Spherical proportional counters (SPCs) are gaseous particle detectors sensitive to single ionization electrons in their target media, with large detector volumes and low background rates. The $\mbox{NEWS-G}$ collaboration employs this technology to search for low-mass dark matter, having previously performed searches with detectors at the Laboratoire Souterrain de Modane (LSM), including a recent campaign with a 135 cm diameter SPC filled with methane. While in situ calibrations of the detector response were carried out at the LSM, measurements of the mean ionization yield and fluctuations of methane gas in SPCs were performed using a 30 cm diameter detector. The results of multiple measurements taken at different operating voltages are presented. A UV laser system was used to measure the mean gas gain of the SPC, along with $\mathrm{^{37}Ar}$ and aluminum-fluorescence calibration sources. These measurements will inform the energy response model of future operating detectors.

The NEWS-G direct detection experiment uses spherical proportional counters to search for light dark matter candidates. New results from a 10 day physics run with a 135 cm in diameter spherical proportional counter at the Laboratoire Souterrain de Modane are reported. The target consists of 114 g of methane, providing sensitivity to dark matter spin-dependent coupling to protons. New constraints are presented in the mass range 0.17 to 1.2 GeV/c^{2}, with a 90% confidence level cross-section upper limit of 30.9 pb for a mass of 0.76 GeV/c^{2}.

The neutron flux distribution within the pool of the SLOWPOKE-2 reactor at the RMC has been characterized using neutron activation measurements as well as MCNP simulations. Westcott equivalent thermal neutron flux values were calculated from measured activities of solutions of Co, Au, and Cd-shielded Au at several reactor flux settings and compared to tabulated fluxes from MCNP simulations. Good agreement was found between the simulated and experimental thermal flux values, while larger uncertainties were highlighted in higher energy neutron fluxes.

Precise identification and thermodynamic assessment of the various phases in spent nuclear fuel are necessary for the accurate dynamic modeling of nuclear fuel. The Thermodynamics of Advanced Fuels – International Database (TAF-ID) compiles high-quality, self-consistent, and reliable thermodynamic data of various phases in chemical systems of interest for the international nuclear industry, such as the Ba-Mo-O ternary system. The thermodynamic properties of compounds in the Ba-Mo-O ternary system, especially those of hexavalent Mo, have been extensively studied and included in computational thermodynamic assessments. In contrast, compounds with Mo in reduced oxidation states, such as BaMo6O10 and Ba3Mo18O28, have been excluded from such assessments due to a lack of experimentally assessed thermodynamic data. In this work, high-quality samples of the aforementioned compounds were synthesized, and the first experimental assessment of their heat capacities in the temperature range 300-600 K were obtained. Furthermore, a reversible phase transition was identified at ∼380 K for BaMo6O10. The collected experimentally-assessed thermodynamic data from this work and initial calculated estimations of standard enthalpies of formation and entropies for these compounds were successfully integrated into a preliminary, updated Ba-Mo-O thermodynamic assessment using the CALPHAD method. Key thermodynamic properties of the newly included compounds (i.e., standard enthalpy of formation and entropy) were calculated using the new Ba-Mo-O assessment.

Complex molybdates are traditionally prepared via solid-state synthesis and aqueous chemistry methods, which generally require long reaction times and large solvent volumes or high sintering temperatures. However, these techniques often result in undesired secondary species, incomplete reactions, and relatively low yields. Mechanochemistry has proven effective for the synthesis of complex molybdates. This work expands on the development of the mechanochemical synthesis of various heptamolybdates (i.e., sodium, rubidium, and cesium), and trimolybdates (i.e., sodium, rubidium, cesium, strontium, and barium). The obtained materials were characterized via powder X-ray diffraction, Fourier-transform infrared spectroscopy, Raman spectroscopy, thermo-gravimetric analysis, and scanning electron microscopy to assess the purity, morphology, and quality of the sample. High purity samples of the various trimolybdates and heptamolybdates were obtained in less than three hours of reaction time, with minimal energy input and by-products. Mechanochemistry provides a fast, more sustainable, and simple procedure for the synthesis of a wide variety of both trimolybdates and heptamolybdates including the monohydrate form of sodium trimolybdate instead of the trihydrate variant commonly obtained from aqueous reactions.

