The supercharged nature of the Earth’s geothermal core can be demonstrated by three thought experiments exhibiting it is tremendously more powerful than any other terrestrial object in the solar system (planet or moon). Identifying a minimum of four byproduct asteroid blast patterns linked to the formation of Earth’s supercharged geothermal core is critical to properly identifying stars that also have these four byproduct asteroid blast patterns. These stars are the most likely to host an Earth-like planet qualified by having a supercharged geothermal core. The Planetary Vaporization-Event (PVE) Hypothesis provides a basis for correlation between the supercharged nature of Earth’s geothermal core and at least 14 listed side effects: (1) the asteroid-wide/planet-scale homogenization and lack thereof of 182W ε for Earth, the Moon, Mars and meteors, (2) the primary and secondary shifting of Earth’s tectonic plates, (3) the solar system wide displacement of Earth’s wayward moons (including Ceres, Pluto, Charon and Orcus) outgassing identical samples of ammoniated phyllosilicates, (4) the formation of asteroids at 100+ times the expected density of a nebular cloud vs. pre-solar grains formation density at the expected density of a nebular cloud, (5) three distinct formation timestamps for all known asteroids within a 5 million year window 4.55+ billion years ago, (6) the estimated formation temperature of CAI at 0.86 billion Kelvin and (7) the remaining chondritic meteorite matrix flash vaporizing at 1,200–1,900 °C, (8) followed by rapid freezing near 0 K, (9) the development of exactly 2 asteroid belts and a swarm of non-moon satellites, (10) particulate size distinction between the 2 asteroid belts of small/inner, large/outer, (11) the proximity of the Trojan Asteroid Groups to the Main Asteroid Belt, (12) observation of a past or present LHB, (13) the development of annual meteor showers for Earth proximal to apogee and/or perigee, (14) the Sun being the most-likely object struck by an asteroid in the inner solar system. Through better understanding of the relevant data at hand and reclassification of the byproducts of supercharging the core of a planet, at least 5 new insights can be inferred and are listed as: (1) the original mass, (2) distance and (3) speed of Earth Mark One, (4) the original order of Earth’s multi-moon formation and (5) the high probability of finding detectable signs of life on a planet orbiting the stars Epsilon Eridani and Eta Corvi. There are at least 6 popular hypothesis that the PVE Hypothesis is in conflict with, listed they are: (1) a giant impact forming the Moon, (2) asteroids being the building blocks of the solar system, (3) the Main Asteroid Belt being the result of a planet that never formed, (4) the LHB being a part of the accretion disk process, (5) the heat in Earth’s core coming primarily from the decay of radioactive elements, (6) the Oort Cloud being the source of ice comets.
The prospective of maize cob powder (MCP) as an effective adsorbent for the removal of malachite green (MG) and congo red (CR) dyes from aqueous solution was investigated. The presence of functional groups and pores on maize cob powder were confirmed by FTIR and SEM analysis. Batch adsorption studies were conducted and various parameters such as contact time, adsorbent dosage, initial dye concentration, pH and temperature were examined to observe their effects in the dyes adsorption process. The optimum conditions for the adsorption of MG and CR onto the adsorbent (MCP) was found to be: contact time (60mins), pH (10.0) and temperature (303 K), adsorbent dose (1 g) for an initial MG dye concentration of 50 mg/L and contact time (80mins), pH (2.0) and temperature (343 K) for an initial CR dye concentration of 50 mg/L and adsorbent dose 1.0 g respectively. The experimental equilibrium adsorption data fitted best and well to the Freundlich isotherm model for CR dye adsorption and Langmuir Isotherm for MG adsorption. The maximum adsorption capacity was found to be 13.02 mg/g and 9.41 mg/g for the adsorption of MG and CR dyes respectively. The kinetic data conformed to the pseudo-second-order kinetic model. Thermodynamic quantities such as Gibbs free energy (ΔG0), enthalpy (ΔH0) and entropy (ΔS0) were evaluated and the negative values of ΔG0, ΔH0 and ΔS0 obtained indicated the spontaneous and exothermic nature of the MG adsorption process while positive enthalpy (ΔH0) indicated an endothermic nature of CR adsorption process.
The motion is investigated of dust/gas particles in the elliptic restricted three-body problem (ER3BP) in which the less massive primary is an oblate spheroid and the more massive a luminous body surrounded by a circumbinary disk. The paper has investigated both analytically and numerically the effects of oblateness and radiation pressure of the primaries respectively together with the gravitational potential from a disk on the triangular equilibrium L4,5 of the system, all in the elliptic framework of the restricted problem of three bodies. The important result obtained therein is a move towards the line joining the primaries in the presence of any /all perturbation(s). A significant shift away from the origin as the radiation pressure factor decreases and oblateness of the smaller primary increase is also observed. It is also seen that, all aforementioned parameters in the region of stability have destabilizing tendencies resulting in a decrease in the size of the region of stability except the gravitational potential from the disc. The binary system Ruchbah in the constellation Cassiopeiae is an excellent model for the problem, using the analytic results obtained, the locations of the triangular points and the critical mass parameter are computed numerically.
