— Clay subfractions (SFs) with particles size of 2–5, 0.6–2.0, 0.3–0.6, 0.2–0.3, and 0.1–0.2 μm of two shale samples (Upper Riphean Inzer Formation, South Urals) are studied using transmission electron microscopy, X-ray diffractometry (XRD), and U–Pb, Sm–Nd, Rb–Sr, and K–Ar methods. The SFs are composed of low-temperature 1M d illite; quartz, chlorite, and 2M 1 illite are observed only in some coarse SFs. Irrespective of the size, the clay particles are equant. The standardized illite crystallinity indices (CIS) of all SFs are typical of the dia(cata)genesis zone. The CIS value increases, the I 002 /I 001 ratio of XRD patterns decreases, and the K content and K/Rb ratio increase with decreasing particle size of the SFs from 2–5 to 0.1–0.2 μm. Leaching with 1N HCl and 1N NH 4 OAc and U–Pb, Sm–Nd, and Rb–Sr analysis of untreated SFs, leachate, and residue allowed us to study the isotope systematic of mixing in mobile and silicate material of shales. The 208 U/ 204 Pb and 87 Rb/ 86 Sr ratios of leachates are lower and the 147 Sm/ 144 Nd ratio is higher than those of residues. The leachates are also characterized by less radiogenic Pb and Sr and more radiogenic Nd relative to residues. With decreasing size of SF particles, the U, Pb, Sm, Nd, and Sr contents of leachates gently decrease and the Rb content increases. The 87 Rb/ 86 Sr and 87 Sr/ 86 Sr ratios of leachates of fine SFs are significantly higher, whereas their 238 U/ 204 Pb ratio is lower in comparison with coarse SFs. What is more, the data points of residues of various SFs occur along the mixing lines in the 87 Rb/ 86 Sr‒ 87 Sr/ 86 Sr and 1/ 86 Sr‒ 87 Sr/ 86 Sr plots. The data points of corresponding leachates also form linear trends in 238 U/ 204 Pb‒ 206 Pb/ 204 Pb, 206 Pb/ 204 Pb‒ 207 Pb/ 204 Pb, 147 Sm/ 144 Nd‒ 143 Nd/ 144 Nd, and 87 Rb/ 86 Sr‒ 87 Sr/ 86 Sr coordinates. Apparent Rb–Sr ages calculated from slopes of “inner isochrons” (“leachochrons”) as well as K-Ar ages gradually decrease from 835–836 and 721–773 Ma, respectively, for SFs of 2–5 μm and to 572‒580 and 555‒580 Ma, respectively, for SFs of 0.1–0.2 μm. Thus, the XRD and isotopic data indicate that both clay and mobile shale constituents are mixtures at least of two components, and the silicate phase contains authigenic illites of various ages. First-generation illite abundant in the coarse SFs of 2–5 μm and 0.6–2.0 μm was formed immediately after the deposition of the Inzer sediments and its age of 803–836 Ma is consistent with stratigraphic age of the Inzer Formation. The formation of this illite was facilitated either by lithostatic burial or intense horizontal fluid flow caused by tectonic inversion in the eastern regions of the Uralian paleobasin. The age of the second-generation illite is 572–580 Ma; it was formed as a result of vertical movements or renovation of the composition of the pore fluids during deformations and metamorphism of the South Urals related to the evolution of the Beloretsk metamorphic complex.

