Effects of carbon dioxide (CO2) addition and pulsed gliding arc (PGA) plasma on methane (CH4) flame stability and pollutant emissions are investigated in this paper. Two main parts are reported: the effects of CO2 addition to the fuel and the impact of PGA plasma on the characteristics of non-premixed CH4/CO2-air flames in a coaxial swirl burner. The burner consists of 2 concentric tubes, the central tube supplies the CH4 flow and the periphery one supplies the airflow. In the central tube, a metal rod is used as a cathode. To produce the PGA plasma, two other electrodes are symmetrically placed around the central one to obtain two PGA plasma zones in the sta-bilization area of flame. The combustor is a parallelepiped chamber, with a 0.48 m square cross section and 1 m height equipped with six windows on each side. This work primarily focuses on pollutant emissions (NOx and CO), flame structures, and stability. OH* chemiluminescence measurements are used to describe the structure and stability of the flame providing information on the flame lengths and lift-off heights. The lift-off heights and the flame lengths are determined as a function of the CO2 concentrations, ranging from 0% to 50% in the fuel, at a fixed swirl number and equivalence ratio. The results show that CO2 addition to the fuel changes significantly the flame shape and its behavior. The flame becomes more unstable at high CO2 percentages. CO2 addition dilutes reactants, reduces NOx production, and increases CO concentrations in the flue gases. To overcome the instabilities problems due to the addition of CO2, the PGA is used and investigated with different parameters of plasma and flame. PGA plasma is generated by a DC pulsed power generator with HV pulse duration of few microseconds. It is observed that the presence of PGA plasma decreases flame instabilities and reduces CO concentration in the flue gases.

A micro-hollow cathode discharge (MHCD) operated in Ar/N 2 gas mixture, working in the normal regime, was studied both experimentally and with a 0D (volume-averaged) model in this work. This source provides high electron densities (up to 10 15 cm −3 ) at low injected power (1 W). To understand the mechanisms leading to the production of N atoms, the densities of electrons, N atoms and argon metastable atoms (Ar*) were monitored over a wide range of experimental conditions. Electrons, N atoms and Ar* densities were probed by means of optical emission spectroscopy, vacuum ultra violet Fourier transform spectroscopy and tunable diode laser absorption spectroscopy, respectively. Measurements showed that using a smaller hole diameter enables to work with less injected power, while increasing the power density inside the hole and, subsequently, increasing the densities of excited species. Varying the percentage of N 2 in the gas mixture highlighted that, up to 80%, the density of N atoms increases although the dissociation rate drops. Looking at the processes involved in the production of N atoms with the help of the 0D model, we found that at very low N 2 fraction, N atoms are mostly produced through dissociative electron-ion recombination. However, adding more N 2 decreases drastically the electron density. The density of N atoms does not drop thanks to the contribution of Ar* atoms, which are the main species dissociating N 2 between 5% and 55% of N 2 in the gas mixture. A reasonable agreement is found between the experiments and the model results. This study shows that, with this MHCD, it is possible to significantly modify the production of N atoms when modifying the physical parameters, making it particularly relevant for applications requiring a N atoms source, such as nitride deposition.

This paper is devoted to the study of the argon flow modification in a cold atmospheric pressure plasma jet driven by nanosecond high voltage (HV) pulses, from single to multiple HV shots applications. A schlieren optical bench has been designed in order to visualize the argon flow downstream expansion in quiescent air, for moderate flow rates below 1 standard liter per minute. A coupled approach is used between charge coupled device (CCD) schlieren imaging and intensified CCD (ICCD) plasma plume imaging, both time-resolved. It is shown that the application of only one HV pulse (i.e. single HV shot) is enough to disturb the flow. The disturbed flow exhibits ripple propagation, on a timescale similar to the flow velocity. When operating in double HV shots, the second ionization wave can be used as a probe, to instantly visualize the flow structure any time after the first HV pulse application. For some flow rates, the ripple can increase in amplitude up to the point when it strongly deforms, or even stops, the plasma plume expansion, after which it is entrained by the flow and the plasma plume retrieves its full usual expansion. When a series of HV pulses are applied, the maximal disturbance of the flow is achieved for a certain pulse repetition frequency (PRF), specific of each flow rate. It is associated with ripples alternation in the plasma plume, in a 3D helical-like arrangement. For greater PRF, the ripples progressively vanish, and the flow is clearly less disturbed. Once the ripples have vanished, increasing further the PRF does not change the plasma plume and flow structures. We suggest that the repetitive plasma ignition mechanically forces the flow inside the capillary with consequences on the global flow structure, similarly to a forced backward-facing step flow with actuator.

