seamount B, offshore Terre Adélie). By combining both data sets, we show that a 50–100 km wide domain of cold and fertile subcontinental mantle was exhumed along the magma‐poor Antarctic margin. This study represents only the second locality, along with the Iberia‐Newfoundland margins, where the importance of exhumed mantle domains along OCTs can be clearly identified. The dredged peridotites preserve characteristics similar to mantle xenoliths found in syn‐ to post‐rift volcanism at the eastern end of the Australian margin (Victoria and Tasmania), indicating the exhumation of fertile subcontinental mantle during rifting between Australia and Antarctica. Seamount B represents the initial stages of exhumation of cold subcontinental lithosphere along an OCT during rifting. This thick mantle domain was likely affected by melt impregnation at high pressure (8 kbar), leading to the formation of plagioclase‐pyroxenites. The combination of continental rifted blocks, a wide domain of volcanic‐poor subcontinental mantle and (ultra‐) slow spreading is analogous to OCTs from the Jurassic Western Tethys and Iberia‐Newfoundland rifted margins. Additionally, evidence of melt stagnation at high pressure suggests that magmatism along the Australian‐Antarctic rifted margins was sufficient to form magnetic anomalies that can be used as isochrons despite their formation in lithosphere other than mature, steady‐state ocean crust.

The linkage between intracontinental extension and the Early Cretaceous Cu-Mo-W polymetallic metallogenesis in the Middle-Lower Yangtze River Belt (MLYRB) has long been a subject of controversy due to the lack of convincing petrogenetic evidence to identify the nature of magmatic sources and their geological histories during extensional mantle upwelling. Here we present new zircon UPb ages, isotopic and geochemical data for granodiorites, quartz diorites and mafic microgranular enclaves (MMEs) in the Tongshankou area. Comparing the MMEs with their host porphyries, the different ratios of incompatible elements and the similar formation ages, coupled with quenched margins and the xenocrysts in the MMEs, indicate that the MMEs was most likely formed by mixing between mafic magma and their host felsic magma. The MMEs share similar geochemical and isotopic characteristics with the Cretaceous mafic rocks from MLYRB, indicating that MMEs were mostly derived from an enriched lithospheric mantle source without adakitic characteristics. Mixing of a crustal melt derived by melting of an amphibolite bearing juvenile lower crust with a mantle melt derived from melting of enriched lithospheric mantle can account for the generation of the Tongshankou prophyries. The melting of juvenile mafic lower crust and enriched lithospheric mantle is suggested to be caused by upwelling of asthenospheric mantle and the reactivity of trans-lithospheric faults in the intracontinental extensional environment. Our results therefore highlight that juvenile mafic lower crust beneath the Yangtze plate is one of the likely source for ore-forming magmatic rocks in the Early Cretaceous.

The development of ideas leading to a greater understanding of subduction initiation is limited by the scarcity of present-day examples. Furthermore, the few examples identified so far unfortunately provide few insights into the nature of magmatism at the inception of subduction. Here we report new observations from the Matthew and Hunter (M&H) subduction zone, a very young subduction zone located in the South-West Pacific. Tectonics of the area show it is younger than 2 Ma, making the M&H the youngest known volcanically-active subduction system and hence providing unique insights into the earliest stages of subduction initiation. Volcanism in this area comprises an exceptionally diverse range of contemporaneously erupting magma compositions which are spatially juxtaposed. Pb isotopic compositions and abundance of LILE and REE strongly suggest melting of upwelling asthenospheric mantle (Indian MORB) and subducted oceanic crust (Pacific MORB of the South Fiji Basin) and the mixing of these two components. Volcanism occurs much closer to the trench compared to volcanism in more mature subduction zones. We demonstrate that the M&H subduction zone is a modern example of an immature subduction system at the stage of pre-arc, near-trench magmatism. It is not yet building an arc but what we propose to call a Subduction Initiation Terrane (SITER). Today, the proto-forearc of the M&H subduction zone is a collage of these SITERs, coeval back-arc domains and remnants of pre-existing terranes including old Vitiaz Arc crust. The M&H area represents a modern analog of a Supra Subduction Zone setting where potentially a majority of ophiolites have formed their crustal and lithospheric components. Present-day magmatism in the M&H area therefore provides clues to understanding unforeseen distribution of contrasted magmatic rock types in fossil forearcs, whether they are at the front of mature subduction zones or in ophiolites. (C) 2018 Elsevier B.V. All rights reserved.