The study of complex phases in nuclear fuels is necessary to understand the physicochemical properties of the fuel. Na6Mo7O24⋅14H2O (1) was prepared via a simplified method and the crystal structure was improved. Upon thermal degradation, 1 decomposes into Na2Mo2O7 and MoO3. Additionally, novel Ba3Mo7O24⋅12H2O (2) was isolated via an aqueous synthetic route and characterized via FTIR and elemental analysis. PXRD pattern of 2 was determined. Thermal degradation of 2 indicates formation of BaMoO4, BaMo3O10, MoO3, and an unidentified phase.

We present the conceptual design and the physics potential of DarkSPHERE, a proposed 3 m in diameter spherical proportional counter electroformed underground at the Boulby Underground Laboratory. This effort builds on the R&D performed and experience acquired by the NEWS-G Collaboration. DarkSPHERE is primarily designed to search for nuclear recoils from light dark matter in the 0.05--10 GeV mass range. Electroforming the spherical shell and the implementation of a shield based on pure water ensures a background level below 0.01 dru. These, combined with the proposed helium-isobutane gas mixture, will provide sensitivity to the spin-independent nucleon cross-section of $2\times 10^{-41} (2\times 10^{-43})$ cm$^2$ for a dark matter mass of $0.1 (1)$ GeV. The use of a hydrogen-rich gas mixture with a natural abundance of $^{13}$C provides sensitivity to spin-dependent nucleon cross-sections more than two orders of magnitude below existing constraints for dark matter lighter than 1 GeV. The characteristics of the detector also make it suitable for searches of other dark matter signatures, including scattering of MeV-scale dark matter with electrons, and super-heavy dark matter with masses around the Planck scale that leave extended ionisation tracks in the detector.

The New Experiments With Spheres-Gas (NEWS-G) collaboration intends to achieve $\mathrm{sub-GeV/c^{2}}$ Weakly Interacting Massive Particles (WIMPs) detection using Spherical Proportional Counters (SPCs). SPCs are gaseous detectors relying on ionization with a single ionization electron energy threshold. The latest generation of SPC for direct dark matter searches has been installed at SNOLAB in Canada in 2021. This article details the different processes involved in the fabrication of the NEWS-G experiment. Also outlined in this paper are the mitigation strategies, measurements of radioactivity of the different components, and estimations of induced background event rates that were used to quantify and address detector backgrounds.

Coherent elastic neutrino-nucleus scattering (CE$\nu$NS) is a process in which neutrinos scatter on a nucleus which acts as a single particle. Though the total cross section is large by neutrino standards, CE$\nu$NS has long proven difficult to detect, since the deposited energy into the nucleus is $\sim$ keV. In 2017, the COHERENT collaboration announced the detection of CE$\nu$NS using a stopped-pion source with CsI detectors, followed up the detection of CE$\nu$NS using an Ar target. The detection of CE$\nu$NS has spawned a flurry of activities in high-energy physics, inspiring new constraints on beyond the Standard Model (BSM) physics, and new experimental methods. The CE$\nu$NS process has important implications for not only high-energy physics, but also astrophysics, nuclear physics, and beyond. This whitepaper discusses the scientific importance of CE$\nu$NS, highlighting how present experiments such as COHERENT are informing theory, and also how future experiments will provide a wealth of information across the aforementioned fields of physics.

