The article considers the theory, methods, and some results of four-year field studies of the processes of runoff formation on a small freezing experimental river catchment in a continuous thick (400 m) permafrost zone (the Republic of Sakha (Yakutia)) based on data on natural water chemistry. The analyzed problems include the seasonal and daily dynamics of river flow in the warm season, the concentrations of some dissolved substances in different types of water, as well as the role of channel widenings, supra-permafrost water, and aufeises in flow formation. Various types of relationships between water discharges and the concentrations of some dissolved substances are described under varying hydrothermal conditions. The role of nonfreezing lake-like channel widenings (bochags) in the regulation of freshet flow of water and dissolved matter is evaluated. The efficiency of the automated digital registration of the level, temperature, and specific electric conductance of water with a high time resolution at hydrological gages is discussed, especially, as applied to the rapid processes in a river.

In the permafrost regions, where water filtration zone is limited by the shallow active layer, the surface flow forms a network of hollows, called «water tracks», oriented along the slope gradient. Water tracks are clearly distinguished on satellite images, but poorly defined in the field. The pattern of the water tracks network depends on geomorphological position, permafrost and geological conditions and dominant cryogenic processes. Surface flow could occur in the water tracks during the snowmelt and heavy rains, when the soil is entirely frozen or fully saturated by water. In dry periods, the water tracks form retention zones due to low filtration rates and significant capacity of thawed soil beneath the troughs. Our study of water tracks in the north-western Yakutia showed the changes of their morphology from upstream towards downstream. The water levels in the water tracks have a pronounced diurnal course in reverse phase to the water temperature variation. They are related to diurnal ground thawing dynamics. Hydrology of water tracks depends on the peat thickness, active layer properties and lithology. Water tracks formed by rubble rocks respond to a storm event with rapidly increasing water level. The deeper thawing layer, the smoother water levels rise and decrease.

The results of long-term studies of a group of aufeis-forming Buluus groundwater sources are given. A stow, which has been formed by the spring, contains the drainage area of the suprapermafrost–intrapermafrost aquifer, which is widespread in the sand deposits of the bestyakhskaya terrace of the Lena River in Central Yakutia. The analysis of observations of 1964–2017 showed stable water chemistry in Buluus spring at the long-term scale. Considerable seasonal variations of water chemistry are typical of low-discharge springs, which start functioning after becoming free of aufeis. The spring water also shows higher concentrations of lithium and fluorine. The possible causes of the different chemistry of spring water are discussed, with special attention paid to the local activity of rock freezing and thawing processes in the aufeis valley. It is shown that groundwater samples are to be taken from all springs in the areas of their group discharge with the aim to assess the effect of natural and technogenic factors on the permafrost–hydrogeochemical conditions.

Structural features of a lake talik associated with eolian relief are discussed. Analysis of hydrochemical and hydrological data for 2010-2017 showed that talik groundwater feeds lake and maintains perennial outflow from the lake. Variations in the chemical composition of the lake and outflowing creek are characterized on an annual and interannual basis. Seasonal comparison of hydrochemical data indicates a downward trend in dissolved-solids content of the lake water over the last six years, suggesting an increasing contribution of suprapermafrost groundwater to the lake and lake talik. Probable reason of enhanced suprapermafrost flow is increase of its duration due to observed rise of winter air temperature.

An intrapermafrost aquifer system, which is widespread in the sand deposits of bestyakhskaya terrace of the Lena R. (Central Yakutia), is characterized by generalized data of many-year studies of its groundwater chemistry. The groundwater discharges onto land surface through high-yield springs. The largest such source forms the Ulakhan-Taryn Creek with a mean many-year yield of 20 740 m(3)/day. The results of generalization were used to show the chemistry of intrapermafrost water to be stable at both many-year and annual scales, to characterize the hydraulic interaction of intrapermafrost water with suprapermafrost and subpermafrost water, to assess the spatial variations of groundwater resources in the intrapermafrost aquifer from the head-formation to the discharge domain. The results of the study are of importance for solving the problem of centralized drinking water supply to large populated localities in the Central Yakutia, including Yakutsk City.