Our work is aimed at enhancing the external quantum efficiency (EQE) of n-i-p photodiodes by reducing the absorption losses in the p-layer and the recombination losses in the p-i interface. We have applied boron-doped and undoped hydrogenated amorphous silicon carbon alloy (a-SiC:H) grown in hydrogen-diluted, silane-methane plasma to both the p-layer and undoped buffer layer, thus tailoring the p-i interface. The current-voltage, capacitance-voltage, and spectral-response characteristics of fabricated photodiodes are correlated with the doping level, optical band gap, and deposition conditions for a-SiC: H layers. The optimized device exhibits a leakage current of about 110 pA/cm(2) at the reverse bias of 5 V, and a peak value of 89% EQE at a wavelength of 530 nm. At shorter wavelengths, the EQE decreases down to 56% at a 400 nm wavelength. Calculations of transmission/reflection losses at the front of the photodiode show that observed short-wavelength sensitivity enhancement can be attributed to improved separation of electron-hole pairs in the p-layer depletion region.
We report on structural, electronic, and optical properties of boron-doped, hydrogenated nanocrystalline silicon (nc-Si:H) thin films deposited by plasma-enhanced chemical vapor deposition (PECVD) at a substrate temperature of 150°C. Film properties were studied as a function of trimethylboron-to-silane ratio and film thickness. The film thickness was varied in the range from 14 to 100 nm. The conductivity of 60 nm thick films reached a peak value of 0.07 S/cm at a doping ratio of 1%. As a result of amorphization of the film structure, which was indicated by Raman spectra measurements, any further increase in doping reduced conductivity. We also observed an abrupt increase in conductivity with increasing film thickness ascribed to a percolation cluster composed of silicon nanocrystallites. The absorption loss of 25% at a wavelength of 400 nm was measured for the films with optimized conductivity deposited on glass and glass/ZnO:Al substrates. A low-leakage, blue-enhanced p-i-n photodiode with an nc-Si p-layer was also fabricated and characterized.
This paper reports on a-Si:H n–i–p photodiodes on PEN substrates with performance characteristics suitable for imaging applications. Segmented n–i–p photodiodes were fabricated using a process sequence and design rules that are compatible with industrial technology. Low-temperature (150°C) plasma-enhanced chemical vapor deposition (PECVD) was employed for the a-Si:H and passivation dielectric layers. Device measurements included current–voltage characteristics, dark current decay, and spectral response. To identify the sources of the reverse dark current, the measurements were performed on variable area test structures with device sizes ranging from 126μm to 2mm. The n–i–p photodiodes on PEN substrates demonstrate quantum efficiencies as high as 83% and reverse current density lower than 500pA/cm2 at −3V, as measured on 126μm photodiodes. Thus, the performance characteristics of the n–i–p diodes on PEN substrates meet the requirements for bio-medical X-ray imaging. We also discuss the mechanisms underlying the reverse dark current and the effect of the substrate on device characteristics.
In this paper, we report on low noise, high fill factor amorphous silicon (a-Si:H) image sensor structures for indirect radiography. Two types of the sensor arrays comprising n-i-p photodiodes and m-i-s photosensors have been fabricated. The device prototypes contain 100 × 100 pixels, with a pixel pitch of 139 μm. The active-matrix addressing is provided by low off-current TFTs. The sensors are vertically integrated onto the TFT-backplane, by implementing a 3-μm-thick low-k interlayer dielectric. This dielectric layer serves to reduce the data line capacitance and to planarize underlying topography. The detector was designed for reduced data-line resistance and parasitic coupling. Details of the device design and fabrication, along with sensor performance characteristics, are presented and discussed.
This paper reports the first successful attempt to fabricate amorphous silicon (a-Si:H) n-i-p photodiodes on a thin stainless-steel foil substrate for medical X-ray imaging applications. Two architectures of the n-i-p-photosensor, where the top electrode is based on amorphous or polycrystalline ITO, have been developed and characterized. The impact of critical fabrication steps including the deposition of semiconductor layers, dry etch of the NIP stack, diode passivation and encapsulation, as well as a contact formation on the device performance is presented and discussed. The test structures comprising segmented photodiodes with a junction area ranged from 0.126 × 0.126 to 1 × 1 mm 2 have been fabricated on stainless-steel foils and on glass substrates for the purposes of process characterization. The fabricated samples are evaluated in terms of current-voltage, capacitance-voltage, and spectral response characteristics.
Because of the inherent desired material and technological attributes such as low temperature deposition and high uniformity over large area, the amorphous silicon (a-Si:H) technology has been extended to digital X-ray diagnostic imaging applications. This paper reports on design, fabrication, and characterization of a MIS-type photosensor that is fully process-compatible with the active matrix a-Si:H TFT backplane. We discuss the device operating principles, along with measurement results of the transient dark current, linearity and spectral response.