Successive magma batches underplate, ascend, stall and erupt along spreading ridges, building the oceanic crust. It is therefore important to understand the processes and conditions under which magma differentiates at mid ocean ridges. Although fractional crystallization is considered to be the dominant mechanism for magma differentiation, open-system igneous complexes also experience Melting-Assimilation-Storage-Hybridization (MASH, Hildreth and Moorbath, 1988) processes. Here, we examine crystal-scale records of partial melting in lower crustal gabbroic cumulates from the slow-spreading Atlantic oceanic ridge (Kane Megamullion; collected with Jason ROV) and the fast-spreading East Pacific Rise (Hess Deep; IODP expedition 345). Clinopyroxene oikocrysts in these gabbros preserve marked intra-crystal geochemical variations that point to crystallization-dissolution episodes in the gabbro eutectic assemblage. Kane Megamullion and Hess Deep clinopyroxene core1 primocrysts and their plagioclase inclusions indicate crystallization from high temperature basalt (>1,160 and >1,200°C, respectively), close to clinopyroxene saturation temperature (<50% and <25% crystallization). Step-like compatible Cr (and co-varying Al) and incompatible Ti, Zr, Y and rare earth elements (REE) decrease from anhedral core1 to overgrown core2, while Mg# and Sr/Sr* ratios increase. We show that partial resorption textures and geochemical zoning result from partial melting of REE-poor lower oceanic crust gabbroic cumulate (protolith) following intrusion by hot primitive mantle-derived melt, and subsequent overgrowth crystallization (refertilization) from a hybrid melt. In addition, toward the outer rims of crystals, Ti, Zr, Y and the REE strongly increase and Al, Cr, Mg#, Eu/Eu*, and Sr/Sr* decrease, suggesting crystallization either from late-stage percolating relatively differentiated melt or from in situ trapped melt. Intrusion of primitive hot reactive melt and percolation of interstitial differentiated melt are two distinct MASH processes in the lower oceanic crust. They are potentially fundamental mechanisms for generating the wide compositional variation observed in mid-ocean ridge basalts. We furthermore propose that such processes operate at both slow- and fast-spreading ocean ridges. Thermal numerical modeling shows that the degree of lower crustal partial melting at slow-spreading ridges can locally increase up to 50%, but the overall crustal melt volume is low (less than ca. 5% of total mantle-derived and crustal melts; ca. 20% in fast-spreading ridges)

Combining geophysical, petrological and structural data on oceanic mantle lithosphere, underlying asthenosphere and oceanic basalts, an alternative oceanic plate spreading model is proposed in the framework of the westward migration of oceanic spreading ridges relative to the underlying asthenosphere. This model suggests that evolution of both the composition and internal structure of oceanic plates and underlying upper mantle strongly depends at all scales on plate kinematics. We show that the asymmetric features of lithospheric plates and underlying upper asthenosphere on both sides of oceanic spreading ridges, as shown by geophysical data (seismic velocities, density, thickness, and plate geometry), reflect somewhat different mantle compositions, themselves related to various mantle differentiation processes (incipient to high partial melting degree, percolation/reaction and refertilization) at different depths (down to 300km) below and laterally to the ridge axis. The fundamental difference between western and eastern plates is linked to the westward ridge migration inducing continuing mantle refertilization of the western plate by percolation-reaction with ascending melts, whereas the eastern plate preserves a barely refertilized harzburgitic residue. Plate thickness on both sides of the ridge is controlled both by cooling of the asthenospheric residue and by the instability of pargasitic amphibole producing a sharp depression in the mantle solidus as it changes from vapour-undersaturated to vapour-saturated conditions, its intersection with the geotherm at ~90km, and incipient melt production right underneath the lithosphere-asthenosphere boundary (LAB). Thus the intersection of the geotherm with the vapour-saturated lherzolite solidus explains the existence of a low-velocity zone (LVZ). As oceanic lithosphere is moving westward relative to asthenospheric mantle, this partially molten upper asthenosphere facilitates the decoupling between lower asthenosphere and lithosphere. Thereby the westward drift of the lithosphere is necessarily slowed down, top to down, inducing a progressive decoupling within the mantle lithosphere itself. This intra-mantle decoupling could be at the origin of asymmetric detachment faults allowing mantle exhumation along slow-spreading ridges. Taking into account the asymmetric features of the LVZ, migration of incipient melt fractions and upwelling paths from the lower asthenosphere through the upper asthenosphere are oblique, upward and eastward. MORB are sourced from an eastward and oblique, near-adiabatic mantle upwelling from the lower asthenosphere. This unidirectional mantle transfer is induced by isostatic suction of the migrating spreading ridge.