This paper studies the classical restricted three-body problem of a carbon atom in the vicinity of two carbon 60 fullerenes ( fullerenes) at the nanoscale. The total molecular energy between the two fullerenes is determined analytically by approximating the pairwise potential energies between the carbon atoms on the fullerenes by a continuous approach. Using software MATHEMATICA, we compute the positions of the stationary points and their stability for a carbon atom at the nanosacle and it is observed that for each set of values, there exists at least one complex root with the positive real part and hence in the Lyapunov sense, the stationary points are unstable. Since only attractive Van der Waals forces contribute to the orbiting behavior, no orbiting phenomenon can be observed for , where the Van der Waals forces becomes repulsive. Although the orbital is speculative in nature and also presents exciting possibilities, there are still many practical challenges that would need to be overcome before the orbital might be realized. However, the present theoretical study is a necessary precursor to any of such developments.
In this manuscript, the authors explore the antimicrobial and anti-inflammatory properties of extracts from two commonly found and used leaves from species Murraya koenigii and Ocimum gratissimum L., Ethanolic extracts were obtained by maceration and were then concentrated. Serial dilutions of the extracts were done for testing. The extracts were tested for growth inhibition of four bacterial and two fungal strains. Visual examination of growth inhibition, compared to standard antibiotic controls, provided minimum inhibitory concentrations for the two extracts against the six microbial strains. In another experiment, the authors test the anti-inflammatory properties of the two leaf extracts in the standard rat-paw model of inflammation. Results from growth inhibition studies suggest that the two leaf extracts inhibit the growth of all six microbes, with varying levels of sensitivity. Results from anti-inflammatory studies are more impressive, with leaf extracts inhibiting inflammation at levels competitive with the standard drug, indomethacin.
The solubility of triazolo quinolone class derivatives in methanol, ethanol, n-propanol, n-butanol and ethyl acetate was measured using a gravimetrical method at temperature ranging from 298.15 K to 328.15 K. The results of these measurements were correlated with semi empirical equations. Some thermodynamic parameters such as dissolution enthalpy, Gibb’s free energy and entropy of mixing have also been calculated.
This paper presents the spectroscopic graphs of recently discovered Supernova Remnants (AT2019fya, SN2019fjp, SN2019fcc, SN2019fce, SN2019fbv & SN2019ffi) for the determination of elements present. The researchers use the spectral plot analysis to analyze the presence of certain elements of the individual supernova remnants (SNR) for the assimilation, differentiation and classification of these SNR. Redshift and velocities of these SNR were also found using the observed wavelength and the rest wavelength ratio. Comparison suggests that AT2019fya is a Type II supernova remnant and some of the SNRs in this study exhibits an existence of krypton (Kr) on their composition which is recently discovered by M. Barlow (2013) to be present at the Crab Nebula. This might suggest that AT2019fya, SN2019fbv, SN2019fce, and SN2019ffi have a pulsar at their center.
A data set of chalcone and pyrimidine derivatives with anti-malarial activity against Plasmodium falciparum was employed in investigating the quantitative structure-activity relationship (QSAR). Molecular docking study was performed for plasmodium falciparum dihydrofolate reductase (PfDHFR-TS). Genetic function approximation (GFA) technique was used to identify the descriptors that have influence on anti-malarial activity. The most influencing molecular descriptors identified include thermodynamics, structural and physical descriptors. Generated model was found to be good based on correlation coefficient, LOF, rm2 and rcv2 values. Nrotb, solubility, polarizibility may have negative influence on antimalarial activity or play an important role in growth inhibition of Plasmodium falciparum. The QSAR models so constructed provide fruitful insights for the future development of anti-malarial agents.
Oxidation of dibenzalacetone with pyrazinium chlorochromate in presence of oxalic acid has been studied at 313 K. Various reaction parameters such as effect of varying oxidant, substrate, Hydrogen ion concentration, catalyst, solvent composition, ionic strength, effect of Mn 2+ , effect of Al 3+ and effect of temperature were studied to determine the kinetics of the reaction. Our study revealed that the reaction followed first order dependence with respect to oxidant and catalyst. The reaction followed fractional order kinetics with respect to substrate and H+. Increase in ionic strength was found to have no effect on the reaction rate and decrease in the dielectric constant of the medium decreases the reaction rate. Increase in the concentration of manganous sulphate retarded the reaction rate which confirmed the two-electron transfer involved in the mechanism. There was no possibility of free radical mechanism, which was confirmed by the addition of acrylonitrile shows no significant effect on the reaction rate indicating the non-involvement of free radical reaction.. Based on the experimental observations a mechanism and rate law has been derived. Moreover, the oxidation product was found to be chalcone epoxide, which was characterized by IR spectrum.