The capabilities of the Thermodynamic of Advanced Fuels - International Database (TAF-ID) for repro-ducing the chemical behaviour of irradiated nuclear fuel in severe accident conditions were studied, by comparing calculation results to experimental observations. SIMFUELs samples containing UO2 + 11 el-ements (Ba, Ce, La, Mo, Nd, Pd, Rh, Ru, Sr, Y and Zr, in concentration representative of a 76 GWd center dot tU -1 Burn-up) were submitted to 1327 degrees C in oxidizing conditions, and to 180 0, 20 0 0, and 210 0 degrees C under re-ducing ones. Samples were characterized by Electron Probe Micro-Analysis (EPMA), High-Resolution XRD, and X-ray Absorption Spectroscopy (XAS). Thermodynamic calculations reproduced accurately the solubil-ity of fission products in the UO2 matrix, and the type and composition of minor oxide and most metallic phases. Calculations also explain metallic phases microstructure as a result of the progressive solidifica-tion of liquids. However, some features such as the U-Pd-Rh association could not be reproduced, due to the lack of a thermodynamic model for this ternary system. (c) 2022 Elsevier B.V. All rights reserved.

Many low-threshold experiments observe sharply rising event rates of yet unknown origins below a few hundred eV, and larger than expected from known backgrounds. Due to the significant impact of this excess on the dark matter or neutrino sensitivity of these experiments, a collective effort has been started to share the knowledge about the individual observations. For this, the EXCESS Workshop was initiated. In its first iteration in June 2021, ten rare event search collaborations contributed to this initiative via talks and discussions. The contributing collaborations were CONNIE, CRESST, DAMIC, EDELWEISS, MINER, NEWS-G, NUCLEUS, RICOCHET, SENSEI and SuperCDMS. They presented data about their observed energy spectra and known backgrounds together with details about the respective measurements. In this paper, we summarize the presented information and give a comprehensive overview of the similarities and differences between the distinct measurements. The provided data is furthermore publicly available on the workshop's data repository together with a plotting tool for visualization.

The amount of energy released by a nuclear recoil ionizing the atoms of the active volume of detection appears "quenched" compared to an electron of the same kinetic energy. This different behavior in ionization between electrons and nuclei is described by the Ionization Quenching Factor (IQF) and it plays a crucial role in direct dark matter searches. For low kinetic energies (below $50~\mathrm{keV}$), IQF measurements deviate significantly from common models used for theoretical predictions and simulations. We report measurements of the IQF for proton, an appropriate target for searches of Dark Matter candidates with a mass of approximately 1 GeV, with kinetic energies in between $2~\mathrm{keV}$ and $13~\mathrm{keV}$ in $100~\mathrm{mbar}$ of methane. We used the Comimac facility in order to produce the motion of nuclei and electrons of controlled kinetic energy in the active volume, and a NEWS-G SPC to measure the deposited energy. The Comimac electrons are used as reference to calibrate the detector with 7 energy points. A detailed study of systematic effects led to the final results well fitted by $\mathrm{IQF}~(E_K)= E_K^\alpha~/~(\beta + E_K^\alpha)$ with $\alpha=0.70\pm0.08$ and $\beta = 1.32\pm0.17$. In agreement with some previous works in other gas mixtures, we measured less ionization energy than predicted from SRIM simulations, the difference reaching $33\%$ at $2~\mathrm{keV}$

Kaluza-Klein axions appear in theories with extra dimensions as higher mass, significantly shorter lifetime, excitations of the Peccei-Quinn axion. When produced in the Sun, they would remain gravitationally trapped in the solar system, and their decay to a pair of photons could provide an explanation of the solar corona heating problem. A low-density detector would discriminate such a signal from the background, by identifying the separation of the interaction point of the two photons. The NEWS-G collaboration uses large volume spherical proportional counters, gas-filled metallic spheres with a spherical anode in their centre. After observation of a single axionlike event in a 42 day long run with the SEDINE detector, a 90% C.L. upper limit of ga gamma gamma < 8.99 x 10-13 GeV-1 is set on the axion-photon coupling for the benchmark of a Kaluza-Klein axion density on Earth of na = 4.07 x 1013 m-3 and two extra dimensions of size R = 1 eV-1.