The elevated oxygen fugacity recorded by subduction-related lavas and peridotites, relative to their mid-ocean ridge counterparts, fundamentally influences the petrogenesis of arc magmas. However, the timing, process, and spatial extent of oxidizing mass transfer at subduction zones remain unknown. Forearc peridotites, which are sometimes exposed on the trench wall of the overriding plate, record chemical fingerprints of the melting and melt-rock interaction processes that occur during and following subduction initiation, and thus provide insight into the spatial and temporal evolution of this oxidized signature. In this study, we present new major element, trace element, and oxygen fugacity data for a suite of forearc peridotites recovered from the Tonga Trench, in addition to a new assessment of literature data for previously studied forearc peridotites. For Tonga samples and literature data for forearc, ridge, and subduction-zone peridotites, we calculate oxygen fugacity (f(O2)) using an updated method. In contrast to previous studies, we find that spinel Cr#, a proxy for extent of melt extraction, does not correlate with oxygen fugacity, such that many forearc peridotites with high spinel Cr# do not record oxygen fugacity higher than the mid-ocean ridge peridotite array. Combining these observations with trace element modeling, we conclude that forearc peridotites are less pervasively influenced by oxidation owing to subduction processes than previously reported. The oxygen fugacity recorded by Tonga forearc peridotites is heterogeneous between dredges and homogeneous within dredges. To explore these variations, we grouped the dredges into two categories. Group I peridotites have high spinel Cr#, extremely depleted trace element compositions and oxygen fugacity values consistent with the mid-ocean ridge peridotite array. We interpret these to be the residues of large degrees of fractional melting, with little influence from arc-like melts or fluids, formed during the first stages of subduction initiation. Group II peridotites have lower spinel Cr#, enriched light rare earth elements, and oxygen fugacity elevated by >= 1 log unit above the mid-ocean peridotite array. We interpret these peridotites to be the residues of flux melting, initiated once corner flow is established in the young subduction zone. We conclude that the forearc mantle is not pervasively oxidized relative to mid-ocean ridge mantle, and that the asthenospheric mantle in the proto-subduction zone region is not oxidized prior to subduction initiation. As the oxidized signature in Group II peridotites accompanies geochemical evidence of interaction with subduction-related fluids and melts, this suggests that the sub-arc mantle is oxidized concurrently with addition of subduction fluids to the mantle wedge.

We report new age determinations and compositions for rocks from 18 dredge hauls collected from eight submarine areas across Central Kerguelen Plateau (CKP). Sea knolls and volcanic fields with multiple small cones were targeted over a ∼125 000 km2 region that includes Heard and McDonald Islands. Large early Miocene (22–16 Ma) sea knolls rise from the western margin of the CKP and are part of a NNW–SSE line of volcanic centres that lie between Îles Kerguelen and Heard and McDonald Islands. These are probably related to hotspot activity now underlying the Heard Island area. We see evidence of much younger activity (5 Ma to present) in volcanic fields to the north of, and up to 300 km NE of, Heard Island. Compositions include basanite, basalt and trachybasalt, which are broadly similar to plateau lava flows from nearby Ocean Drilling Program Site 1138, lower Miocene lavas at Îles Kerguelen, dredged rocks from the early Miocene sea knolls, and Big Ben lavas from Heard Island. Geochemical data indicate decreasing fractions of mantle source melting with time. We propose that a broad region of the CKP became volcanically active in Neogene time owing to incubation of plume material at the base of the relatively stationary overlying plateau. The presence of pre-existing crustal faults gave access for melts from the Heard mantle plume to rise to the surface.