The uniform propagation of positive-polarity surface plasmas in air at atmospheric pressure has been achieved using a multi-layer structure, consisting of a silicon wafer covered by a 1 mu m thick dielectric SiO2 layer as a propagation surface. Instead of the branched streamers observed in the same conditions when using conventional bulk dielectric surfaces, the plasma exhibits a homogenous ring-shaped structure with a high degree of reproducibility and stability. The plasma is generated by applying nanosecond positive voltage pulses to a tungsten wire touching the dielectric surface. The plasma has been imaged in single shot operation at high spatial resolution with an ultraviolet reflective microscope coupled with a fast intensified charge-coupled device camera. Time- and space-resolved optical emission spectroscopy shows that the homogenous ring corresponds to the propagation of an ionization front with a region of high N-2(+*) emission. We discuss the origin of the ring-shaped ionization wave, considering the role of the Si-SiO2 interface and the effect of illumination by an external light source. The ring ionization wave may result from branching inhibition, due to a photoelectric effect at the interface created by the photons emitted by the plasma. The generation of stable uniform surface ionization waves, in ambient air at atmospheric pressure, could be of interest for further advanced plasma-surface interaction studies or flow control applications.

The last decade has seen an impressive increase of the research dedicated to the biological applications of low temperature atmospheric pressure plasmas. Medical appli-cations are tacking an increasing place underlined by many clinical trials. They now concern numerous domains, including blood coagulation, dental care, skin decontamination and hygiene, wound and ulcer treatment, dermatology, cancer treatment. Biological applications are also now extended to agriculture and, more recently, to cosmetic. Despite the huge number of in vitro and in vivo experiments, there are still numerous challenges to overcome linked to the nature of the encountered target (biological tissues and materials, organs and their direct environment, liquids) that have a direct effect on the produced itself and on the generated species. That must therefore be taken into account in the applied treatments and complicates the definition of a plasma dose expected by many.

He(23S) helium metastable is a key state in the energetic transfers occurring in atmospheric pressure plasma jets that are widely used for applications related to biology or material processing. Its measurement mainly relies on laser absorption, and this is not always easy to perform. In this work, we show a simple way to follow the time evolution of this state that relies on late time evolution of the transitions emitted from the N2 +(B) state, which is mainly populated by Penning ionization from He(23S). Indeed, we show that the late time decay of N2 +(B) is found to be the same as that of He(23S) concentration. Using previous work cited in the literature, we conclude that this type of monitoring can be used for argon metastable, with N2(C) being the tracer in that case.

