Quantum systems of indistinguishable particles are commonly described using the formalism of second quantisation, which relies on the assumption that any admissible quantum state must be either symmetric or anti-symmetric under particle permutations. Coherence-induced many-body effects such as superradiance, however, can arise even in systems whose constituents are not fundamentally indistinguishable as long as all relevant dynamical observables are permutation-invariant. Such systems are not confined to symmetric or anti-symmetric states and therefore require a different theoretical approach. Focusing on non-interacting systems, here we combine tools from representation theory and thermodynamically consistent master equations to develop such a framework. We characterise the structure and properties of the steady states emerging in permutation-invariant ensembles of arbitrary multi-level systems that are collectively weakly coupled to a thermal environment. As an application of our general theory, we further explore how these states can in principle be used to enhance the performance of quantum thermal machines. Our group-theoretical framework thereby makes it possible to analyse various limiting cases that would not be accessible otherwise. In addition, it allows us to show that the properties of multi-level ensembles differ qualitatively from those of spin ensembles, which have been investigated earlier using the standard Clebsch-Gordan theory. Our results have a large scope for future generalisations and pave the way for systematic investigations of collective effects arising from permutation-invariance in quantum thermodynamics.

Bell's theorem shows that no local hidden-variable model can explain the measurement statistics of a quantum system shared between two parties, thus ruling out a classical (local) understanding of nature. In this paper we demonstrate that by relaxing the positivity restriction in the hidden-variable probability distribution it is possible to derive quasiprobabilistic Bell inequalities whose sharp upper bound is written in terms of a negativity witness of said distribution. This provides an analytic solution for the amount of negativity necessary to violate the Clauser-Horne-Shimony-Holt inequality by an arbitrary amount, therefore revealing the amount of negativity required to emulate the quantum statistics in a Bell test.

The classical Gibbs paradox concerns the entropy change upon mixing two gases. Whether an observer assigns an entropy increase to the process depends on their ability to distinguish the gases. A resolution is that an "ignorant" observer, who cannot distinguish the gases, has no way of extracting work by mixing them. Moving the thought experiment into the quantum realm, we reveal new and surprising behaviour: the ignorant observer can extract work from mixing different gases, even if the gases cannot be directly distinguished. Moreover, in the macroscopic limit, the quantum case diverges from the classical ideal gas: as much work can be extracted as if the gases were fully distinguishable. We show that the ignorant observer assigns more microstates to the system than found by naive counting in semiclassical statistical mechanics. This demonstrates the importance of accounting for the level of knowledge of an observer, and its implications for genuinely quantum modifications to thermodynamics.

The existence of fundamentally identical particles represents a foundational distinction between classical and quantum mechanics. Because of their exchange symmetry, identical particles can appear to be entangled-another uniquely quantum phenomenon with far-reaching practical implications. However, a long-standing debate has questioned whether identical particle entanglement is physical or merely a mathematical artifact. In this work, we provide such particle entanglement with a consistent theoretical description as a quantum resource in processes frequently encountered in optical and cold atomic systems. This leads to a plethora of applications of immediate practical impact. On the one hand, we show that the metrological advantage for estimating phase shifts in systems of identical bosons amounts to a measure of their particle entanglement, with a clear-cut operational meaning. On the other hand, we demonstrate in general terms that particle entanglement is the property resulting in directly usable mode entanglement when distributed to separated parties, with particle conservation laws in play. Application of our tools to an experimental implementation with Bose-Einstein condensates leads to the first quantitative estimation of identical particle entanglement. Further connections are revealed between particle entanglement and other resources such as optical nonclassicality and quantum coherence. Overall, this work marks a resolutive step in the ongoing debate by delivering a unifying conceptual and practical understanding of entanglement between identical particles.

