We investigate the formation and transport of gas bubbles across a model porous electrode/catalyst using lattice Boltzmann simulations. This approach enables us to systematically examine the influence of a wide range of morphologies, flow velocities, and reaction rates on the efficiency of gas production. By exploring these parameters, we identify critical parameter combinations that significantly contribute to an enhanced yield of gas output. Our simulations reveal the existence of an optimal pore geometry for which the product output is maximized. Intriguingly, we also observe that lower flow velocities improve gas production by leveraging coalescence-induced bubble detachment from the electrode/catalyst.
Liquid lens coalescence is an important mechanism involved in many industrial and scientific applications. It has been investigated both theoretically and experimentally, yet it is numerically very challenging to obtain consistent results over the wide ranges of surface tension and viscosity values that are necessary to capture the asymptotic temporal behavior in the viscous and inertial limits. We report results of massively parallel simulations based on the color gradient lattice Boltzmann method, which overcome these limitations, and investigate the scaling laws of both regimes. For the two-dimensional case we find good agreement with the similarity solution of the thin-sheet equation, where in the viscous regime the connecting bridge grows linearly with time and in the inertial regime proportionally to t2/3. In three dimensions, the viscous growth of the bridge also exhibits a linear time dependence, while in the inertial regime the growth of both the bridge height and the bridge width is proportional to t1/2.
Hydrodynamic interactions are crucial for determining the cooperative behavior of microswimmers at low Reynolds numbers. Here we provide a comprehensive analysis of the scaling laws and the strength of the interactions in the case of a pair of three-sphere swimmers. Both stroke-based and force-based elastic microswimmers are analyzed using an analytic perturbative approach, focusing on passive and active interactions. The former are governed by the cycle-averaged flow field of a single swimmer, which is dipolar at long range. However, at intermediate distances, with a cross-over at the order of 102 swimmer lengths, the quadrupolar field dominates which, notably, yields an increase of the swimming velocity compared to individual swimmers, even when the swimmers are one behind another. Furthermore, we find that active rotations resulting from the interplay of the time-resolved swimming stroke and the ambient flow fields and, even more prominently, active translations are model-dependent. A mapping between the stroke-based and force-based swimmers is only possible for the low driving frequency regime where the characteristic time scale is smaller than the viscous one. Finally, we find that the long-term behavior of the swimmers, while sensitive to the initial relative positioning, does not depend on the pusher or puller nature of the swimmer. These results clearly indicate that the behavior of swarms will depend on the swimmer model, which was hitherto not well appreciated.
Hydrodynamic interactions are crucial for determining the cooperative behavior of microswimmers at low Reynolds numbers. Here we provide a comprehensive analysis of the scaling and strength of the interactions in the case of a pair of three-sphere swimmers with intrinsic elasticity. Both stroke-based and force-based microswimmers are analyzed using an analytic perturbative approach. Following a detailed analysis of the passive interactions, as well as active translations and rotations, we find that the mapping between the stroke-based and force-based swimmers is only possible in a low driving frequency regime where the characteristic time scale is smaller than the viscous one. Furthermore, we find that for swimmers separated by up to hundreds of swimmer lengths, swimming in pairs speeds up the self propulsion, due to the dominant quadrupolar hydrodynamic interactions. Finally, we find that the long term behavior of the swimmers, while sensitive to initial relative positioning, does not depend on the pusher or puller nature of the swimmer.