The use of cold atmospheric pressure plasma jets for in vivo treatments implies most of the time plasma interaction with conductive targets. The effect of conductive target contact on the discharge behavior is studied here for a grounded metallic target and compared to the free jet configuration. In this work, realized with a plasma gun, we measured helium metastable HeM (23S1) concentration (by laser absorption spectroscopy) and electric field (EF) longitudinal and radial components (by electro-optic probe). Both diagnostics were temporally and spatially resolved. Mechanisms after ionization front impact on the target surface have been identified. The remnant conductive ionized channel behind the ionization front electrically transiently connects the inner high voltage electrode to the target. Due to impedance mismatching between the ionized channel and the target, a secondary ionization front is initiated and rapidly propagates from the target surface to the inner electrode through this ionized channel. This leads to a greatly enhanced HeM production inside the plasma plume and the capillary. Forward and reverse dynamics occur with further multi reflections of more or less damped ionization fronts between the inner electrode and the target as long as the ionized channel is persisting. This phenomenon is very sensitive to parameters such as target distance and ionized channel conductivity affecting electrical coupling between these two and evidenced using positive or negative voltage polarity and nitrogen admixture. In typical operating conditions for the plasma gun used in this work, it has been found that after the secondary ionization front propagation, when the ionized channel is conductive enough, a glow like discharge occurs with strong conduction current. HeM production and all species excitation, especially reactive ones, are then driven by high voltage pulse evolution. The control of forward and reverse dynamics, impacting on the production of the glow like discharge, will be useful for biomedical applications on living tissues.

In this work, helium flow modifications, visualized by schlieren imaging, induced by the plasma generated in a plasma jet have been studied in conditions used for biomedical treatments (jet being directed downwards with a low helium flow rate). It has been shown that the plasma action can shift up to few centimeters downstream the effects of buoyancy, which allows to the helium flow to reach a target below in conditions for which it is not the case when the plasma is off. This study reveals the critical role of large and long lifetime negative ions during repetitive operations in the kHz regime, inducing strong modifications in the gas propagation. The cumulative added streamwise momentum transferred to ambient air surrounding molecules resulting from a series of applied voltage pulses induces a gradual built up of a helium channel on tens of millisecond timescale. In some conditions, a remarkable stable cylindrical helium channel can be generated to the target with plasma supplied by negative polarity voltage pulses whereas a disturbed flow results from positive polarity operation. This has a direct effect on air penetration in the helium channel and then on the reactive species production over the target which is of great importance for biomedical applications. It has also been shown that with an appropriate combination of negative and positive polarity pulses, it is possible to benefit from both polarity features in order to optimize the plasma plume propagation and plasma delivery to a target.

Recently, Iseni (arXiv:1709.03109v1) reported measurements and analysis of electric field (EF) strengths adjacent to propagating ionization waves (IWs) in non-thermal atmospheric pressure He plasma jets. We demonstrate that these measurements are in error due to an improperly aligned electric field probe.

HAL is a multi-disciplinary open access archive for the deposit and dissemination of scientific research documents, whether they are published or not. The documents may come from teaching and research institutions in France or abroad, or from public or private research centers. L’archive ouverte pluridisciplinaire HAL, est destinée au dépôt et à la diffusion de documents scientifiques de niveau recherche, publiés ou non, émanant des établissements d’enseignement et de recherche français ou étrangers, des laboratoires publics ou privés. Gas flow modification by an atmospheric plasma jet Xavier Damany, Thibault Darny, Claire Douat, Sebastien Dozias, Jean Michel Pouvesle, Robert Eric

Atmospheric pressure plasma jets have demonstrated their ability in biomedical applications thanks to their low gas temperature and their capacity to produce radicals, ions, electrons, UV radiation and electric fields. However the understanding of the interactions between the plasma and living cells and tissues is still far from being completely understood. Recently, Robert et al characterized two components of the electric field from a plasma jet and showed that the latter can propagate deeply in tissues on several mm [1]. In this work, we focus on the study of the electric field induced by the plasma and its influence on the cell membrane. Propidium iodide, dextran sulfate and plasmid DNA are used to measure the permeability of the membrane, while an electro-optic probe is used to measure the longitudinal and the radial components of the electric field. The two components are both spatially and temporally resolved. To investigate the contribution of the electric field on the cell membrane, a dielectric barrier is used between the plasma and the biological target. A comparison with and without the barrier will be presented for both biological and agriculture applications. [1] E. Robert et al, 2015, Phys. Plasmas 22 122007