The 2–5, 0.6–2, 0.3–0.6, 0.2–0.3 and 0.1–0.2 µm clay subfractions (SFs) separated from two shale samples of the Upper Riphean Inzer Formation, the southern Urals, were studied by the TEM, XRD, and U–Pb, Sm–Nd, Rb–Sr and K–Ar isotopic methods. All the SFs consist of the low-temperature 1Md illite; admixtures of quartz, chlorite and 2M1 illite occur only in the coarsest SFs. The clay particles are isometric, regardless of their size. The CIS (Crystallinity Index Standard) illite values for the all SFs are typical for the dia(kata)genetic zone. As the size of particles in the SF decreases from 2–5 to 0.1–0.2 µm, the CIS rises, the I002/I001 ratio on the XRD diagrams decreases, and the K content and the K/Rb ratio increase. Leaching with 1N HCl and 1N ammonium acetate (NH4OAc) and subsequent U–Pb, Sm–Nd and Rb–Sr analyses of the untreated SF, acid (acetate) leachate and residue made possible to study the mixing systematics in mobile and silicate materials of the shales. The 238U/204Pb and 87Rb/86Sr ratios in the acid and acetate leachates are below, and the 147Sm/144Nd ratio is above those in the residues. Less radiogenic Pb and Sr and more radiogenic Nd are also common for the leachates compared to the residues. As the size of particles in the SFs decreases, the U, Pb, Sm, Nd and Sr contents in the residues are smoothly reduced, whereas the Rb content shows an increase. The 87Rb/86Sr and 87Sr/86Sr values in the residues for fine-grained SFs are well above, and the 238U/204Pb value is well below those for coarse-grained SFs. What is more, in the 87Rb/86Sr–87Sr/86Sr and 1/86Sr–87Sr/86Sr diagrams, data points for the residues of variable size are arranged on the mixing lines. The data points of respective acid and acetate leachates also form linear trends in the 238U/204Pb–206Pb/204Pb, 206Pb/204Pb–207Pb/204Pb, 147Sm/144Nd–143Nd/144Nd, and 87Rb/86Sr–87Sr/86Sr coordinates. The apparent Rb–Sr age values, calculated from the slopes of “inner isochrons” (“leachochrons”), along with the K–Ar ages are smoothly lowered from 835–836 and 721–773 m.y. for the 2–5 µm SF to 572–580 and 555–580 m.y. for the 0.1–0.2 µm SF. Hence the XRD and isotopic data testify that the clay as well as the mobile material of the shale represent the mixtures of at least two components, the silicate phase containing authigenic illites of different ages. The first illite generation enriched in coarse-grained 2–5 and 0.6–2 µm SFs was formed shortly after deposition of the Inzer sediments, and its age of 803–836 m.y. is in agreement with the stratigraphic age of the formation. Simple lithostatic burial or intensive lateral fluid flow induced by tectonic inversion in the eastern regions of the Urals paleobasin may be considered as the geological processes responsible for the forming of this illite. The second illite generation was formed 572–580 m.y. ago. As the starting points for its formation, alternatively, may be concerned either vertical tectonics or renewal of pore fluid compositions during deformations and metamorphism on the southern Urals area related to evolution of the Beloretsk metamorphic complex.

Определен Pb–Pb изотопный возраст и получена Sr-изотопная характеристика осадочных известняков верхнего рифея юга Енисейского кряжа на западной окраине Сибирской платформы. Возраст карбонатных осадков дадыктинской свиты тунгусикской серии в Каменской фациальной зоне на востоке Енисейского кряжа составляет 1020 ± 20 млн лет. Возраст известняков горевской свиты широкинской серии в Глушихинской фациальной зоне на западе региона оценивается в 1020 ± 70 млн лет. Отношение 87 Sr/ 86 Sr в известняках дадыктинской свиты заключено в пределах 0.70536–0.70590, а горевской – 0.70552–0.70578. Это совпадает с понижением отношения 87 Sr/ 86 Sr в океане сразу после кульминационной фазы гренвильской орогении. Корреляция широкинской серии с ослянской серией Каменской зоны в сочетании с другими данными ограничивает время накопления тунгусикской, широкинской и ослянской серий интервалом 1030–950 млн лет. Изотопный возраст границы среднего и верхнего рифея в основании тунгусикской серии Енисейского кряжа оценивается как 1030 млн лет, что согласуется с возрастом этого рубежа в разрезах Туруханского поднятия и Учуро-Майского региона Сибири. Установлено, что большая часть верхнего рифея (неопротерозоя) в осадочной летописи Енисейского кряжа отсутствует. Наблюдаемая фациальная зональность рифейских отложений Енисейского кряжа отражает конфигурацию древнего осадочного бассейна, который существовал на западной окраине Сибирской платформы задолго до коллизионных событий, сопровождавшихся гранитообразованием и метаморфизмом, в неопротерозое.

