In quantum metrology, entangled states of many-particle systems are investigated to enhance measurement precision of the most precise clocks and field sensors. Whereas single-parameter quantum metrology is well established, joint multiparameter estimation poses conceptual challenges and has been explored only theoretically. We experimentally demonstrated multiparameter quantum metrology with an array of entangled atomic ensembles. By splitting a spin-squeezed ensemble, we created an atomic sensor array featuring intersensor entanglement that can be flexibly configured to enhance measurement precision of multiple parameters jointly. Using an optimal estimation protocol, we achieved substantial gains over the standard quantum limit in key multiparameter estimation tasks, thus grounding the concept of quantum enhancement of field sensor arrays and imaging devices.

In 1935, Einstein, Podolsky and Rosen (EPR) conceived a Gedankenexperiment which became a cornerstone of quantum technology and still challenges our understanding of reality and locality today. While the experiment has been realized with small quantum systems, a demonstration of the EPR paradox with spatially separated, massive many-particle systems has so far remained elusive. We observe the EPR paradox in an experiment with two spatially separated Bose-Einstein condensates containing about 700 Rubidium atoms each. EPR entanglement in conjunction with individual manipulation of the two condensates on the quantum level, as demonstrated here, constitutes an important resource for quantum metrology and information processing with many-particle systems. Our results show that the conflict between quantum mechanics and local realism does not disappear as the system size is increased to over a thousand massive particles.

The existence of fundamentally identical particles represents a foundational distinction between classical and quantum mechanics. Because of their exchange symmetry, identical particles can appear to be entangled-another uniquely quantum phenomenon with far-reaching practical implications. However, a long-standing debate has questioned whether identical particle entanglement is physical or merely a mathematical artifact. In this work, we provide such particle entanglement with a consistent theoretical description as a quantum resource in processes frequently encountered in optical and cold atomic systems. This leads to a plethora of applications of immediate practical impact. On the one hand, we show that the metrological advantage for estimating phase shifts in systems of identical bosons amounts to a measure of their particle entanglement, with a clear-cut operational meaning. On the other hand, we demonstrate in general terms that particle entanglement is the property resulting in directly usable mode entanglement when distributed to separated parties, with particle conservation laws in play. Application of our tools to an experimental implementation with Bose-Einstein condensates leads to the first quantitative estimation of identical particle entanglement. Further connections are revealed between particle entanglement and other resources such as optical nonclassicality and quantum coherence. Overall, this work marks a resolutive step in the ongoing debate by delivering a unifying conceptual and practical understanding of entanglement between identical particles.

We experimentally and theoretically study phase coherence in two-component Bose-Einstein condensates of $^{87}{\rm Rb}$ atoms on an atom chip. Using Ramsey interferometry we measure the temporal decay of coherence between the $|F=1,m_{F}=-1\rangle$ and $|F=2,m_{F}=+1\rangle$ hyperfine ground states. We observe that the coherence is limited by random collisional phase shifts due to the stochastic nature of atom loss. The mechanism is confirmed quantitatively by a quantum trajectory method based on a master equation which takes into account collisional interactions, atom number fluctuations, and losses in the system. This decoherence process can be slowed down by reducing the density of the condensate. Our findings are relevant for experiments on quantum metrology and many-particle entanglement with Bose-Einstein condensates and the development of chip-based atomic clocks.

Ultracold Bose gases allow the detailed study of the dynamics of two weakly coupled superfluids. The experimental platform offers precise control of the crucial parameters as well as the capability for a very direct observation of the relevant observables. We give a detailed introduction into the experimental realization of a weak linkWeak links for ultracold Bose gases and the corresponding theoretical description.

Many-particle entanglement is a fundamental concept of quantum physics that still presents conceptual challenges. Although nonclassical states of atomic ensembles were used to enhance measurement precision in quantum metrology, the notion of entanglement in these systems was debated because the correlations among the indistinguishable atoms were witnessed by collective measurements only. Here, we use high-resolution imaging to directly measure the spin correlations between spatially separated parts of a spin-squeezed Bose-Einstein condensate. We observe entanglement that is strong enough for Einstein-Podolsky-Rosen steering: We can predict measurement outcomes for noncommuting observables in one spatial region on the basis of corresponding measurements in another region with an inferred uncertainty product below the Heisenberg uncertainty bound. This method could be exploited for entanglement-enhanced imaging of electromagnetic field distributions and quantum information tasks.

We observe multistep condensation of sodium atoms with spin F=1, where the different Zeeman components m_{F}=0,±1 condense sequentially as the temperature decreases. The precise sequence changes drastically depending on the magnetization m_{z} and on the quadratic Zeeman energy q (QZE) in an applied magnetic field. For large QZE, the overall structure of the phase diagram is the same as for an ideal spin-1 gas, although the precise locations of the phase boundaries are significantly shifted by interactions. For small QZE, antiferromagnetic interactions qualitatively change the phase diagram with respect to the ideal case, leading, for instance, to condensation in m_{F}=±1, a phenomenon that cannot occur for an ideal gas with q>0.