Discharged CANDU fuel is stored under water in irradiated fuel bays (IFBs) to remove their decay heat. If the fuel is exposed to air, a self-sustaining reaction could result when the Zircaloy-4 sheathing reaches temperatures sufficient for a breakaway oxidation. To predict when the transition occurs, a 2-D fuel bundle cross-section model in air was developed using the COMSOL Multiphysics®platform. Breakaway was predicted to occur at its earliest within 2.6 hours for a range of recently discharged bundle powers. It was concluded due to the time required for heat up and cracking of the oxide layer, sufficient margin exists for operators to intervene before a passively cooled, isolated bundle undergoes breakaway. To examine the effect of multiple bundles, a 3-D model based on a quarter of a stand-alone spent fuel rack was developed to calculate the steady-state temperature and mass fluxes of air. The model provided a lower bound for the ambient temperatures because the flow resistance of the bundle was not considered. The correct incorporation of flow resistance is a necessary step before conclusions could be made about the safety of IFBs. However, the analysis using a Computational Fluid Dynamics model for a 0.5 MW fuel rack, indicated that the maximum temperature of the air within the rack was 642 K and located at the centre of the outlet. This result is encouraging to support the safety of IFBs, as the temperature is well below the 873 K, which is approximately the minimum required for a breakaway reaction.

New Experiments with Spheres-Gas (NEWS-G) is a dark matter direct detection experiment that will operate at SNOLAB (Canada). Similar to other rare-event searches, the materials used in the detector construction are subject to stringent radiopurity requirements. The detector features a 140-cm diameter proportional counter comprising two hemispheres made from commercially sourced 99.99% pure copper. Such copper is widely used in rare-event searches because it is readily available, there are no long-lived Cu radioisotopes, and levels of non-Cu radiocontaminants are generally low. However, measurements performed with a dedicated 210Po alpha counting method using an XIA detector confirmed a problematic concentration of 210Pb in bulk of the copper. To shield the proportional counter's active volume, a low-background electroforming method was adapted to the hemispherical shape to grow a 500-µm thick layer of ultra-radiopure copper to the detector's inner surface. In this paper the process is described, which was prototyped at Pacific Northwest National Laboratory (PNNL), USA, and then conducted at full scale in the Laboratoire Souterrain de Modane in France. The radiopurity of the electroplated copper was assessed through Inductively Coupled Plasma Mass Spectrometry (ICP-MS). Measurements of samples from the first (second) hemisphere give 68% confidence upper limits of <0.58µBq/kg (<0.24µBq/kg) and <0.26µBq/kg (<0.11µBq/kg) on the 232Th and 238U contamination levels, respectively. These results are comparable to previously reported measurements of electroformed copper produced for other rare-event searches, which were also found to have low concentration of 210Pb consistent with the background goals of the NEWS-G experiment.

Fuel-Cladding Chemical Interaction (FCCI) in metallic nuclear fuels is a key phenomenon that limits the maximum burn-up and operating power as it can cause premature failure of the fuel cladding. Therefore, being able to accurately predict the interactions of the fuel-cladding system by means of thermodynamic calculations contributes to our understanding of how to mitigate this failure mechanism. In order to test the capabilities of the Thermodynamic of Advanced Fuels - International Database (TAF-ID) to predict these interactions, calculations have been performed on two irradiated metallic fuels: U-5Fs in SS316 cladding and U-10Zr in HT9 cladding, for which experimental observations are available in the literature. TAF-ID calculations have allowed the confirmation of some of the phases that were observed during experimental characterizations and the identification of unknown ones: Particularly for the U-5Fs fuel, two primary Fe-rich phases have been predicted: (i) FeU (6), that extends up to 120 mu m into the fuel, and (ii) UFe 2 with >30 wt.% Fe, likely to be the Fe-rich layer observed experimentally adjacent to the cladding on the fuel side. Also, minor phases that have been experimentally observed, such as U-Mo, U-Ru, and lanthanoid-noble metals (Nd,Ce-Pd), have been predicted to be stable. As for the U-10Zr fuel, calculations predicted several U-Fe-Zr phases (e.g., FeU (6), UFe (2), and.-FeUZr), Fe-(Ce,Nd) phases (e.g., Fe (17) Ln (2)), and a FCC phase consisting of Ce, Nd, La, Y, and Sr. These predicted phases are in excellent agreement with experimental observations. (C) 2021 Elsevier B.V. All rights reserved.