— The Pb–Pb isotope age and the Sr isotope signature of the Upper Riphean sedimentary limestones from the south of the Yenisei Range on the western margin of the Siberian Craton were obtained. The Pb–Pb age of carbonate deposits of the Dadykta Formation of the Tungusik Group in the Kamenka facial zone in the east of the Yenisei Range is 1020 ± 20 Ma. The Pb–Pb age of limestone of the Gorevka Formation of the Shirokaya Group in the Glushikha facies zone in the western part of the region is estimated at 1020 ± 70 Ma. The 87 Sr/ 86 Sr ratio in limestones of the Dadykta Formation lies within 0.70536–0.70590 and that of the Gorevka Formation lies within 0.70552–0.70578. This coincides with a decrease in the 87 Sr/ 86 Sr ratio in a paleo-ocean immediately after the culmination of the Grenville orogeny. The correlation of the Shirokaya Group with the Oslyanka Group of the Kamenka Zone in combination with other data has shown that the accumulation of the Tungusik, Shirokaya, and Oslyanka groups occurred within an interval of 1030–950 Ma. The isotope age of the Middle and Upper Riphean boundary at the base of the Tungusik Group of the Yenisei Range is estimated at 1030 Ma, which is consistent with the age of this boundary in the sections of the Turukhansk Uplift and the Uchur-Maya Region of Siberia. It was revealed that the greater part of the Upper Riphean (Neoproterozoic) in the sedimentary record of the Yenisei Range is missing. The observed facial zoning of the Riphean deposits of the Yenisei Range represents the configuration of the ancient sedimentary basin that existed at the western margin of the Siberian Craton long before the collisional events accompanied by granite intrusions and superimposed metamorphism in the Neoproterozoic.

For the first time, the age of magnesite in the Lower Riphean Bakal Formation of the Southern Urals is determined by the U—Pb (Pb—Pb) method: it is equal to 1366 ± 47 Ma (MSWD = 18). The stage of magnesite formation of the Bakal ore field was associated with the Mashak rifting pulse and took place prior to the formation of industrial deposits of the Bakal siderite.

The geochemistry, geochronology, and isotope geochemical systematics (Nd, Sr, Hf, and Pb) of the granitoids of the Pozdnestanovoy complex of the Dzhugdzhur–Stanovoy superterrane of the Central Asia fold belt were investigated. It was shown that their age is Mesozoic (142–138 Ma) rather than Early Precambrian, as was previously supposed. The main sources of parental melts for these granitoids were the Neoarchean and Paleoproterozoic rocks of the lower continental crust of the Dzhugdzhur–Stanovoy superterrane and the rocks of the Late Paleozoic–Early Mesozoic continental crust of the Amur microplate. They were formed at depths of >40 km and temperatures of 700–800°C, most likely through the melting of mafic feldspar granulites under the conditions of aqueous fluid infiltration without any significant contribution from a juvenile heat source. The granitoids of the Pozdnestanovoy complex were emplaced during the closure of the eastern segment of the Mongolia–Okhotsk Ocean owing to the collision of the Siberian and Sino-Korean continents.

Изучены Pb-изотопные системы калиевого полевого шпата, пирита, пирротина из габброидов и руд раннепротерозойского массива Велимяки в юго-восточной части Фенноскандинавского щита. Изохронный Pb-Pb-возраст сульфидов определен как ~450 млн лет, что соответствует пересечению линии регрессии с кривой накопления свинца с = 10,4-10,8; модельный Pb-возраст сульфидов близок к изохронному при условии, что изотопный состав Pb эволюционировал из геохимического резервуара возраста 1,9 млрд лет. Изотопные параметры Pb сульфидов и калиевого полевого шпата указывают на формирование их в верхнекоровых условиях ( = U/Pb > 10). Из полученных данных следует, что изотопный состав Pb калиевого полевого шпата отвечает протерозойскому времени (1890 млн лет) магматической кристаллизации пород массива, а сильно радиогенные свинцы сульфидов с наибольшей вероятностью свидетельствуют о более позднем (каледонском) времени формирования сульфидных руд.