We investigate the quantum thermodynamical properties of localised relativistic quantum fields, and how they can be used as quantum thermal machines. We study the efficiency and power of energy transfer between the classical gravitational degrees of freedom, such as the energy input due to the motion of boundaries or an impinging gravitational wave, and the excitations of a confined quantum field. We find that the efficiency of energy transfer depends dramatically on the input initial state of the system. Furthermore, we investigate the ability of the system to extract energy from a gravitational wave and store it in a battery. This process is inefficient in optical cavities but is significantly enhanced when employing trapped Bose Einstein condensates. We also employ standard fluctuation results to obtain the work probability distribution, which allows us to understand how the efficiency is related to the dissipation of work. Finally, we apply our techniques to a setup where an impinging gravitational wave excites the phononic modes of a Bose Einstein condensate. We find that, in this case, the percentage of energy transferred to the phonons approaches unity after a suitable amount of time. These results give a quantitative insight into the thermodynamic behaviour of relativistic quantum fields confined in cavities.

We study the process of assisted work distillation. This scenario arises when two parties share a bipartite quantum state ρ_{AB} and their task is to locally distill the optimal amount of work when one party is restricted to thermal operations, whereas the other can perform general quantum operations and they are allowed to communicate classically. We demonstrate that this question is intimately related to the distillation of classical and quantum correlations. In particular, we show that the advantage of one party performing global measurements over many copies of ρ_{AB} is related to the nonadditivity of the entanglement of formation. We also show that there may exist work bound in the quantum correlations of the state that is only extractable under the wider class of local Gibbs-preserving operations.

Motivated by recent progress on the motive power of information in quantum thermodynamics, we put forth an operational resource theory of Maxwell's demons. We show that the resourceful ({\em daemonic}) states can be partitioned into at most nine irreducible subsets. The sets can be classified by a rank akin to the Schmidt rank for entanglement theory. Moreover, we show that there exists a natural monotone, called the wickedness, which quantifies the multilevel resource content of the states. The present resource theory is shown to share deep connections with the resource theory of thermodynamics. In particular, the nine irreducible sets are found to be characterized by well defined temperatures which, however, are not monotonic in the wickedness. This result, as we demonstrate, is found to have dramatic consequences for Landauer's erasure principle. Our analysis therefore settles a longstanding debate surrounding the identity of Maxwell's demons and the operational significance of other related fundamental thermodynamic entities.

The reaction-coordinate mapping is a useful technique to study complex quantum dissipative dynamics into structured environments. In essence, it aims to mimic the original problem by means of an augmented system, which includes a suitably chosen collective environmental coordinate-the reaction coordinate. This composite then couples to a simpler residual reservoir with short-lived correlations. If, in addition, the residual coupling is weak, a simple quantum master equation can be rigorously applied to the augmented system, and the solution of the original problem just follows from tracing out the reaction coordinate. But, what if the residual dissipation is strong? Here, we consider an exactly solvable model for heat transport-a two-node linear quantum wire connecting two baths at different temperatures. We allow for a structured spectral density at the interface with one of the reservoirs and perform the reaction-coordinate mapping, writing a perturbative master equation for the augmented system. We find that (a) strikingly, the stationary state of the original problem can be reproduced accurately by a weak-coupling treatment even when the residual dissipation on the augmented system is very strong, (b) the agreement holds throughout the entire dynamics under large residual dissipation in the overdamped regime; and (c) such a master equation can grossly overestimate the stationary heat current across the wire, even when its nonequilibrium steady state is captured faithfully. These observations can be crucial when using the reaction-coordinate mapping to study the largely unexplored strong-coupling regime in quantum thermodynamics.

We investigate manipulations of pure quantum states under incoherent or strictly incoherent operations assisted by a coherence battery, that is, a storage device whose degree of coherence is allowed to fluctuate in the process. This leads to the derivation of fluctuation relations for quantum coherence, analogous to Jarzynski's and Crooks' relations for work in thermodynamics. Coherence is thus revealed as another instance of a physical resource, in addition to athermality and entanglement, for which a connection is established between the majorisation framework (regulating pure state transformations under suitable free operations) and the emergence of fluctuation theorems. Our study is hoped to provide further insight into the general structure of battery assisted quantum resource theories, and more specifically into the interplay between quantum coherence and quantum thermodynamics.