We devise a method to shortcut the adiabatic evolution of a spin-1 Bose gas with an external magnetic field as the control parameter. An initial many-body state with almost all bosons populating the Zeeman sublevel $m=0$, is evolved to a final state very close to a macroscopic spin-singlet condensate, a fragmented state with three macroscopically occupied Zeeman states. The shortcut protocol, obtained by an approximate mapping to a harmonic oscillator Hamiltonian, is compared to linear and exponential variations of the control parameter. We find a dramatic speedup of the dynamics when using the shortcut protocol.

Large spin systems can exhibit unconventional types of magnetic ordering, different from the ferromagnetic or Neel-like antiferromagnetic order commonly found in spin 1/2 systems. Spin-nematic phases, for instance, do not break time-reversal invariance, and their magnetic order parameter is characterized by a second-rank tensor with the symmetry of an ellipsoid. Here we show direct experimental evidence of spin-nematic ordering in a spin 1 Bose-Einstein condensate of sodium atoms with antiferromagnetic interactions. In a mean field description this order is enforced by locking the relative phase between spin components. We reveal this mechanism by studying the spin noise after a spin rotation, which is shown to contain information hidden when looking only at averages. The method should be applicable to high-spin systems in order to reveal complex magnetic phases.

We experimentally demonstrate an alternative method for the dynamic generation of atomic spin squeezing, building on the interplay between linear coupling and nonlinear phase evolution. Since the resulting quantum dynamics can be seen as rotation and shear on the generalized Bloch sphere, we call this scheme twist-and-turn (TnT). This is closely connected to an underlying instability in the classical limit of this system. The short-time evolution of the quantum state is governed by a fast initial spreading of the quantum uncertainty in one direction, accompanied by squeezing in the orthogonal axis. We find an optimal value of $\xi_{\text{S}}^2=-7.1(3)$ dB in a single BEC and scalability of the squeezing to more than 10^4 particles with $\xi_{\text{S}}^2=-2.8(4)$ dB.

We propose a theoretical framework based on SU(3) coherent states as a convenient tool to describe the collective state of a Bose-Einstein condensate of spin-1 atoms at thermal equilibrium. We work within the single-mode approximation, which assumes that all atoms condense in the same spatial mode. In this system, the magnetization mz is conserved to a very good approximation. This conservation law is included by introducing a prior distribution for mz and constructing a generalized statistical ensemble that preserves its first moments. In the limit of large particle numbers, we construct the partition function at thermal equilibrium and use it to compute various quantities of experimental interest, such as the probability distribution function and moments of the population in each Zeeman state. When N is large but finite (as in typical experiments, where ), we find that fluctuations of the collective spin can be important.

Entanglement is the key quantum resource for improving measurement sensitivity beyond classical limits. However, the production of entanglement in mesoscopic atomic systems has been limited to squeezed states, described by Gaussian statistics. Here we report on the creation and characterization of non-Gaussian many-body entangled states. We develop a general method to extract the Fisher information, which reveals that the quantum dynamics of a classically unstable system creates quantum states that are not spin squeezed but nevertheless entangled. The extracted Fisher information quantifies metrologically useful entanglement which we confirm by Bayesian phase estimation with sub shot-noise sensitivity. These methods are scalable to large particle numbers and applicable directly to other quantum systems.

In this thesis we study experimentally the magnetic properties of spin-1 Bose-Einstein condensate of Sodium at equilibrium. In this system the atoms can occupy any of the three Zeeman states characterized by their spin projection on the quantization axis m=+1,0,-1. We measure the many-body spin state of the system as a function of the applied magnetic field and of the magnetization (difference between the populations of the spin states m=+1 and m=-1) of the atomic sample. We find that our measurements reproduce very well the mean-field prediction, and we identify two magnetic phases expressing the competition between the antiferromagnetic inter-particle interactions and the effect of the magnetic field. We describe these phases in terms of a spin nematic order characterizing the symmetry of the many-body spin state. In a second part we focus on the properties of condensates of very low magnetization under a weak magnetic field. In these conditions, the symmetry of the system manifests itself in huge spin fluctuations. This phenomenon is not explainable by a naive mean-field theory and we develop a more elaborate statistical approach to describe the spin state of the condensate. We measure the spin fluctuations and are able from their analysis to infer the temperature characterizing the spin degree of freedom of the condensate. We find that this temperature differs from the temperature of the thermal fraction surrounding the condensate. We interpret this difference as a consequence of the weak coupling between these two systems.