We have studied Pb isotopic systems of K-feldspar, pyrite, and pyrrhotine from gabbroids and ore of the Velimyaki Early Proterozoic massif in the northern Ladoga region in the southeastern part of the Fennoscandian Shield. The isochronous Pb–Pb age of sulfides has been determined as ∼450 Ma, which corresponds to intersection of the regression line with the lead accumulation curve with μ = 10.4–10.8; the model Pb age of sulfides is close to isochronous under the condition that the composition of lead evolved from a geochemical reservoir with an age of 1.9 Ga. The isotopic parameters of the lead in sulfides and K-feldspar indicate their formation in upper crust conditions (μ = 238U/204Pb > 10). From the obtained data, it follows that the isotopic composition of lead in K-feldspar corresponds to a Proterozoic age (1890 Ma) of magmatic crystallization of the rocks in the massif, and strongly radiogenic lead sulfides testify, with the greatest probability, to the later (Caledonian) formation of sulfide ores.

Neoproterozoic sedimentary records reveal a poorly documented, similar to 150 m.y. time interval, between 1000 and 850 Ma, that limit our understanding of C and Sr isotope variations in seawater and thus operation of the biogeochemical carbon cycle, changes in surface redox state, and fluctuations in continental vs. hydrothermal fluxes to the oceans following assembly of the supercontinent Rodinia. Carbon and Sr isotope data for carbonates from the Karatau Group of the Southern Ural Mountains in Russia provides a record partially covering the younger portion of this time interval. The lower part of the Karatau Group (LKG) contains well-preserved carbonate strata of the Katav, Inzer, and Min'yar formations that are focus of this study. Pb-Pb isochron ages for carbonates from the Inzer and Min'yar formations are 844 +/- 24 and 820 +/- 77 Ma, respectively, establishing an early Tonian age. Carbon isotope data for unaltered carbonates in the LKG show a range of moderately positive to negative values from -2.8 to +5.9%o, with the majority below +3.0%0. Sr-87/Sr-86 values range from 0.70522 to 0.70534 in the Lower Inzer Member, increasing in the overlying Upper Inzer Member and Min'yar Formation, from 0.70555 to 0.70600. The Sr isotope range of the Lower Inzer Member is similar to that typical for the 1.030.95 Ga seawater (0.70519-0.70554), suggesting that the Sr isotope composition of seawater in the aftermath of Rodinian assembly was unradiogenic for 150 m.y. This pattern indicates that supercontinent scale orogenic events do not result in an enhanced, long-term flux of radiogenic Sr from continents once the supercontinent assembled. To account for the prolonged period characterized by unradiogenic Sr seawater composition and moderate-amplitude C isotope variations, we suggest a supercontinent configuration ringed by continental arcs and with predominantly internal runoff. In this model, accompanying supercontinent blanketing resulted in thermal perturbation in the mantle, emplacement of multiple Large Igneous Provinces, and high continental freeboard. Weathering of juvenile arcs would have provided unradiogenic Sr and a high flux of sediments to the oceans, enhancing organic carbon burial and progressive oxygenation of surface environments and contributing to instability in the biogeochemical carbon cycle. Mass anomalies induced by protracted mantle plume activity led to True Polar Wander and brought the supercontinent, covered with juvenile mafic volcanics and segmented by failed rift systems, to low latitudes thus enhancing chemical weathering, atmospheric CO2 consumption, and eventually ushering in Snowball Earth conditions. Comparison with the records for early Paleoproterozoic strata indicates that a similar sequence of events bracketed both ends of the Proterozoic, highlighting fundamental relationships among plate tectonics, mantle dynamics, biogeochemical carbon cycling, surface oxygenation, and climate change. (C) 2017 Elsevier B.V. All rights reserved.

The isotopic–geochemical features of late and postorogenic granites of the S type and ambient migmatites are studied within the Russian part of the Svecofennian orogen of the Fennoscandinavian Shield. The spatial association of leucosomes of migmatites and granites of the S type and their similar petro- and geochemistry and distribution of Pb isotopes are evidence of the genetic similarity of their parental melts. The Borodinskoe pluton has a more primitive 206Pb/207Pb ratio, which indicates the presence of upper and U-poor lower crustal material in the source of granitic magmas. This conclusion is supported by the ɛNt(t) lower value of granites of this pluton relative to those of other plutons of the region.

