Методом соосаждения из водных растворов при различном порядке смешения реагентов синтезированы однофазные порошки твердого раствора KGd1,52Yb0,40Er0,08F7 со средним размером частиц 350 нм. Выявлены и исследованы процессы поверхностного вымывания калия. Определена оптимальная температура термообработки (525оС), позволившая достигнуть величины энергетического выхода ап-конверсионной люминесценции эрбия 1,30±0,02% при возбуждении на длине волны 974 нм с плотностью мощности накачки 1 Вт/см2.
Single-phase powders of a KGd1.52Yb0.40Er0.08F7 solid solution with an average particle size of 350 nm are synthesized by co-precipitation from aqueous solutions with a different order of mixing reagents. Surface leaching processes of potassium are revealed and studied. The optimal temperature of thermal treatment (525 °C) is determined. It enables the achievement of the energy yield of erbium up-conversion luminescence of 1.30±0.02
The possibility of doping the KGd2F7 matrix with ytterbium and erbium ions by introducing yttrium ions with a concentration of 25 mol.% was confirmed and the conditions were determined for the synthesis of anti-Stokes phosphors based on single-phase KGd2F7:Yb,Er solid solutions. The dependences were revealed of the sizes of coherent scattering regions, crystal lattice parameters, and energy yield of luminescence on the temperature and duration of heat treatment. Heat treatment conditions were determined to ensure the achievement of intense anti-Stokes luminescence. As a result, effective phosphors KGd2F7:Yb (20.0 mol.%),Er (4.0 mol.%) with an energy yield of up-conversion luminescence of 3.80 % were developed. Disordering of the crystal structure (transition from cubic to tetragonal modification) at a temperature of 600 degrees C was recorded, corresponding to the rule of Ostwald steps.
The review presents the history of the creation and work of the Scientific Council “Cybernetics” (SCC)—the center for development of cybernetics in the USSR and Russia. The Council’s activity is covered as a structure that coordinates scientific and technical activity in cybernetics in the country via a system of sections: about 16 public and professional bodies involving thousands of specialists. Brief information about the sections is given. The chronology of development of the SCC is discussed, in particular, information about its chairmen, starting with the renowned organizer of research and development, Academician and Admiral Axel Ivanovich Berg and the following academicians: B.N. Petrov, O.M. Belotserkovsky, A.P. Ershov, E.P. Velikhov, B.V. Bunkin, and Yu.I. Zhuravlev. The SCC’s publishing activity is briefly reviewed. The second function, built into the SCC from its onset, is as a research institute conducting its own research on the most pressing scientific problems insufficiently covered by existing structures. Several main areas of research by the SCC itself and its successor, the Axel Berg Institute of Cybernetics and Educational Computing of the Federal Research Center “Computer Science and Control” of the RAS: coding and transmission of information, economic cybernetics, aircraft control, supercomputers, digital technologies in education, mathematical logic and the theory of algorithms, pattern recognition and image analysis, mathematical methods of image analysis, theoretical physics, biomedical cybernetics, and ultrasound imaging. Another function of the SCC is considered: as an incubator of new academic industrially oriented structures and the fate of one of them—the Institute of Cybernetics Problems—is traced.