AbstractU 1704 Alle dargestellten Steroide werden jeweils über mehrere Stufen erhalten.
High resolution i.r. spectrometry gives useful information about the structures of steroidal microbiological hydroxylation products. The polyketones formed by mild oxidation of the hydroxylation products are examined in the CO stretching and –CO–CH2– scissoring regions. Interpretation of the spectra by the characteristic group frequency approach is valid provided that the occurrence of interactions between carbonyl groups is recognised in predicting band positions and intensities. The hydroxylation products are most usefully studied, as dilute solutions, in the O–H stretching region. With compounds in which strong intramolecular hydrogen bonding occurs, the structures are almost uniquely defined by the characteristics of the O–H absorptions.
Chemischer Informationsdienst. Organische ChemieVolume 2, Issue 27 Organoelement Compounds ChemInform Abstract: MIKROBIOLOGISCHE HYDROXYLIERUNG VON STEROIDEN 2. MITT. STRUKTURAUFKLAERUNG UND INFRAROT-SPEKTROSKOPIE, CARBONYL-, GESTOERTE METHYLEN- UND HYDROXY-SCHWINGUNGEN VON STEROIDKETONEN UND -ALKOHOLEN A. D. BOUL, A. D. BOULSearch for more papers by this authorJ. W. BLUNT, J. W. BLUNTSearch for more papers by this authorJ. W. BROWNE, J. W. BROWNESearch for more papers by this authorV. KUMAR, V. KUMARSearch for more papers by this authorG. D. MEAKINS, G. D. MEAKINSSearch for more papers by this authorJ. T. PINHEY, J. T. PINHEYSearch for more papers by this authorV. E. M. THOMAS, V. E. M. THOMASSearch for more papers by this author A. D. BOUL, A. D. BOULSearch for more papers by this authorJ. W. BLUNT, J. W. BLUNTSearch for more papers by this authorJ. W. BROWNE, J. W. BROWNESearch for more papers by this authorV. KUMAR, V. KUMARSearch for more papers by this authorG. D. MEAKINS, G. D. MEAKINSSearch for more papers by this authorJ. T. PINHEY, J. T. PINHEYSearch for more papers by this authorV. E. M. THOMAS, V. E. M. THOMASSearch for more papers by this author First published: July 6, 1971 https://doi.org/10.1002/chin.197127142Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat No abstract is available for this article. References A. D. BOUL, J. W. BLUNT, J. W. BROWNE, V. KUMAR, G. D. MEAKINS, J. T. PINHEY, V. E. M. THOMAS, MIKROBIOLOGISCHE HYDROXYLIERUNG VON STEROIDEN 2. MITT. STRUKTURAUFKLAERUNG UND INFRAROT-SPEKTROSKOPIE, CARBONYL-, GESTOERTE METHYLEN- UND HYDROXY-SCHWINGUNGEN VON STEROIDKETONEN UND -ALKOHOLEN, J. Chem. Soc. C, 1971, 1130. DOI: 10.1039/j39710001130; 10.1039/j39710001130 Web of Science®Google Scholar Volume2, Issue27July 6, 1971 ReferencesRelatedInformation