We study experimentally the equilibrium phase diagram of a spin 1 Bose-Einstein condensate with antiferromagnetic interactions, in a regime where spin and spatial degrees of freedom are decoupled. For a given total magnetization mz, we observe for low magnetic fields an "antiferromagnetic" phase where atoms condense in the m=+/-1 Zeeman states, and occupation of the m=0 state is suppressed. Conversely, for large enough magnetic fields, a phase transition to a "broken axisymmetry" phase takes place: The m=0 component becomes populated and rises sharply above a critical field Bc(mz). This behavior results from the competition between antiferromagnetic spin-dependent interactions (dominant at low fields) and the quadratic Zeeman energy (dominant at large fields). We compare the measured Bc as well as the global shape of the phase diagram with mean-field theory, and find good quantitative agreement.

We experimentally investigate the mixing and demixing dynamics of Bose-Einstein condensates in the presence of a linear coupling between two internal states. The observed amplitude reduction of the Rabi oscillations can be understood as a result of demixing dynamics of dressed states as experimentally confirmed by reconstructing the spatial profile of dressed state amplitudes. The observations are in quantitative agreement with numerical integration of coupled Gross-Pitaevskii equations without free parameters, which also reveals the criticality of the dynamics on the symmetry of the system. Our observations demonstrate new possibilities for changing effective atomic interactions and studying critical phenomena.

An atomic analogue to homodyne detection for the measurement of matter-wave quadratures is realized, which is needed to extend quantum applications to massive particles. Continuous variable entanglement is regarded as an essential resource for quantum applications, including enhanced measurement resolution, quantum teleportation and quantum memories. These applications rely on techniques to manipulate and detect coherences (quadratures) of quantum fields. In optics, coherent homodyne detection of quadratures is a standard technique, but no corresponding method was available for massive particles. Gross et al. now report the realization of an atomic analogue to homodyne detection for the measurement of matter-wave quadratures. They use it to demonstrate continuous variable entanglement of a quantum state produced by spin-changing collisions in a Bose–Einstein condensate. Historically, the completeness of quantum theory has been questioned using the concept of bipartite continuous-variable entanglement1. The non-classical correlations (entanglement) between the two subsystems imply that the observables of one subsystem are determined by the measurement choice on the other, regardless of the distance between the subsystems. Nowadays, continuous-variable entanglement is regarded as an essential resource, allowing for quantum enhanced measurement resolution2, the realization of quantum teleportation3,4,5 and quantum memories3,6, or the demonstration of the Einstein–Podolsky–Rosen paradox1,7,8,9. These applications rely on techniques to manipulate and detect coherences of quantum fields, the quadratures. Whereas in optics coherent homodyne detection10 of quadratures is a standard technique, for massive particles a corresponding method was missing. Here we report the realization of an atomic analogue to homodyne detection for the measurement of matter-wave quadratures. The application of this technique to a quantum state produced by spin-changing collisions in a Bose–Einstein condensate11,12 reveals continuous-variable entanglement, as well as the twin-atom character of the state13. Our results provide a rare example of continuous-variable entanglement of massive particles6,14. The direct detection of atomic quadratures has applications not only in experimental quantum atom optics, but also for the measurement of fields in many-body systems of massive particles15.

Interference is fundamental to wave dynamics and quantum mechanics. The quantum wave properties of particles are exploited in metrology using atom interferometers, allowing for high-precision inertia measurements. Furthermore, the state-of-the-art time standard is based on an interferometric technique known as Ramsey spectroscopy. However, the precision of an interferometer is limited by classical statistics owing to the finite number of atoms used to deduce the quantity of interest. Here we show experimentally that the classical precision limit can be surpassed using nonlinear atom interferometry with a Bose-Einstein condensate. Controlled interactions between the atoms lead to non-classical entangled states within the interferometer; this represents an alternative approach to the use of non-classical input states. Extending quantum interferometry to the regime of large atom number, we find that phase sensitivity is enhanced by 15 per cent relative to that in an ideal classical measurement. Our nonlinear atomic beam splitter follows the 'one-axis-twisting' scheme and implements interaction control using a narrow Feshbach resonance. We perform noise tomography of the quantum state within the interferometer and detect coherent spin squeezing with a squeezing factor of -8.2 dB (refs 11-15). The results provide information on the many-particle quantum state, and imply the entanglement of 170 atoms.

We report on the experimental demonstration of the internal bosonic Josephson effect in a rubidium spinor Bose-Einstein condensate. The measurement of the full time dynamics in phase space allows the characterization of the theoretically predicted π-phase modes and quantitatively confirms analytical predictions, revealing a classical bifurcation. Our results suggest that this system is a model system which can be tuned from classical to the quantum regime and thus is an important step towards the experimental investigation of entanglement generation close to critical points.