Motivated by recent experimental progress, we study the quantum transport properties of two-dimensional electron gases under high perpendicular magnetic fields. We use a simple tight-binding model to model the system and open-source software to simulate quantum electronic transport properties such as band structure variations and conductance-flux relationships in such systems. Dependence of quantum transport properties on two-dimensional square, triangular and kagome lattice shapes were studied adding a Gaussian noise to account for the impurities. Numerical simulations are presented to predict the emergence of physical effects related to quantum Hall effect, such as the existence of Landau levels and edge states. The kagome lattice exhibits a different band structure giving rise to a flat band, due to its trihexagonal geometry. The peak conductance value increases with decreasing lattice constant due to higher transmission probability. The transport properties vary significantly with lattice geometries, both with the lattice type and the lattice constant.
Interactions of sulforhodamine B or ethyl eosin (as the anionic dye) with cetylpyridinium bromide (as a cationic surfactant) have been investigated by visible spectroscopy in aqueous solution. The object of research is the association between an anion of dye and of cationic surfactant in aqueous solutions and its features. Computer simulation of these interactions was carried out with the use of AM1 and PM3 semi-empirical methods. A new spectrophotometric method was developed for determination of critical micelle concentration of cationic surfactants.
Within the framework of the theory of relativistic vector fields, the covariant expressions are presented for the equations of motion of the matter and the field. These expressions can be written either in terms of the field tensors, that is, the fields’ strengths and solenoidal vectors, or in terms the four-potentials, that is, the fields’ scalar and vector potentials. This state of things is due to the fact that the Lagrange function initially implied the complementarity of description in terms of the strengths and the field potentials. It is shown that the equation for the fields, obtained by taking the covariant derivative in the equation for the metric, has a deeper meaning than the ordinary equation of motion of the matter, found with the help of the principle of least action. In particular, the above-mentioned equation for the fields leads to the generalized Poynting theorem, and after integration over the volume it allows us to introduce for consideration the integral vector as a measure of the energy and the fields’ energy fluxes, associated with a system of particles and fields.
This study examines the triangular points in the elliptic restricted three-body problem when both primaries are sources of radiation as well as oblate spheroids with oblateness up to zonal harmonic J4. The positions of triangular points and their critical mass ratio are seen to be affected by the eccentricity, semi major axis, radiation and oblateness of both primaries up to zonal harmonic J4. We highlight the effects of the said parameters on the locations of the triangular points of 61 CYGNI and STRUVE 2398. The triangular points of these systems are found to be unstable.
The corrosion behaviour of cationic surfactants, namely: cetyl trimethyl ammonium bromide (CTAB) and dodecyl trimethyl ammonium bromide (DTAB), have been used as corrosion inhibitors for carbon steel in well water. Protection efficiencies of the studied surfactants were depended on the hydrophobic chain length and concentration of the surfactants. The results shows that the order of protection efficiency is CTAB > DTAB. Tafel curves showed these surfactants are acting as an anodic inhibitors. Nyquist curves revealed that a protective film is formed on the metal surface. FTIR spectra suggest that the tested surfactants protective film consists of Fe 2+ -CTAB, Fe 2+ -DTAB and Zn(OH) 2 . Protection efficiency values and synergism parameters obtained weight loss; potentiodynamic polarization and electrochemical impedance spectroscopy are consistent.
An (4E,6E)-alkadienyl alcohol which is a solid compound which can be stored at rt, upon dissolving into a suitable solvent undergoes facile autoxidation (4E,6E)-alkadienyl alcohol 1 in air at room temperature. The result is complete decompose leading to a mixture of products, including benzaldehyde (24%) and cinnamaldehyde (29%). Possible mechanistic explanations for the autoxidation are discussed.
Protection against ultraviolet radiation is one of the areas, in which considerable attention is being paid. Application of a wash durable finish on cotton fabric to protect the wearer from these radiations remains a challenge. The harmful effects of UV radiations result in the form of eye disorders, accelerated ageing of skin, DNA damage and cause of cancer. The current study focuses upon the use of TiO2 on cotton fabric to impart UV protection. TiO2 is deposited on cotton fabric using its pre-cursor. Sol-gel method has been used to convert pre-cursor into titanium oxide directly on fabric surface. The deposition was further stabilized on fabric surface by various heat treatments such as curing, hydrothermal and solvothermal treatments. It has been found that the TiO2 remains wash durable with a reasonably high degree of UV protection after hydrothermal and solvothermal treatments. EDX and ICP-MS techniques were used to examine the add-on % of TiO2 on cotton fabrics. The morphology of the TiO2 coated cotton fabric was studied using Field emission scanning electron microscopy. The measurement of UV protection property of the fabric has been carried out using UV-visible spectrophotometer (UV-2000F, Labsphere, USA).