The Pb-Sr-O-C isotope compositions of calcite marbles of the Derbina Formation, exposed in the northwestern part of the Derbina block of the East Sayan, were studied. Rocks of the Derbina Formation were metamorphosed under high-temperature amphibolite facies conditions. The carbonate constituent of marbles contains (ppm) 15–130 Mn, 130–160 Fe, 0.008–0.039 Rb, 645–2190 Sr, 0.565–0.894 U, and 0.288–1.42 Pb. These concentrations are similar to those in modern carbonate sediments. The values of δ13C in marbles of the Derbina Formation range from–0.6 to +1.4‰ PDB; the values of δ18O range from 21.5 to 28.6‰ SMOW. The 87Sr/86Sr ratio values in the two least altered rocks, which meet geochemical criteria of the Rb-Sr system preservation in high-grade carbonate rocks, are 0.70804 and 0.70829. The protolith ages of marbles determined using Sr and C chemostratigraphy lie within the interval of 560–530 Ma, which is regarded as the period of carbonate sedimentation. The slope of the straight line on the 206Pb/204Pb–207Pb/204Pb diagram (n = 9, MSWD = 19) constructed on the basis of the data points of bulk carbonate constituents of all samples studied and those representing leachate steps of one of them in 0.5N HBr yields Late Vendian age (556 ± 31 (2σ) Ma. Taking into account the data on Sr and C isotope systematics of Derbina marbles, this age is regarded as the age of early diagenesis of carbonate sediments close to the age of sedimentation. Thus, metacarbonate rocks of the Derbina Formation preserved the pre-metamorphic chemostratigraphic and isotope-geochronological information. The age obtained testifies that formation of the carbonate cover of the Derbina block occurred in the Late Vendian. At the end of the Cambrian, carbonate deposits were metamorphosed during the Early Caledonian tectonic event in the southeastern part of the Central Asian Fold Belt.

The Pb-Pb age of phosphorite concretions of the Zigaza-Komarovo Formation, which composes the intermediate horizons of the Riphean stratotype of the South Urals, was determined in fractions resulting from the stepwise dissolution of concretions in 0.1 N, 0.5 N, and 1 N HCl. The determination of the Sr isotopic composition in phosphate fractions was favorable for rejection the fractions polluted with extraneous material. On the 207Pb/204Pb-206Pb/204Pb diagram, the isochron based on 31 points corresponds to 1330 ± 20 Ma (MSWD = 1.12), which is in agreement with the stratigraphic position of the Zigaza-Komarovo Formation. The decreased μ2 value of 9.57 for the phosphorite concretions relative to that of the average earthly lead based on the Stacey-Kramers model (9.74) is related to the rocks with an admixture of mantle lead, which occur in the run-off area of the Zigaza-Komarovo sediments.

The U-Pb and Pb-Pb methods were used for determining age of cap limestones from the Neoproterozoic Tsagaan Oloom Formation corresponding to the lower part of the sedimentary cover in the Dzabkahn microcontinent of Central Asia. The weighted average age value appeared to be equal to 632 ± 14 Ma (MSWD = 0.11, probability 0.74). This value allows the following assumptions: (1) the lower boundary of the Tsagaan Oloom Formation corresponds to the beginning of the Ediacaran; (2) Dzabkhan tillites are correlative with glacial sediments of the Marinoan Epoch. The low 238 U/ 204 Pb and 232 Th/ 238 U ratios observed in initial Pb sources of limestones from the Tsagaan Oloom Formation indicate that the Dzabkhan paleobasin received at its early development stages a bulk of material from eroded upper Riphean juvenile rocks. The 87 Sr/ 86 Sr ratio in fractions of Tsagaan Oloom limestones enriched with primary carbonate material and satisfying geochemical criteria of Rb-Sr systems retentivity (Mn/Sr < 0.20 and Fe/Sr < 1) varies from 0.70676 to 0.70691 and reflects this ratio in the World Ocean approximately 630 Ma ago.