For irradiation experiments (e.g., of per- and polyfluoroalkyl substances), values of nuclear particle flux and absorbed dose rates were obtained for the Safe LOW-POwer Kritical Experiment-2 (SLOWPOKE-2) nuclear reactor at the Royal Military College of Canada using extensive simulations of the reactor core via the Monte Carlo N-Particle code, version 6 (MCNP6). Calculations from this work were compared to data from previously conducted experimental and simulation work to ensure simulation fidelity. In addition, reactor core burnup calculations were conducted using the fuel-depletion capability in MCNP6.1 to address the 30+ years of SLOWPOKE-2 reactor use. The combined absorbed dose rate in the inner irradiation sites was simulated to be 36 +/- 1 kGy h(-1) at a 10-kW(thermal) power setting, specifically, 20 +/- 6 kGy h(-1) from neutrons and 16 +/- 5 kGy h(-1) from photons.

The Thermodynamics of Advanced Fuels – International Database (TAF-ID) was developed using the Calphad method to provide a computational tool to perform thermodynamic calculations on nuclear fuel materials under normal and off-normal conditions. Different kinds of fuels are considered: oxide, metallic, carbide and nitride fuels. Many fission products are introduced as well as structural materials (e.g., zirconium, steel, concrete, SiC) and absorbers (e.g., B4C), in order to investigate the thermochemistry of irradiated fuels and to predict their chemical interaction with the surrounding materials. The approach to develop the database and the models implemented in the database are described. Examples of models for key chemical systems are presented. Finally, a few examples of application calculations on severe accidents with UO2 fuels, irradiated fuel chemistry of MOX and metallic fuels and metallic fuel/cladding interaction show how this tool can be used. To validate the database, the calculations are compared to the available experimental data. A good agreement is obtained which gives confidence in the maturity degree and quality of the TAF-ID database. The working version is only accessible to the participants of the TAF-ID project (Canada, France, Japan, the Netherlands, Republic of Korea, United Kingdom, USA). A public version is accessible by all the NEA countries. The current version contains models on the Am–Fe, Am–Np, Am-O-Pu, Am–U, Am–Zr, C–O–U-Pu, Cr–U, Np–U, Np–Zr, O–U–Zr, Re–U, Ru–U, Si–U, Ti–U, U-Pu-Zr, U–W systems. It is progressively extended with our published assessments. Information on how to join the project is available on the website: https://www.oecd-nea.org/science/taf-id/.

Spherical Proportional Counters (SPCs) are a novel gaseous detector technology employed by the NEWS-G low-mass dark matter search experiment for their high sensitivity to single electrons from ionization. In this paper, we report on the first characterization of the single electron response of SPCs with unprecedented precision, using a UV-laser calibration system. The experimental approach and analysis methodology are presented along with various direct applications for the upcoming next phase of the experiment at SNOLAB. These include the continuous monitoring of the detector response and electron drift properties during dark matter search runs, as well as the experimental measurement of the trigger threshold efficiency. We measure a mean ionization energy of $\mathrm{W}=27.6\pm0.2~\mathrm{eV}$ in $\mathrm{Ne + CH_4}$ $(2\%)$ for 2.8 keV X-rays, and demonstrate the feasibility of performing similar precision measurements at sub-keV energies for future gas mixtures to be used for dark matter searches at SNOLAB.

Spherical proportional counters (SPCs) are a novel gaseous detector technology employed by the NEWS-G low-mass dark matter search experiment for their high sensitivity to single electrons from ionization. In this paper, we report on the first characterization of the single electron response of SPCs with unprecedented precision, using a UV-laser calibration system. The experimental approach and analysis methodology are presented along with various direct applications for the upcoming next phase of the experiment at SNOLAB. These include the continuous monitoring of the detector response and electron drift properties during dark matter search runs, as well as the experimental measurement of the trigger threshold efficiency. We measure a mean ionization energy of W = 27.6 +/- 0.2 eV in Ne + CH4 (2%) for 2.8 keV x-rays, and demonstrate the feasibility of performing similar precision measurements at sub-keV energies for future gas mixtures to be used for dark matter searches at SNOLAB.