The variation of the lightning activities over Sri Lanka and surrounded costal belt (5.75 0 N-10.00 0 N and 79.5 0 E-89.00 0 E) is studied using lightning flash data of Lightning Imaging Sensor (LIS) which was launched in November 1997 for NASA’s Tropical Rainfall Measuring Mission (TRMM). The LIS data for the period of 1998 to 2014 are considered for this study. The spatial and temporal variation of lightning activities is investigated and respective results are presented. The diurnal variation over the studied area presents that maximum and minimum flash count recorded at 1530-1630 Local Time (10-11UTC) and 0530-0630LT (00-01UTC) respectively. Maximum lightning activities over the observed area have occurred after the 1330LT (08UTC) in every year during the considered time period. The seasonal variation of the lightning activities shows that the maximum lightning activities happened in First inter monsoon season (March to April) with 30.90% total lightning flashes and minimum lightning activities recorded in Northeast monsoon season (December to February) with 8.51% of total lightning flashes. Maximum flash density of 14.37fl km -2 year -1 was observed at 6.98 0 N/80.16 0 E in First inter monsoon season. These seasonal lighting activities are agree with seasonal convective activities and temperature variation base on propagation of Intra-Tropical Convection Zone over the studied particular area. Mean monthly flash count presents a maximum in the month of April with 29.12% of lightning flashes. Variation pattern of number of lightning activities in month of April shows a tiny increment during the time period of 1998 to 2014. Maximum annual flash density of 28.09fl km -2 yr -1 was observed at 6.98 0 N/80.17 0 E. The latitudinal variation of the lightning flash density is depicted that extreme lightning activities have happened at the southern part of the county and results show that there is a noticeable lack of lightning activities over the surrounded costal belt relatively landmass.
This study includes the effect of the etching time on the morphology of the surfaces produced using the electrochemical method of silicon ( p-type), where it was found that the etching leads to increase the porosity layer of silicon. The production of nanocrystalline structures and control of their production conditions is the first step to control the properties of the devices. These are very important applications for the etching of renewable energy.
The potential of Calcinated and uncalcinated zinc oxide as effective Photocatatlyst for the degradation of malachite green dye, MG from aqueous medium using UV light has been identified. The photocatalysts were characterized using scanning electron microscope, SEM and x-ray diffraction, XRD. The SEM investigations of the calcinated ZnO revealed highly dispersed nanomaterials and the particles were of nanometer size in agreement with the XRD result. The uncalcinated zinc oxide, ZnO revealed some pronounced nanoparticles. The degradation of MG by the photocatalyst was found to be influenced by adsorbent loading and irradiating time. The optimum degradation was obtained at 0.5g catalyst loading of both calcinated and uncalcinated zinc oxide which is 98.48% and 96.31 % respectively at 150 minutes. The degradation kinetics conformed to the pseudo-first-order kinetic model. The present study showed that calcinated and uncalcinated zinc oxide ZnO can be effectively used as efficient photocatalyst for the degradation of Malachite green dyes from aqueous solutions and effluents.
Chitosan, a naturally occurring biopolymer extracted from prawn heads was used in the treatment of crump rubber processing effluent for safe disposal into the environment. The triplicate analyses of the effluent samples obtained by composite sampling method indicated high levels of pollution which violated the permissible limits of environmental discharge standards; with a low DO of 0.63mg/L, BOD, 312.00±1.32mg/L and COD, 1069.58±2.42mg/L (mean±SD) respectively. Chitosan was analyzed according to standard procedures; it showed good coagulative potentials from the elemental analysis and a degree of deacetylation of 76.5%. The crump rubber processing effluent was treated with chitosan and Iron (III) Chloride respectively by coagulation and flocculation method and the results obtained via the physico-chemical characterization of the treated effluent showed that the use of chitosan as a coagulant compared favourably with Iron (III) Chloride after treatment. DO levels increased from 0.63mg/L to 3.90 mg/L. There were also remarkable reduction in the Turbidity, Biochemical Oxygen Demand (BOD) and the Chemical Oxygen Demand (COD) levels of the treated samples by over 80% respectively and 70% reduction in the nutrient levels. The efficacy of chitosan in comparison with Iron (III) Chloride suggests that it can be used as a replacement for synthetic coagulants based on its availability and environmental friendliness.
